Texturing polymer surfaces by transfer casting

• US 4,329,385 A
• Filed: 12/19/1980
• Issued: 05/11/1982
• Est. Priority Date: 12/19/1980
• Status: Expired due to Fees

• Current Assignee: United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration
• Original Assignee: United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration
• Inventors: Sovey, James S., Banks, Bruce A., Weigand, Albert J.
• Primary Examiner(s): Weisstuch, Aaron
• Application Number:
  US06/218,587
• Time in Patent Office: 508 Days
• Field of Search: 264/22, 264/220, 428/141, 204/192 E, 204/192 EC, 156/643
• US Class Current: 428/141
• CPC Class Codes: A61F 2/0077 Special surfaces of prostheses, e.g. for improving ingrowth A61F2/30767 takes precedence
• CPC Class Codes: B29C 2035/0872 using ion-radiation, e.g. alpha-rays
• CPC Class Codes: B29C 39/026 characterised by the shape of the surface
• CPC Class Codes: B29C 59/16 by wave energy or particle radiation , e.g. infrared heating B29C59/007 takes precedence
• CPC Class Codes: B29D 7/01 Films or sheets
• CPC Class Codes: B29K 2023/00 Use of polyalkenes or derivatives thereof as moulding material
• CPC Class Codes: B29K 2027/12 containing fluorine
• CPC Class Codes: B29K 2075/00 Use of PU, i.e. polyureas or polyurethanes or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2083/00 Use of polymers having silicon, with or without sulfur, nitrogen, oxygen, or carbon only, in the main chain, as moulding material
• CPC Class Codes: B29K 2827/12 containing fluorine
• CPC Class Codes: B29L 2031/7534 Cardiovascular protheses
• CPC Class Codes: Y10T 428/24355 Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]

Abstract

This invention is concerned with fabricating textured surfaces on polymers without altering their surface chemistries.

A surface of a fluorocarbon polymer 10 is exposed to a beam 12 of ions from a source 14 to texture it. The polymer 18 which is to be surface-roughened is then cast over the textured surface 20 of the fluorocarbon polymer. After curing, the cast polymer is peeled off the textured fluorocarbon polymer, and the peeled off surface 22 has a negative replica of the textured surface 20.

The microscopic surface texture provides large surface areas for adhesive bonding. In cardiovascular prosthesis applications the surfaces are relied on for the development of a thin adherent well nourished thrombus.

Claims

1. A method for texturing the surfaces of a polymer without altering the chemistry of the same comprising the steps of

placing a fluorocarbon polymer in a vacuum environment of about 4×

10^-5 torr,

exposing at least one surface of said fluorocarbon polymer to a neutralized beam of ions having an energy between about 200 eV and 2000 eV and an ion beam current density between 0.5 mA/cm² and 1.0 mA/cm² to texture the same,

removing said fluorocarbon polymer from said vacuum environment,

casting a polymer over said textured surface of said fluorocarbon polymer and curing the same, and

separating said cast and cured polymer from said fluorocarbon polymer whereby the surface of said polymer has a negative replica of said textured surface of said fluorocarbon polymer.

2. A method of texturing the surface of a polymer as claimed in claim 1 including

providing a source of argon ions in said vacuum environment, and

positioning said fluorocarbon polymer in the beam of argon ions at a location of about 20 centimeters from said source, said at least one surface being substantially normal to said beam.

3. A method of texturing the surface of a polymer as claimed in claim 2 wherein the argon ion beam is substantially uniform over said at least one surface.

4. A method of texturing the surface of a polymer as claimed in claim 1 wherein the fluorocarbon polymer is first sputtered onto a substrate.

5. A method of texturing the surface of a polymer as claimed in claim 1 wherein said polymer is selected from the group consisting of silicone rubbers, polyurethanes, and polyolefins.

6. A method of texturing the surface of a polymer as claimed in claim 1 including the step of applying a release agent to said textured surface prior to casting said polymer over the same.

7. A polymer article textured according to the process of claim 1.