Polyamide-polyethylene laminates

• US 4,322,480 A
• Filed: 12/29/1980
• Issued: 03/30/1982
• Est. Priority Date: 12/29/1980
• Status: Expired due to Fees

• Current Assignee: Allied Corp. (Honeywell International Inc.)
• Original Assignee: Allied Chemical Corporation (Honeywell International Inc.)
• Inventors: Wilson, George S., Tuller, Harold W., Schulze, Stephen R.
• Primary Examiner(s): Robinson, Ellis P.
• Application Number:
  US06/220,884
• Time in Patent Office: 456 Days
• Field of Search: 428/475.8, 428/476.1, 428/523, 428/476.3, 428/476.6, 428/476.9
• US Class Current: 428/476.1
• CPC Class Codes: B32B 2323/043 HDPE, i.e. high density polyethylene
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 27/34 comprising polyamides
• CPC Class Codes: Y10T 428/31743 Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/31746 Polymer of monoethylenically unsaturated hydrocarbon
• CPC Class Codes: Y10T 428/3175 Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/31754 Natural source-type polyamide
• CPC Class Codes: Y10T 428/31757 Polymer of monoethylenically unsaturated hydrocarbon
• CPC Class Codes: Y10T 428/31938 Polymer of monoethylenically unsaturated hydrocarbon

Abstract

A laminate structure comprising at least one layer of a polyamide and at least one layer of polyethylene containing from 0.1 to 20 percent based on the weight of the polyethylene of oxidized high density polyethylene.

Claims

1. A laminate structure comprised of:

at least one layer of a polyamide; and

at least one layer of polyethylene containing from 0.1 to 20% based on the weight of the polyethylene of oxidized polyethylene.

2. The laminate structure of claim 1 wherein the polyethylene layer contains from 0.1 to 10% based on the weight of the polyethylene of oxidized polyethylene.

3. The laminate structure of claim 1 wherein the polyethylene layer has a specific gravity of 0.91 to 0.965.

4. The laminate structure of claim 1 wherein the polyethylene layer is high density polyethylene.

5. The laminate structure of claim 4 wherein the polyethylene layer has a specific gravity of 0.94 to 0.965.

6. The laminate structure of claim 4 wherein the high density polyethylene layer contains from 3 to 7% based on the weight of the high density polyethylene of oxidized polyethylene.

7. The laminate structure of claim 1 wherein the oxidized polyethylene has a specific gravity of from 0.915 to 0.99.

8. The laminate structure of claim 7 wherein the oxidized polyethylene has a specific gravity of from 0.97 to 0.99.

9. The laminate structure as recited in claim 1 wherein the oxidized polyethylene is oxidized high density polyethylene.

10. The laminate structure of claim 1 wherein the oxidized polyethylene has a molecular weight of from about 500 to about 8,000.

11. The laminate structure of claim 10 wherein the oxidized polyethylene has an acid number of from about 10 to 40 mg KOH/gm of oxidized polyethylene.

12. The laminate structure of claim 4 wherein the oxidized polyethylene has a molecular weight of from about 5000 to 6000 and an acid number from about 15 to 30 mg KOH/gr of oxidized polyethylene.

13. The laminate structure of claim 4 wherein the polyamide is polyepsiloncaprolactam or polyhexamethylene adipamide.

14. The laminate structure of claim 4 wherein the polyamide is polyepsiloncaprolactam.

15. The laimate structure as recited in claim 4 wherein at least one layer of the polyamide has about 60 to 97 mol percent of its end groups as amine end groups.

16. The laminate as recited in claim 15 wherein the polyamide contains amine and acid terminal groups, wherein at least 1.5 times as many amine end groups than acid groups are present.

17. A laminate structure composed of:

at least one layer of polyepsilon caprolactam;

at least one layer of high density polyethylene containing from 3 percent to 7 percent, based on the weight of the high density polyethylene, of oxidized poyethylene.

18. The laminated structure of claim 17 wherein the polyepsilon caprolactam has amine and acid terminal groups, wherein at least 1.5 times as many amine end groups than acid end groups are present.

19. The laminated structure as recited in claims 17 or 18 wherein the oxidized polyethylene has a molecular weight from 500 to 8000 and an acid number from 10 to 40 mg KOH/gram of oxidized polyethylene.

20. A laminate structure as recited in claim 19 wherein the oxidized polyethylene is high density polyethylene.

21. A laminate structure comprised of:

at least one layer comprised of at least 50 wt. %, based on the total weight of the layer, of a polyamide, and

at least one layer of high density polyethylene containing from 0.1 to 10%, based on the weight of the high density polyethylene of oxidized high density polyethylene.

22. The laminate structure of claim 21 wherein the polyamide is polyepsiloncaprolactam or polyhexamethylene adipamide.

23. The laminate structure of claim 21 wherein at least 75% polyamide is present.

24. The laminate structure as recited in claim 21 wherein the layer of polyamide contains at least 50 wt. percent, based on the total weight of the layer, of a polyamide and a corresponding amount of high density polyethylene containing from 0.1 to 10% based on the weight of the high density polyethylene of oxidized high density polyethylene.