Liquid or pasty thermosetting adhesive which can be pre-gelled and which is based on epoxide resin, and the use of this adhesive

• US 4,332,713 A
• Filed: 10/29/1980
• Issued: 06/01/1982
• Est. Priority Date: 11/09/1979
• Status: Expired due to Term

• Current Assignee: CIBA Specialty Chemicals
• Original Assignee: Ciba-Geigy Corporation (Novartis Ag)
• Inventors: Lehmann, Hans
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): Lipman, Bernard
• Application Number:
  US06/202,021
• Time in Patent Office: 580 Days
• Field of Search: 260/29.8, 260/13, 525/58, 525/119, 525/120, 525/423, 525/110, 525/113, 156/328, 156/330
• US Class Current: 156/328
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/28 Non-macromolecular organic substances
• CPC Class Codes: C09J 163/00 Adhesives based on epoxy resins; Adhesives based on derivatives of epoxy resins

Abstract

A liquid or pasty thermosetting adhesive which can be pre-gelled, which is suitable for the bonding of moulded parts or for the sealing of folded seams, and which contains (a) a liquid epoxide resin having on average more than one epoxide group in the molecule, and (b) a latent epoxide curing agent insoluble in the epoxide resin, the adhesive being characterized in that it also contains (c) in an amount of 5 to 50 percent by weight relative to the epoxide resin, at least one halogen-free thermoplast in powder form, which is insoluble in the epoxide resin at room temperature, and which has a softening point of between 60° and 160° C., such as a polyethylene, a polypropylene or an ethylene/acrylic acid/acrylate terpolymer.

Claims

1. A liquid or pasty thermosetting adhesive, which can be pre-gelled and which is based on epoxide resin, which consists essentially of

(a) a liquid epoxide resin having on average more than one epoxide group in the molecule or a mixture of said liquid epoxide resins,

(b) an effective amount of a latent curing agent for epoxide resin, which is insoluble in the epoxide resin at room temperature, and which is selected from the group consisting of dicyandiamide, melamine, guanamine, polycarboxylic acid polyhydrazides, carboxylic acid imides and imidazole derivatives, and

(c) 5 to 50% by weight, relative to the epoxide resin, of at least one halogen-free thermoplast in powder form, which is insoluble in the epoxide resin at room temperature, and which thermoplast has a softening point of between 60°

and 160°

C.

2. An adhesive according to claim 1, which contains as thermoplast:

polyethylene, polypropylene or an ethylene/acrylic acid/acrylate terpolymer.

3. An adhesive according to claim 1, which contains as thermoplast:

polyamide, ethyl cellulose, polyvinyl formal or polyvinyl butyral.

4. An adhesive according to any claim 1, which contains at least one thermoplast in an amount of 5 to 20 percent by weight, relative to the epoxide resin.

5. An adhesive according to claim 1, which contains dicyandiamide as a curing agent for epoxide resins.

6. An adhesive according to claim 1, which contains, as liposoluble additive, limonene, dipentene or turpentine oil, in an amount of 1-10 percent by weight relative to the adhesive.

7. An adhesive according to claim 1, which contains a liquid epoxide resin mixture, 1-10 percent by weight, relative to the adhesive, of limonene, 5-20 percent by weight, relative to the epoxide resin, of polyvinylbutyral powder, 5-20 percent by weight, relative to the epoxide resin, of dicyandiamide, 1-20 percent by weight, relative to the epoxide resin, of a thixotropic agent, 1-20 percent by weight, relative to the epoxide resin, of an accelerator, and 1-100 percent by weight, relative to the epoxide resin, of a filler.

8. A process for the bonding of moulded parts or for the sealing of folded seams, which process comprises applying to the surfaces to be bonded or to the folded seams to be sealed an adhesive according to claim 1;

heating the adhesive to a temperature higher than the melting temperature of the thermoplast, and holding it at this temperature until it is able, on being cooled to room temperature, to form a non-tacky coating dry to the touch, the coated parts then being cooled, and the adhesive subsequently cured by heating after the parts have been joined together.

9. A process according to claim 8, in which polyethylene powder having a melting range of 116°

-119°

C. is added as thermoplast to the adhesive, and the pre-gelling is effected for 10-30 seconds at about 180°

C.