Radiation induced graft polymerization

• US 4,340,057 A
• Filed: 12/24/1980
• Issued: 07/20/1982
• Est. Priority Date: 12/24/1980
• Status: Expired due to Fees

• Current Assignee: SC Johnson & Son Incorporated
• Original Assignee: SC Johnson & Son Incorporated
• Inventors: Bloch, Daniel R., Rogers, John R., Odders, Charles N.
• Primary Examiner(s): Bell, James J.
• Application Number:
  US06/219,669
• Time in Patent Office: 573 Days
• Field of Search: 204/159.12, 204/160.1, 128/284, 128/285, 128/287, 128/296, 427/44, 260/17.4 CL, 428/290, 428/507, 428/913, 428/255, 428/274, 428/304, 428/508, 428/511, 428/913, 428/248
• US Class Current: 604/358
• CPC Class Codes: A61L 15/60 Liquid-swellable gel-forming materials, e.g. super-absorbents
• CPC Class Codes: C08L 33/02 Homopolymers or copolymers of acids; Metal or ammonium salts thereof
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10T 428/249954 With chemically effective material or specified gas other than air, N, or carbon dioxide in void-containing component
• CPC Class Codes: Y10T 428/249992 Linear or thermoplastic
• CPC Class Codes: Y10T 428/3188 Next to cellulosic
• CPC Class Codes: Y10T 428/31884 Regenerated or modified cellulose
• CPC Class Codes: Y10T 428/31895 Paper or wood
• CPC Class Codes: Y10T 442/277 Coated or impregnated cellulosic fiber fabric

Abstract

An absorbent material is prepared by treating a substrate with an aqueous monomer dispersion of an acrylate salt and a cross-linking monomer and thereafter irradiating the treated substrate with high energy ionizing radiation to form a cage matrix of the polymer and monomer substrate. The absorbent material can be swelled with a solution containing a volatile additive to dispense said additive over a period of time.

Claims

1. Method of preparing moisture-swellable absorbent material comprising:

(a) treating a substrate capable of forming graft polymers with an acrylate salt under the influence of high energy ionizing radiation, with an aqueous monomer dispersion of

(i) an acrylate salt selected from the group consisting of sodium acrylate, potassium acrylate, lithium acrylate, ammonium acrylate and mixtures thereof, and;

(ii) a water-dispersible cross-linking monomer in amounts from about 2 percent to 10 percent by weight of said acrylate salt, said aqueous dispersion having sufficient acrylate salt and cross-linking monomer to form a reaction product with said substrate in amounts from about 60 percent to 200 percent by weight of the substrate; and

(b) irradiating said treated substrate with high energy ionizing radition having an energy of at least about 150,000 electron volts at a dose rate no greater than 90 megarads per second to provide a dosage from about 0.5 to 25 megarads, to thereby form a graft polymer on the surface of, and on interpenetrating network within, said substrate.

2. The process of claim 1, wherein said material is a web, sheet, pad, yarn, batt, tow, creped tissue, cord, scrim, continuous fiber, floc, bristle, artificial straw, filament, fluff, or fabric.

3. The process of claim 1 wherein said material is a cellulosic absorbent material.

4. The process of claim 3, wherein said material is cotton, rayon, a cellulose derivative or a regenerated cellulose.

5. The process of claim 4, wherein said material is a nonwoven absorbent article.

6. The process of claim 5, wherein said article is a diaper, tampon, sanitary napkin, medical sponge, bandage, wiping cloth, soil mulch or disposable feminine hygiene shield.

7. The process of claim 1, wherein the water dispersible cross-linking monomer is selected from the group consisting of pentaerythritol triacrylate, tetraethylene glycol diacrylate, trimethylol propane triacrylate, a vinyl phosphonate and mixtures thereof.

8. The process of claim 1 wherein the cross-linking monomer is employed in amounts of about 4 to 10 percent by weight of said acrylate salt.

9. The process of claim 1, wherein the monomer solids in the aqueous dispersion is from about 40 to 70 percent by weight.

10. The process of claim 1, wherein the high energy ionizing radiation is an electron beam.

11. The process of claim 1, wherein said aqueous dispersion comprises sodium acrylate and from about 4 to 8 percent by weight of said acrylate, of a vinyl phosphonate monomer.

12. The process of claim 1 wherein said reaction product add-on to said substrate is from about 75% to 200% by weight and said irradiating step is conducted at a dose rate no greater than 45 megarads per second to provide a dosage from about 1.75 to 25 megarads.

13. The moisture-swellable absorbent material formed by the process which comprises:

(a) treating a substrate capable of forming graft polymers with an acrylate salt under the influence of high energy ionizing radiation with an aqueous monomer dispersion of

(i) an acrylate salt selected from the group consisting of sodium acrylate, potassium acrylate, lithium acrylate, ammonium acrylate and mixtures thereof, and;

(ii) a water-dispersible cross-linking monomer in amounts from about 2% to 10% by weight of said acrylate salt in said aqueous dispersion having sufficient acrylate salt and cross-linking monomer to form a reaction product with said substrate in amounts from about 60 percent to 200 percent by weight of substrate,

(b) by irradiating said treated substrate with high energy ionizing radiation having an energy of at least about 150,000 electron volts at a dose rate up to about 90 megarads per second to provide a dosage from about 0.5 to 25 megarads to thereby form a graft polymer on the surface and an interpenetrating network within, said substrate.

14. The product of claim 13, wherein said material is a cellulosic non-woven absorbent article.

15. The product of claim 14, wherein the article is a diaper.

16. The product of claim 13 wherein said reaction product add-on to said substrate is from about 75% to 200% by weight and said irradiating step is conducted at a dose rate no greater than 45 megarads per second to provide a dosage from about 1.75 to 25 megarads.

17. A method for preparing a swelled article capable of dispensing volatile additives which comprises forming a moisture swellable absorbent material by:

(a) treating substrate capable of forming graft polymers with an acrylate salt under the influence of high energy ionizing radiation, with an aqueous monomer dispersion of

(i) an acrylate salt selected from the group consisting of sodium acrylate, potassium acrylate, lithium acrylate, ammonium acrylate and mixtures thereof, and;

(ii) a water-dispersible cross-linking monomer in amounts from about 2 to 10 percent by weight of said acrylate salt, said aqueous dispersion having sufficient acrylate salt and cross-linking monomer to form a reaction product with said substrate in amounts from about 60 percent to 200 percent by weight of the substrate;

(b) irradiating said treated substrate with high energy ionizing radiation having an energy of at least about 150,000 electron volts at a dose rate no greater than about 90 megarads per second to provide a dosage from 0.5 to 25 megarads and thereby form a graft polymer on the surface of, and an interpenetrating network within, said substrate, and

(c) treating said swellable material with an aqueous solution or dispersion containing said volatile additive to permit said material to absorb said aqueous solution or dispersion.

18. The method of claim 17 wherein said reaction product add-on to said substrate is from about 75% to 200% by weight and said irradiating step is conducted at a dose rate no greater than 45 megarads per second to provide a dosage from about 1.75 to 25 megarads.

19. A swelled article capable of dispensing predetermined amounts of volatile additive formed by the process which comprises forming a moisture swellable absorbent material by:

(a) treating substrate capable of forming graft polymers with an acrylate salt under the influence of high energy ionizing radiation, with an aqueous monomer dispersion of

(i) an acrylate salt selected from the group consisting of sodium acrylate, potassium acrylate, lithium acrylate, ammonium acrylate and mixtures thereof, and;

(ii) a water-dispersible cross-linking monomer in amounts from about 2 to 10 percent by weight of said acrylate salt, said aqueous dispersion having sufficient acrylate salt and cross-linking monomer to form a reaction product with said substrate in amounts from about 60 percent to 200 percent by weight of the substrate;

(b) irradiating said treated substrate with high energy ionizing radiation having an energy of at least about 150,000 electron volts at a dose rate no greater than about 90 megarads per second to provide a dosage from 0.5 to 25 megarads and thereby form a graft polymer on the surface, and in an interpenetrating network within, said substrate, and

(c) treating said swellable material with an aqueous solution or dispersion containing said volatile additive to permit said material to absorb said aqueous solution or dispersion.

20. The article of claim 19, wherein said additive is a perfume, an air freshener, a disinfectant, or mixtures thereof.

21. The article of claim 19, wherein said reaction product add-on to said substrate is from about 75% to 200% by weight and said irradiating step is conducted at a dose rate no greater than 45 megarads per second to provide a dosage from about 1.75 to 25 megarads.