Removing inclusions

• US 4,316,734 A
• Filed: 03/03/1980
• Issued: 02/23/1982
• Est. Priority Date: 03/03/1980
• Status: Expired due to Term

• Current Assignee: Battelle Memorial Institute
• Original Assignee: Battelle Memorial Institute
• Inventors: Ensminger, Dale, Spinosa, Emilio D.
• Primary Examiner(s): Kellogg, Arthur D.
• Application Number:
  US06/126,797
• Time in Patent Office: 722 Days
• Field of Search: 65/134, 65/135, 65/, 65/136, 55/15
• US Class Current: 65/134.9
• CPC Class Codes: B01D 19/0078 by vibration
• CPC Class Codes: C03B 5/225 Refining C03B5/18 takes precedence ; Refining agents C03C1/004
• CPC Class Codes: Y02P 40/57 Improving the yield, e-g- reduction of reject rates

Abstract

A method of removing gaseous inclusions from a highly viscous liquid (10) that comprises applying sonic energy, as by means of acoustic horns (11), or other suitable acoustic source, in the liquid (10) at an energy intensity sufficient to induce migration and coalescence of the inclusions in the liquid (10), and less than that required to produce substantial cavitation therein, until the volume density of the inclusions has been reduced to a desired level. Typically the frequency and the energy intensity are selected, and adjusted if necessary, to provide a mode of operation whereby the liquid (10) is subjected to a cyclic component of stress that causes bubbles to collide and form larger bubbles, and to a substantially unidirectional component of stress, due to viscous losses and other mechanisms occuring in an acoustic field (e.g. radiation pressure), that tends to drive the growing bubbles away from the source (11) of the sonic energy and thus to facilitate their movement toward the surface (13) of the liquid (10) and the environs.

Claims

1. A method of removing gaseous inclusions from a highly viscous liquid containing both inclusions and dissolved gases comprising

applying sonic energy in the liquid at an energy intensity sufficient to induce migration and coalescence of the inclusions in the liquid, and less than that required to produce substantial cavitation therein, so as to avoid substantial liberation of dissolved gases, until the volume density of the inclusions has been reduced to a desired level.

2. A method as in claim 1, wherein the viscosity of the liquid is within the range of about 50 to 1000 poise.

3. A method as in claim 1, wherein the energy intensity is within the range of about 0.003 to 15 watts per square centimeter.

4. A method as in claim 1, wherein the frequency of the sonic energy is within the range of about 16 Hz to 100 kHz.

5. A method as in claim 1, wherein the frequency of the sonic energy is selected, and adjusted if necessary, to match the acoustic parameters of the liquid and the container holding it.

6. A method as in claim 1, wherein the source of the sonic energy is selected, and adjusted if necessary, to have an acoustic impedance that substantially matches the acoustic impedance of the liquid at the interface between the source and the liquid.

7. A method as in claim 1, wherein the frequency and the energy intensity are selected, and adjusted if necessary, to provide a mode of operation whereby the liquid is subjected to a cyclic component of stress that causes bubbles to collide and form larger bubbles, and to a substantially unidirectional component of stress, due to viscous losses and other mechanisms existing in an acoustic field, that tends to drive the growing bubbles away from the source of the sonic energy and thus to facilitate their movement toward the surface of the liquid and the environs.

8. A method as in claim 1, wherein the liquid is molten glass at a temperature within the range of about 1200 to 1500 C., having a viscosity within the range of about 50 to 1000 poise, wherein the intensity of the sonic energy is within the range of about 0.003 to 15 watts per square centimeter, and the frequency is within the range of about 16 Hz to 100 kHz.

9. A method as in claim 1, wherein the liquid is molten glass, and the frequency and the energy intensity are selected, and adjusted if necessary, responsive to the dynamic viscosity of the glass and the acoustic impedance at the interface between the source of the sonic energy and the glass, to provide a mode of operation wherein a substantial percentage of the bubbles in the glass migrate upward at rates at least about equal to a rate at which a bubble about 0.4 millimeter in diameter typically rises because of buoyancy through glass at a viscosity of about 100 poise.