Aqueous alkali metal chloride electrolytic cell

• US 4,319,969 A
• Filed: 08/14/1980
• Issued: 03/16/1982
• Est. Priority Date: 08/31/1979
• Status: Expired due to Term

• Current Assignee: Asahi Glass Company, Limited (AGC, Inc.)
• Original Assignee: Asahi Glass Company, Limited (AGC, Inc.)
• Inventors: Morimoto, Takeshi, Suzuki, Kohji, Oda, Yoshio
• Primary Examiner(s): Gantz, Delbert E.
• Assistant Examiner(s): Valentine, Donald R.
• Application Number:
  US06/177,896
• Time in Patent Office: 579 Days
• Field of Search: 204/252, 204/283-284, 204/290 R, 204/296, 204/98, 204/128, 204/292, 427/282, 427/126.5, 427/245
• US Class Current: 204/252
• CPC Class Codes: C25B 1/46 in diaphragm cells
• CPC Class Codes: C25B 9/23 comprising ion-exchange membranes in or on which electrode material is embedded

Abstract

An electrolytic cell has a gas-liquid permeable porous electrode layer on a cation exchange membrane. The electrode layer is formed by printing a paste comprising an electrode powder on the surface of said cation exchange membrane by a screen printing process and bonding it.

Claims

1. An electrolytic cell having a gas-liquid permeable porous electrode layer on a cation exchange membrane, wherein said electrode layer is formed by screen printing a paste comprising a hydrophobic polymer and an electrode powder on the surface of said cation exchange membrane, wherein said electrode powder is a metal, an electroconductive metal oxide, or an electroconductive reduced metal oxide powder, and bonding said paste to said membrane by the application of heat and pressure.

2. The electrolytic cell according to claim 1 wherein said electrode layer is an anode and said electrode powder for said anode is made of a platinum group metal or an electric conductive oxide thereof or an electric conductive reduced oxide thereof.

3. The electrolytic cell according to claim 1 wherein said electrode layer is a cathode and said electrode powder for said cathode is made of a platinum group metal or an electric conductive oxide thereof or an iron group metal.

4. The electrolytic cell according to claim 1 wherein said electrode layer has a porosity of 10 to 99% and a thickness of 0.1 to 100μ

.

5. The electrolytic cell according to claim 1 or 3 wherein said screen has a mesh number of 10 to 2400 and a thickness of 2 mm to 4μ

.

6. The electrolytic cell according to claim 1, 3 or 4 wherein said cation exchange membrane is made of a fluorinated polymer having carboxylic acid groups or sulfonic acid groups.

7. The electrolytic cell according to claim 6 wherein said cation exchange membrane is made of a copolymer having the units ##STR3## wherein X represents fluorine, chlorine or hydrogen atom or --CF₃ ;

X'"'"' represents X or CF₃ (CF₂)_m ;

m represents an integer of 1 to 5;

Y represents the following unit;

##STR4## x, y and z respectively represent an integer of 1 to 10;

Z and Rf represent --F or C₁ -C₁₀ perfluoroalkyl group; and

A represents --COOM or --SO₃ M or a functional group which is convertible into --COOM or --SO₃ M by a hydrolysis or a neutralization such as --CN, --COF, --COOR₁, --SO₂ F, --CONR₂ R₃ and --SO₂ NR₂ R₃ and M represents hydrogen or an alkali metal atom;

R₁ represents a C₁ -C₁₀ alkyl group;

R₂ and R₃ represent H or a C₁ -C₁₀ alkyl group.

8. The electrolytic cell according to claim 1, which is used for producing an alkali metal hydroxide and chlorine by an electrolysis of an aqueous solution of an alkali metal chloride.