Natural gas processing

• US 4,322,225 A
• Filed: 11/04/1980
• Issued: 03/30/1982
• Est. Priority Date: 11/04/1980
• Status: Expired due to Term

• Current Assignee: Phillips Petroleum Company (ConocoPhillips)
• Original Assignee: Phillips Petroleum Company (ConocoPhillips)
• Inventors: Gray, Michael L., Bellinger, Robert M.
• Primary Examiner(s): Adee, John
• Application Number:
  US06/203,922
• Time in Patent Office: 511 Days
• Field of Search: 55/25, 55/27, 55/44, 55/55, 55/57, 55/48
• US Class Current: 95/256
• CPC Class Codes: F25J 2200/04 in a dual pressure main column system
• CPC Class Codes: F25J 2200/70 Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
• CPC Class Codes: F25J 2200/78 Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2240/02 Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
• CPC Class Codes: F25J 2270/04 Internal refrigeration with work-producing gas expansion loop
• CPC Class Codes: F25J 2270/90 External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more

Abstract

In accordance with the present invention a normally gaseous feed mixture, having a temperature of essentially atmospheric temperature and a pressure substantially above atmospheric pressure, is cooled to a lower temperature sufficient to liquefy a portion of the feed mixture, the cooled feed mixture is separated into a first vapor phase and a first liquid phase, the first vapor phase is further cooled to a temperature sufficiently low to liquefy a portion of the first vapor phase, the cooled first vapor phase is separated into a second vapor phase and a second liquid phase, the pressures of the first liquid phase and the second liquid phase are separately reduced to a pressure sufficiently low to flash portions of the liquid phases, the reduced-pressure, first liquid phase is introduced into the lower portion of a third separation step while the reduced-pressure, second liquid phase is introduced into the upper portion of the third separation step, in which the reduced-pressure, first and second liquid phases are simultaneously separated to produce a third vapor phase and a third liquid phase, at least a portion of the second vapor phase is expanded to a pressure approximately the same as the reduced pressures of the first and second liquid phases but sufficiently low to liquefy a portion of the second vapor phase, the expanded second vapor phase, the remaining portion of the second vapor phase, if any, and the third vapor phase are introduced into the upper portion of a fourth separation step and the third liquid phase is introduced into the fourth separation step at a point below the previously mentioned upper portion of the fourth separation step and the streams introduced into the fourth separation step are simultaneously separated to produce a fourth liquid product enriched in higher boiling components and a fourth vapor product enriched in lower boiling components.

Claims

1. A method for separating higher boiling constituents from a normally gaseous feed mixture containing lower boiling constituents and said higher boiling constituents, at a temperature near atmospheric temperature and at a first elevated pressure substantially above atmospheric pressure, comprising:

(a) cooling said feed mixture, in a first cooling stage, to a first reduced temperature sufficiently low to liquefy a portion of said feed mixture;

(b) separating the thus cooled feed mixture, in a first separation step, into a first vapor stream and a first liquid stream;

(c) cooling said first vapor stream, in a second cooling stage, to a second reduced temperature sufficiently low to liquefy a portion of said first vapor stream;

(d) separating the thus cooled first vapor stream, in a second separation step, into a second vapor stream and a second liquid stream;

(e) reducing the pressure of said first liquid stream, in a first pressure reduction step, to a second elevated pressure substantially above atmospheric pressure but sufficiently low to flash a portion of said first liquid stream;

(f) reducing the pressure of said second liquid stream, in a second pressure reduction step, to a third elevated pressure substantially above atmospheric pressure and approximately equal to said second elevated pressure but sufficiently low to flash a portion of said second liquid stream;

(g) simultaneously separating the thus reduced-pressure, first liquid stream, in a lower portion of a third separation step, and the thus reduced-pressure, second liquid stream, in an upper portion of said third separation step, into a third vapor stream and a third liquid stream;

(h) expanding at least a portion of said second vapor stream, in an expansion stage, to a fourth elevated pressure substantially above atmospheric pressure and approximately equal to said second and said third elevated pressures but sufficiently low to liquefy a portion of said at least a portion of said second vapor stream;

(i) simultaneously separating the thus expanded at least a portion of said second vapor stream, the remaining portion, if any, of said second vapor stream and said third vapor stream, in an upper portion of a fourth separation step, and said third liquid stream, in a portion of said fourth separation step below said upper portion of said fourth separation step, into a fourth vapor stream, containing a substantially larger proportion of said lower boiling constituents than said feed mixture, and a fourth liquid stream, containing a substantially larger proportion of said higher boiling constituents than said feed mixture; and

(j) collecting said fourth vapor stream and said fourth liquid stream, respectively, as products of said method.

2. A method in accordance with claim 1 wherein the thus expanded at least portion of the second vapor stream, the remaining portion, if any, of said second vapor stream and the third vapor stream are cooled, in a third cooling stage, to a third reduced temperature sufficiently low to liquefy portions of said expanded at least a portion of the second vapor stream, said remaining portion, if any, of said second vapor stream and said third vapor stream;

the thus cooled said expanded at least a portion of said second vapor stream, said remaining portion, if any, of said second vapor stream and said third vapor stream are separated, in a fifth separation step, into a fifth liquid stream and fifth vapor stream, prior to separation in the fourth separation step, said fifth vapor stream is separated in an uppermost portion of the upper portion of said fourth separation step and said fifth liquid stream is separated in a lowermost portion of said upper portion of said fourth separation step above the portion of said further separation step at which the third liquid stream is separated.

3. A method in accordance with claim 2 wherein at least a portion of the fifth vapor stream is expanded, in a second expansion stage, to a fifth elevated pressure substantially above atmospheric pressure but sufficiently low to liquefy a portion of said at least a portion of said fifth vapor stream, prior to separation of its separation in the fourth separation step, and the thus expanded at least a portion of said fifth vapor stream and the remaining portion, if any, of said fifth vapor stream are separated in the upper most portion of the upper portion of said fourth separation step.

4. A method in accordance with claim 1 wherein liquids separated from the pressure-reduced, second liquid stream, in the third separation step, and vapors separated from the pressure-reduced, first liquid stream, in said third separation step, are passed over an extended contact surface, in said third separation step, and in countercurrent contact with each other while passing over said extended contact surface.

5. A method in acordance with claim 4 wherein the extended contact surface is a fluid-permeable packing.

6. A method in accordance with claim 1, 4 or 5 wherein the second cooling stage comprises passing the fourth vapor stream in indirect heat exchange with the first vapor stream.

7. A method in accordance with claim 2 or 3 wherein the third cooling stage comprises passing the fourth vapor stream in indirect heat exchange with the expanded at least a portion of the second vapor stream, the remaining portion, if any, of the second vapor stream and the third vapor stream and the second cooling stage comprises thereafter passing said fourth vapor stream in indirect heat exchange with the first vapor stream.

8. A method in accordance with claim 1, 4 or 5 wherein at least a portion of the cooling in the first cooling stage comprises passing the fourth vapor stream in indirect heat exchange with at least a portion of the normally gaseous feed mixture, in at least one sequential cooling step.

9. A method in accordance with claim 6 wherein at least a portion of the cooling in the first cooling stage comprises passing the fourth vapor stream in indirect heat exchange with at least a portion of the normally gaseous feed mixture, in at least one sequential cooling exchange step, after passing said fourth vapor stream in indirect heat exchange with the first vapor stream.

10. A method in accordance with claim 7 wherein at least a portion of the cooling in the first cooling stage comprises passing the fourth vapor stream in indirect heat exchange with at least a portion of the normally gaseous feed mixture, in at least one sequential cooling step, after passing said fourth vapor stream in indirect heat exchange with the first vapor stream.

11. A method in accordance with claim 8 wherein at least a second portion of the cooling in the first cooling stage comprises passing at least a portion of the normally gaseous feed mixture in indirect heat exchange with an external refrigerant.

12. A method in accordance with claim 1, 2, 3, 4 or 5 wherein the normally gaseous feed mixture is divided into two portions, a first portion of said two portions is passed in indirect heat exchange with at least one portion of the liquids separating in the fourth separation step and at least a portion of the cooling of the remaining, second portion of said two portions is cooled by passing the same in indirect heat exchange with the fourth vapor stream.

13. A method in accordance with claim 12 wherein the first portion of the two portions of the normally gaseous feed mixture is between about 30 mole % and about 50 mole % of the total of said normally gaseous feed mixture.

14. A method in accordance with claim 1 wherein the energy generated in the expansion stage is utilized to compress the fourth vapor stream prior to the collection of said fourth vapor stream as a product.

15. A method in accordance with claim 1 wherein the normally gaseous feed mixture is a natural gas containing methane and ethane and higher molecular weight hydrocarbons and a major portion of said methane is collected as the fourth vapor stream and a major portion of said ethane and higher molecular weight hydrocarbons is collected as the fourth liquid stream.

16. Apparatus for separating higher boiler constituents from a normally gaseous feed mixture containing lower boiling constituents and said higher boiling constituents, at a temperature near atmospheric temperature and at a first elevated pressure substantially above atmosphermic pressure, comprising:

(a) first cooling means adapted to cool said normally gaseous feed mixture to a first reduced temperature sufficiently low to liquefy a portion of said feed mixture;

(b) first separating means adapted to receive the thus cooled normally gaseous feed mixture and separate said cooled normally gaseous feed mixture into a first vapor stream and a first liquid stream;

(c) second cooling means adapted to cool said first vapor stream to a second reduced temperature sufficiently low to liquefy a portion of said first vapor stream;

(d) second separating means adapted to receive the thus cooled first vapor stream and separate said cooled, first vapor stream into a second vapor stream and a second liquid stream;

(e) first pressure reducing means adapted to reduce the pressure of said first liquid stream to a second elevated pressure substantially above atmospheric pressure but sufficiently low to flash a portion of said first liquid stream;

(f) second pressure reducing means adapted to reduce the pressure of said second liquid stream to a third elevated pressure substantially above atmospheric pressure and approximately equal to said second elevated pressure but sufficiently low to flash a portion of said second liquid stream;

(g) third separating means adapted to simultaneously receive the thus reduced-pressure, first liquid stream, in a lower portion of said third separating means, and receive the thus reduced-pressure, second liquid stream, in an upper portion of said third separating means, and to simultaneously separate the thus received reduced-pressure, first liquid stream and the thus received reduced-pressure, second liquid stream into a third vapor stream and a third liquid stream;

(h) first expansion means adapted to expand at least a portion of said second vapor stream to a fourth elevated pressure substantially above atmospheric pressure and approximately equal to said second and said third elevated pressures but sufficiently low to liquefy a portion of said at least a portion of said second vapor stream;

(i) fourth separating means adapted to simultaneously receive the thus expanded at least a portion of the second vapor stream, the remaining portion, if any, of the second vapor stream and said third vapor stream in an upper portion thereof, and said third liquid stream in a portion thereof below said upper portion thereof and to simultaneously separate said expanded at least a portion of said second vapor stream, said remaining portion, if any, of said second vapor stream, said third vapor stream and said third liquid stream into a fourth vapor stream and a fourth liquid stream;

(j) means for collecting said fourth vapor stream as a product; and

(k) means for collecting said fourth liquid stream as a product.

17. Apparatus in accordance with claim 16 in which additionally includes a third cooling means adapted to cool the thus expanded at least a portion of the second vapor stream, the remaining portion, if any, of the second vapor stream and the third vapor stream to a third reduced temperature sufficiently low to liquefy a portion of said expanded at least a portion of said second vapor stream, said remaining portion, if any, of said second vapor stream and said third vapor stream and a fifth separation means adapted to receive the thus cooled expanded at least a portion of said second vapor stream, said remaining portion, if any, of said second vapor stream and separate said expanded at least a portion of said second vapor stream, said remaining portion, if any, of said second vapor stream and said third vapor stream into a fifth vapor stream and a fifth liquid stream, and the fourth separating means is adapted to receive said fifth vapor stream in an uppermost portion of the upper portion of said fourth separation means and to receive said fifth liquid stream in a lowermost portion of said upper portion of said fourth separation means located above the portion of the fourth separation means at which the third liquid stream is received.

18. Apparatus in accordance with claim 17 which additionally includes second expansion means adapted to receive at least a portion of the fifth vapor stream and expand said at least a part of said fifth vapor stream to a fifth elevated pressure substantially above atmospheric pressure but sufficiently low to liquefy a portion of said at least a portion of said fifth vapor stream and the fourth separation means is adapted to receive the thus expanded at least a portion of the fifth vapor stream and the remaining portion, if any, of the fifth vapor stream in the uppermost portion of the upper portion of said fourth separation step.

19. Apparatus in accordance with claim 16 wherein the third separation means includes an extended contact surface between the point of reception of the reduced pressure first liquid stream and the point of reception of the reduced pressure second liquid stream.

20. Apparatus in accordance with claim 19 wherein the extended contact surface is a fluid-permeable packing means.

21. Apparatus in accordance with claim 16, 19 or 20 wherein the second cooling means is adapted to pass the fourth vapor stream in indirect heat exchange with the first vapor stream.

22. Apparatus in accordance with claim 17 or 18 wherein the third cooling means is adapted to pass the fourth vapor stream in indirect heat exchange with the expanded at least a portion of the second vapor stream, the remaining portion, if any, of the second vapor stream and the third vapor stream, and the second cooling means is adapted to pass the fourth vapor stream in indirect heat exchange with the first vapor stream after said passage of said fourth vapor stream through said third cooling means.

23. Apparatus in accordance with claim 16 wherein the first cooling means includes at least one heat exchange means adapted to pass said fourth vapor stream in indirect heat exchange with at least a portion of the normally gaseous feed mixture.

24. Apparatus in accordance with claim 23 wherein the first cooling means additionally includes at least one additional heat exchange means adapted to pass an external refrigerant in indirect heat exchange with the normally gaseous feed mixture.

25. Apparatus in accordance with claim 16 wherein the first cooling means includes at least one heat exchange means adapted to pass at least a portion of the normally gaseous feed mixture in indirect heat exchange with a portion of liquids separating in the fourth separator means.

26. Apparatus in accordance with claim 16 wherein the expander means is an expander portion of a turbo expander-compressor means.

27. Apparatus in accordance with claim 26 wherein the compressor portion of the turbo expander-compressor means is adapted to compress the fourth vapor stream prior to collection of said fourth vapor stream by the means for collecting said fourth vapor stream as a product.

28. Apparatus in accordance with claim 24 wherein the first and the second expansion means are expander portions of a first and a second turbo expander-compressor, respectively.

29. Apparatus in accordance with claim 28 wherein the compressor portions of the first and second turbo expander-compressors are adapted to sequentially compress said fourth vapor prior to the collection of said fourth vapor stream by the means for collecting said fourth vapor stream as a product.