Method for increasing recycling life of non-aqueous cells

• US 4,331,743 A
• Filed: 09/02/1980
• Issued: 05/25/1982
• Est. Priority Date: 09/02/1980
• Status: Expired due to Term

• Current Assignee: Duracell Incorporated (Berkshire Hathaway Incorporated)
• Original Assignee: Duracell International Incorporated (Berkshire Hathaway Incorporated)
• Inventors: Bowden, William L., Dey, Arabinda N.
• Primary Examiner(s): Walton, Donald L.
• Application Number:
  US06/182,912
• Time in Patent Office: 630 Days
• Field of Search: 429/50, 429/196, 429/194, 429/199, 429/49
• US Class Current: 429/50
• CPC Class Codes: H01M 10/36 Accumulators not provided for in groups H01M10/05-H01M10/34
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02P 70/50 Manufacturing or production processes characterised by the final manufactured product
• CPC Class Codes: Y02W 30/84 Recycling of batteries or fuel cells

Abstract

A method for increasing the recycling life of an electrochemical cell containing a lithium (or other active metal subject to dendritic plating) anode and a clovoborate salt or other salt, which forms soluble oxidizing agents at elevated charging voltages, comprising the step of charging the cell at a potential above normal charging voltage whereby said soluble oxidizing agents are formed.

Claims

1. A method for improving the cycling life of a rechargeable cell containing an active anode metal subject to dendritic plating on charging, a porous cathode, an electrolyte solvent and a dissolved salt which is stable at charging voltages and capable of forming soluble oxidizing moieties, at higher voltages;

which moieties are capable of scavenging and solvating insoluble electrically disconnected anode metal and anode metal in insoluble compounds within said cell and said salt being further capable of being recycled thereby;

said method comprising charging said cell at a voltage above said charging voltage and sufficiently high whereby said salt forms said soluble oxidizing moieties at said cathode which scavenge and solvate insoluble electrically disconnected anode metal and anode metal in insoluble compounds with said salt being recycled thereby.

2. The method of claim 1 wherein said salt is a clovoborate salt.

3. The method of claim 2 wherein said clovoborate salt has an anion with the formula (B_m X_n)^-k wherein m, n and k are integers with m ranging from 6-20, n ranging from 6-18 and k ranging from 1-4, B is boron and X is selected from the group consisting of H, F, Cl, Br, I, OH and combinations thereof.

6. The method of claim 3 wherein said clovoborate salt comprises Li₂ B₁₀ Cl₁₀.

7. The method of claim 2 wherein said active anode metal comprises an alkali or alkaline earth metal.

8. The method of claim 7 wherein said active anode metal is lithium.

9. The method of claim 8 wherein said voltage is at least 3.5 volts.

10. The method of claim 9 wherein said porous cathode is comprised of porous carbon.

4. A method for improving the cycling life of a rechargeable cell containing an active anode metal subject to dendritic plating on charging, a porous cathode, an electrolyte solvent and a dissolved salt which is stable at charging voltages;

said method comprising charging said cell at a voltage sufficiently high whereby said salt forms soluble oxidizing moieties at said cathode which scavenge and solvate insoluble electrically disconnected anode metal and anode metal in insoluble compounds with said salt being recycled thereby, wherein said salt is a clovoborate salt which has an anion with the formula (B_m X_n)^-k wherein m, n and k are integers with m ranging from 6-20, n ranging from 16-18 and k ranging from 1-4, B is boron and X is selected from the group consisting of H, F, Cl, Br, I, OH and combinations thereof, and wherein said electrolyte solvent consists essentially of SO₂.

5. The method of claim 4 wherein said clovoborate salt comprises an electrolyte salt for said cell.

11. A method for improving the cycling life of a rechargeable non-aqueous inorganic cell comprising a lithium anode, a porous cathode, an inorganic sulfur dioxide electrolyte solvent and a clovoborate salt comprising the step of charging said cell at a voltage above 3.5 volts for at least part of the time for said charging.

12. The method of claim 11 wherein said sulfur dioxide is the sole electrolyte solvent.

13. The method of claim 12 wherein said clovoborate salt comprises the electrolyte salt for said cell.

14. The method of claim 13 wherein said clovoborate salt comprises a lithium cation and an anion having the formula (B_m X_n)^-k wherein m, n and k are integers with m ranging from 6-20, n ranging from 6-18 and k ranging from 1-4, B is boron and X is selected from the group consisting of H, F, Cl, Br, I, OH and combinations thereof.

15. The method of claim 14 wherein said clovoborate salt comprises Li₂ B₁₀ Cl₁₀.

16. The method of claim 15 wherein said porous cathode is comprised of porous carbon.