Sintered compact for a machining tool and a method of producing the compact

• US 4,334,928 A
• Filed: 02/08/1980
• Issued: 06/15/1982
• Est. Priority Date: 12/21/1976
• Status: Expired due to Term

• Current Assignee: Sumitomo Electric Industries Limited (Sumitomo Corporation)
• Original Assignee: Sumitomo Electric Industries Limited (Sumitomo Corporation)
• Inventors: Hara, Akio, Yazu, Shuji
• Primary Examiner(s): Hunt, Brooks H.
• Application Number:
  US06/119,771
• Time in Patent Office: 858 Days
• Field of Search: 51/307, 51/309 R, 75/236-242, 75/244, 428/552, 428/565
• US Class Current: 75/238
• CPC Class Codes: B22F 7/06 of composite workpieces or articles from parts, e.g. to form tipped tools B22F7/002 takes precedence
• CPC Class Codes: B23B 27/148 Composition of the cutting inserts
• CPC Class Codes: C04B 35/5831 based on cubic boron nitrides or Wurtzitic boron nitrides, including crystal structure transformation of powder
• CPC Class Codes: C22C 2026/005 with additional metal compounds being borides
• CPC Class Codes: C22C 26/00 Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
• CPC Class Codes: Y10T 428/12056 Entirely inorganic
• CPC Class Codes: Y10T 428/12146 Nonmetal particles in a component

Abstract

A sintered compact for use in a machining tool comprising 80 to 10 volume % of a high pressure form of boron nitride, and the balance a matrix of at least one binder compound material selected from the group consisting of a carbide, nitride, carbonitride, boride or silicide of IVa and Va transition metal of the periodic table, their mixtures as well as the solid solution of these compounds; the matrix forming a continuous bonding structure in the sintered body.

A method of producing the compact comprises preparing a mix of 80 to 10 volume % of a high pressure form of a boron nitride powder with 20 to 90 volume % of at least one powdered binder compound selected from the group consisting of a carbide, a nitride, a carbonitride, a boride and a silicide of a IVa, or a Va metal, mixtures thereof or solid solutions of these compounds, and sintering the mix under pressures more than 20 Kb at temperatures higher than 700° C. for more than 3 minutes.

Claims

1. A sintered compact for use in a tool consisting essentially of:

80 to 20 volume % of high pressure from boron nitride; and

the balance being a matrix of at least one binder compound material selected from the group consisting of a carbide, a nitride, a carbonitride, a boride and a silicide of a IVa a Va transition metal of the periodic table, mixtures thereof and their solid solution compounds;

the matrix forming a continuous bonding structure in a sintered body and where the high pressure boron nitride is interspersed within a continuous matrix.

2. A sintered compact as claimed in claim 1, wherein said carbide, nitride and carbonitride of the IVa and Va metal is formulated as MC₁±

x, MN₁±

x and M(C,N)₁±

x and in which (C1±

x) has the value of less than 0.97;

wherein M is selected from the group consisting of Ti, Zr, Hf, V,Nb and Ta and x represents the amount of atomic voids in the lattice structure.

3. A sintered compact as claimed in claim 1, wherein 0.1 to 20 volume % of at least one element selected from the group consisting of Al and Si is contained in the sintered, body.

4. A sintered compact as claimed in claim 1, wherein said binder compound material is at least one material selected from the group consisting of a carbide, a nitride and a carbonitride of a IVa metal formulated as MC₁±

x, MN₁±

x and M(C,N)₁±

x of which the (1±

x) value is less than 0.97, said high pressure form of boron nitride is the cubic form boron nitride, and 0.1 to 20 volume % of at least one element selected from the group consisting of Al and Si is contained in the sintered body;

wherein M is selected from the group consisting of Ti, Zr, Hf, V,Nb and Ta and x represents the amount of atomic voids in the lattice structure.

5. A sintered compact as claimed in claim 1, wherein 0.1 to 20 volume % of at least one element selected from the group consisting of Ni, Co, Fe and Cu is contained in the sintered body.

6. A sintered compact as claimed in claim 1, wherein said high pressure form boron nitride contains cubic boron nitride which is transformed from the wurtzite form boron nitride during sintering, and said binder compound material is at least one material selected from the group consisting of a carbide, a nitride and a carbonitride of a IVa and a Va metal formulated as MC₁±

x, MN₁±

x and M(C,N)₁±

x, and the matrix comprises at least one solid solution compound selected from the group consisting of M-C-O, M-N-O and M-C-N-O;

wherein M is the IVa and Va metal and x represents the amount of atomic voids in the lattice structure.

7. A sintered compact as claimed in claim 1, wherein the lattice vacancies in the crystals of the carbide, nitride and carbonitride in the matrix is lower than that of the carbide, nitride and carbonitride of the powdered binder compound material, and the lattice constant of the former is larger than that of the latter.

8. A sintered compact as claimed in claim 1, wherein the average particle size of said high pressure form of boron nitride is less than 10 micron.

9. A sintered compact as claimed in claim 1, further comprising a cemented carbide substrate integrally bonded to the sintered body.