Carbon dioxide measurement system

• US 4,321,545 A
• Filed: 03/13/1980
• Issued: 03/23/1982
• Est. Priority Date: 03/13/1980
• Status: Expired due to Term

• Current Assignee: James N. Cameron
• Original Assignee: James N. Cameron
• Inventors: Cameron, James N.
• Primary Examiner(s): Tokar, Michael J.
• Application Number:
  US06/130,086
• Time in Patent Office: 740 Days
• Field of Search: 324/439, 324/450
• US Class Current: 324/442
• CPC Class Codes: G01N 27/021 before and after chemical transformation of the material
• CPC Class Codes: G01N 27/06 of a liquid involving electrolysis G01N27/26

Abstract

A method and apparatus wherein a sample of gas or fluid containing carbon dioxide in the form of dissolved carbon dioxide gas, bicarbonate ion, and/or carbonate ion is injected into an extraction chamber provided with an acid extracting fluid. A carbon dioxide-free gas stream is passed through the extraction chamber in order to carry the dissolved CO₂ gas formed from bicarbonate and carbonate ions, as well as that already present, onto a spiral absorbing column, wherein a dilute alkaline solution absorbs the CO₂ with a resulting change in electrical conductivity of the alkaline solution. The system disclosed provides electrical means for measuring the conductivity difference thus produced, means for conversion of this difference to an appropriately coded electrical signal, and means for providing a direct display of the sample concentration. Means are provided for indicating when a sample is being processed by the apparatus, and for holding the displayed concentration until manually re-set. Two types of extraction chambers are disclosed, one for gas and non-foaming liquids, and a second for foaming liquids such as blood. The method and apparatus is suitable for use with samples containing as little as 20 nano-Moles (10^-9 Moles) of carbon dioxide in all forms.

Claims

1. A method of obtaining consistent and reproducible results from a CO₂ measuring system whose detection is based on the principal of electrical conductivity change in an alkaline solution, wherein temperature fluctuations, small sample problems, and foaming of liquids are prone to cause error, comprising the steps of:

(a) injecting a sample into an extraction chamber, wherein

(b) an acid solution is employed to convert bicarbonate ion, carbonate ion, and carbonic acid, the usual chemical formulae for which are HCO₃^-, CO₃^2-, and H₂ CO₃, respectively, to dissolved CO₂ gas,

(c) removal of the CO₂ from the extraction chamber by a carrier gas stream containing no CO₂,

(d) employing the carrier gas stream to conduct the removed CO₂ onto a column wherein it is brought into contact with an alkaline solution, which re-absorbs CO₂,

(e) employing the same carrier gas stream further to circulate the alkaline absorbing fluid first through one cell of a detector, then through a second cell of a detector after absorption of the CO₂ has occurred,

(f) employing analog and digital circuitry to provide an automatically switched counting period, at the end of which the sample concentration is directly displayed.

2. Apparatus for the application of the method of conductivity difference measurement to the measurement of the total carbon dioxide content of a gas or fluid, wherein an acid medium is employed to remove all CO₂ from a solution into a carrier gas stream, and an alkaline absorbing fluid is used to re-absorb the CO₂ from the carrier gas stream and thus produce an electrical conductivity difference in the alkaline absorbing fluid, comprising:

(a) an integrated piece of apparatus for conducting the entire process following the single step of injecting a sample,

(b) the combination of acid extraction chamber and alkaline absorber column and bath driven by a carrier gas stream, this stream providing the circulating action in both extraction chamber and alkaline absorber column and detectors,

(c) the combination of AC oscillator circuitry for detecting the difference in electrical conductivity produced as a result of a sample being processed, and digital circuitry to start and stop integration of the signal from a sample automatically and to scale the intergrated output in a visual display so as to provide a direct measurement of the concentration in the sample,

(d) the provision of extraction chambers to be used with gas, non-foaming liquids, and with foaming liquids such as blood.