Plasticizers for polyvinylchloride comprising a reaction product of alkanedicarboxic acid and alkanolether

• US 4,330,452 A
• Filed: 01/14/1980
• Issued: 05/18/1982
• Est. Priority Date: 01/14/1980
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Cook, Frank T.
• Primary Examiner(s): Lilling, Herbert J.
• Application Number:
  US06/111,745
• Time in Patent Office: 855 Days
• Field of Search: 260/31.4 R, 260/30.4 R
• US Class Current: 524/308
• CPC Class Codes: C08K 5/11 of acyclic polycarboxylic acids
• CPC Class Codes: C08L 27/06 Homopolymers or copolymers of vinyl chloride

Abstract

The use of a group of diester compounds that are particularly effective as plasticizers in polyvinylchloride-resin formulations and articles made therefrom. These compounds are the diesters of alkanedicarboxylic acids and alkanolethers. They are prepared by the direct esterification reaction of dicarboxylic acids with alkanolethers or by the trans esterification reaction of diesters with the corresponding alkanolethers.

Claims

1. An article comprising a body, at least a portion of which includes a fused polyvinylchloride polymer and a plasticizer which is a diester reaction product formed by reacting an alkanedicarboxylic acid with an alkanolether, wherein the alkanolether is 2-hydroxyethylmethyl ether, 2-hydroxyethylethyl ether, 2-hydroxyethylpropyl ether, 2-hydroxyethylisopropyl ether, 2-hydroxyethyltertiarybutyl ether, 2-hydroxyethyl-2'"'"'-methoxyethyl ether, 2-hydroxyethyl-2'"'"'-ethoxyethyl ether, 2-hydroxyethyl-2'"'"'-propoxyethyl ether, 2-hydroxyethyl-2'"'"'-isopropoxyethyl ether, 2-hydroxyethyl-2'"'"'-tertiary-butoxyethyl ether, or a mixture thereof.

2. The article of claim 1 wherein the alkanedicarboxylic acid is dodecanedicarboxylic acid.

3. The article of claim 2 wherein the ratio of the plasticizer is between about ten and about one-hundred parts by weight per hundred parts by weight of polyvinylchloride polymer.

4. The article of claim 3 wherein a stabilizer is included with a ratio of between about one part and about four parts per hundred parts of polyvinylchloride polymer by weight.