Oil-containing waste water treating material consisting of modified active carbon

• US 4,320,011 A
• Filed: 08/07/1980
• Issued: 03/16/1982
• Est. Priority Date: 08/13/1979
• Status: Expired due to Term

• Current Assignee: Mitsubishi Rayon Company Limited (Mitsubishi Chemical Holdings Corporation)
• Original Assignee: Mitsubishi Rayon Company Limited (Mitsubishi Chemical Holdings Corporation)
• Inventors: Sato, Hiroshi, Shigeta, Sadaaki, Takenaka, Yasuo
• Primary Examiner(s): Cintins, Ivars C.
• Application Number:
  US06/176,052
• Time in Patent Office: 586 Days
• Field of Search: 210/679, 210/680, 210/694, 210/924, 210/502, 210/506, 252/428, 252/438, 252/444
• US Class Current: 210/694
• CPC Class Codes: B01D 17/0202 by ab- or adsorption
• CPC Class Codes: C02F 1/681 by addition of solid materials for removing an oily layer on water

Abstract

An oil-containing waste water treating material, comprising an active carbon upon whose surface is chemically bonded at least one nitrogenous compound which is an amine or a quaternarized derivative thereof.

Claims

1. An oil-containing waste water treating material, comprising:

an active carbon upon whose surface is chemically bonded at least one nitrogenous vinyl compound having at least one structure selected from the group consisting of amine structures, and quaternary ammonium structures.

2. The treating material of claim 1, wherein said nitrogenous vinyl compound is dimethylaminoethyl methacrylate, diethylaminoethyl methacrylate, 2-hydroxy-3-methacryloxypropyltrimethylammonium chloride, methacrylic acid dimethylaminoethylmethyl chloride, 2-vinylpyridine or 4-vinylpyridine.

3. The treating material of claim 1, which is a modified active carbon wherein at least one said nitrogenous vinyl compound is graft polymerized on the surface of said active carbon.

4. The treating material of claim 1, which is a modified active carbon obtained by graft polymerizing a nitrogenous vinyl compound having an amine structure onto the surface of said active carbon and then treating said active carbon with a halide.

5. The treating material of claim 1, which is a modified active carbon obtained by graft polymerizing a nitrogenous vinyl compound having an amine structure onto the surface of said active carbon, treating said active carbon subjected to graft polymerization with a halide, reacting a nitrogenous vinyl compound having an amine structure with the halide treated active carbon and then treating the product obtained with a halide.

6. The treating material of claim 4 or 5 wherein said halide is hydrochloric acid, methyl iodide, methyl chloride or n-butyl bromide.

7. A method of removal of oil fractions from oil-containing waste water, comprising:

contacting said waste water with a bed of active carbon upon whose surface is chemically bonded at least one nitrogenous vinyl compound having at least one structure selected from the group consisting of amine structures, and quaternary ammonium structures.