Electric double layer capacitor

• US 4,327,400 A
• Filed: 01/03/1980
• Issued: 04/27/1982
• Est. Priority Date: 01/10/1979
• Status: Expired due to Term

• Current Assignee: Matsushita Electric Industrial Company Limited (Panasonic Holdings Corporation)
• Original Assignee: Matsushita Electric Industrial Company Limited (Panasonic Holdings Corporation)
• Inventors: Mori, Hajime, Muranaka, Takayoshi
• Primary Examiner(s): JAMES, ANDREW
• Application Number:
  US06/109,406
• Time in Patent Office: 845 Days
• Field of Search: 361/433, 29/570
• US Class Current: 361/502
• CPC Class Codes: H01G 11/04 Hybrid capacitors
• CPC Class Codes: H01G 11/28 arranged or disposed on a current collector; Layers or phases between electrodes and current collectors, e.g. adhesives
• CPC Class Codes: H01G 11/38 Carbon pastes or blends; Binders or additives therein
• CPC Class Codes: H01G 11/52 Separators
• CPC Class Codes: H01G 11/70 characterised by their structure
• CPC Class Codes: H01G 11/80 Gaskets; Sealings
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors

Abstract

An electric double layer capacitor comprising a pair of polarization electrodes and an electrolyte disposed in-between and utilizing an electric double layer formed at the interface between the polarization electrodes and the electrolyte, wherein the polarization electrodes comprise a carbon electrode material and polyvinylpyrrolidone as a binder thereof; and therefore adherence, conductivity and a molding characteristic of the carbon electrode material are increased thereby improving characteristics as the capacitive device and reliability of the electric double layer capacitor.

Claims

1. An electric double layer capacitor comprising:

a pair of polarization electrodes each electrode including a conducting member formed from an expanded metal sheet with a number of expanded holes, and a carbon electrode material including active carbon and a polyvinyl pyrrolidone binder; and

a separator impregnated with an electrolyte and disposed between said polarization electrodes.

2. An electric double layer capacitor in accordance with claim 1 wherein said separator includes a composite porous sheet formed from nonwoven fabrics selected from the group consisting of polyethylene, polypropylene and polyester, and a cellulose coating layer thereon.

3. An electric double layer capacitor in accordance with claim 1 wherein said expanded metal sheet is an aluminum sheet having an opening rate of 40-60% and said expanded holes have a size of 0.5-1.0 mm in a small width and 1.0-2.0 mm in a large width.

4. An electric double layer capacitor in accordance with claim 1 wherein said electrolyte is a mixed solvent of propylene carbonate, γ

-butyrolactone and tetraethylammonium perchlorate.

5. An electric double layer capacitor in accordance with claim 1 further comprising internal lead wires of high purity soft aluminum for attaching to said conducting members by pins.

6. An electric double layer capacitor in accordance with claim 4 wherein said electrolyte is a mixed solvent comprising propylene carbonate of 5-30 wt %, γ

-butyrolactone of 70-90 wt % and tetraethylammonium perchlorate of 5-20 wt %.

7. An electric double layer capacitor in accordance with claim 5 further comprising external lead wires of a solderable metal welded to said internal lead wires.

8. An electric double layer capacitor in accordance with claim 7 further comprising

a casing for encapsulating said pair of polarization electrodes, said pair of conducting members and said separator in a wound form and impregnated with said electrolyte, and

an elastic rubber material and a sealing resin for sealing an opening of said casing, and

said external lead wires passing through said elastic rubber material and said sealing resin.

9. An electric double layer capacitor in accordance with claim 8 wherein said elastic rubber material is selected from the group consisting of EPT (ethylene propylene terpolymer) and IIR (isobutylene-isoprene rubber).

10. An electric double layer capacitor in accordance with claim 8 or 9 wherein said electric rubber material has a protruded portion at the lower part thereof disposed apart from said wound polarization electrodes and the internal wall of said casing.

11. An electric double layer capacitor in accordance with claim 8 wherein said casing has thinner portions near bottom edges thereof.

12. An electric double layer capacitor in accordance with claim 8 wherein said sealing resin is selected from the group consisting of an epoxy resin, an acrylic acid resin and a silicone resin.

13. An electric double layer capacitor in accordance with claim 8 wherein welded portions of said internal and said external lead wires are buried in said sealing resin.

14. An electric double layer capacitor in accordance with claim 8 wherein said sealing resin seals said opening of said casing and said elastic rubber material is disposed between said wound polarization electrodes and said sealing resin.

15. An electric double layer capacitor in accordance with claim 8 further comprising a cover tube for covering said casing, wherein said sealing resin seals an opening part of said cover tube.