Self-bonding silicone rubber compositions

• US 4,329,273 A
• Filed: 05/02/1980
• Issued: 05/11/1982
• Est. Priority Date: 03/07/1978
• Status: Expired due to Term

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Hardman, Bruce B., Dujack, George M.
• Primary Examiner(s): Marquis, Melvyn I.
• Application Number:
  US06/145,944
• Time in Patent Office: 739 Days
• Field of Search: 528/15, 528/18, 528/31, 528/32, 528/33, 528/42, 528/43, 260/37 SB
• US Class Current: 524/862
• CPC Class Codes: C08G 77/12 containing silicon bound to hydrogen C08G77/045 takes precedence
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08G 77/24 halogen-containing groups
• CPC Class Codes: C08G 77/70 Siloxanes defined by use of the MDTQ nomenclature
• CPC Class Codes: C08L 2666/44 Silicon-containing compounds
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes

Abstract

A self-bonding silicone rubber composition comprising a vinyl-terminated polysiloxane polymer, a hydride siloxane cross-linking agent, a platinum catalyst and as the self-bonding additive, the partial hydrolysis product of an aliphatically unsaturated hydrolyzable alkoxy silane.

Claims

1. A self-bonding silicone rubber composition comprising (A) 100 parts by weight of a base polymer of the formula, ##STR8## where R is selected from the class consisting of monovalent hydrocarbon radicals and halogenated monovalent hydrocarbon radicals, and x is such that the viscosity of the base polymer varies from 100 to 200,000,000 centipoise at 25°

C.;

(B) from 0.5 to 50 parts by weight of a hydride siloxane cross-linking agent;

(C) from 1 to 500 parts per million of platinum catalyst; and

(D) from 0.1 to 5 parts by weight of a self-bonding additive which is the partial hydrolysis product of a compound of the formula,

space="preserve" listing-type="equation">R.sub.a.sup.1 Si (OR.sup.3).sub.4-a

wherein R¹ is an aliphatic unsaturated radical selected from the class consisting of alkenyl radicals and alkynyl radicals of 2 to 8 carbon atoms, R³ is selected from the class consisting of alkyl radicals and cycloalkyl radicals of 1 to 8 carbon atoms and is 1 and wherein the partial hydrolysis product is such that on the average 16 to 49 mole percent of the hydrocarbonoxy groups of said silane are hydrolyzed.

2. The composition of claim 1 wherein 1 to 1.5 parts by weight of self-bonding additive is utilized.

3. The composition of claim 1 wherein R is selected from the class consisting of alkyl radicals, cycloalkyl radicals, aryl radicals and flucroalkyl radicals of 1 to 8 carbon atoms.

4. The composition of claim 1 wherein the hydride siloxane cross-linking agent has the formula, ##STR9## where R⁷ is selected from the class consisting of hydrogen, monovalent hydrocarbon radicals and halogenated monovalent hydrocarbon radicals, R⁴ is a monovalent hydrocarbon radical and y varies such that the polymer has a viscosity in the range of 10 to 500 centipoise at 25°

C.

5. The composition of claim 1 wherein the hydride silixoane cross-linking agent is a resin composed of H R₂⁵ SiO₀.5 units, and SiO₂ units wherein the ratio of the H+R⁵ radicals to Si varies from 1.0 to 1.0, to 2.7 to 1.0 wherein R⁵ is selected from the class consisting of monovalent hydrocarbon radicals and halogenated monovalent hydrocarbon radicals.

6. The composition of claim 1 wherein there is additionally present from 10 to 200 parts by weight of a compound selected from reinforcing fillers, extending fillers, and a vinyl-containing reinforcing resin comprising R⁶ SiO₀.5 units and SiO₂ units, in which from about 2.5 to 10 mole percent of the silicon atoms contain silicon-bonded vinyl groups where R⁶ is a monovalent hydrocarbon radical.

7. The composition of claim 1 wherein the reinforcing filler is selected from the class consisting of fumed silica and precipitated silica.

8. The composition of claim 7 wherein said filler is treated with a treating agent selected from the class consisting of cyclosiloxanes silazanes and mixtures thereof.

9. The composition of claim 1 wherein there is present from 1 to 30 parts by weight of a vinyl-containing polymer of the formula, ##STR10## wherein R⁶ is selected from the class consisting of alkyl radicals, cycloalkyl radicals, aryl radicals and fluoroalkyl radicals of 1 to 8 carbon atoms where z varies such that the viscosity of the polymer varies from 100 to 5,000 centipoise at 25°

C.

10. The composition of claim 1 wherein there is present from 0 to 50 parts by weight of a vinyl-containing silicone resin.