Crystalline glucose and process for its production

• US 4,342,603 A
• Filed: 02/24/1981
• Issued: 08/03/1982
• Est. Priority Date: 02/27/1980
• Status: Expired due to Fees

• Current Assignee: TATE & LYLE PLC
• Original Assignee: TATE & LYLE PLC
• Inventors: Daniels, Michael J.
• Primary Examiner(s): Marantz, Sidney
• Application Number:
  US06/237,645
• Time in Patent Office: 525 Days
• Field of Search: 127/58, 127/30, 127/38
• US Class Current: 127/30
• CPC Class Codes: C13K 1/10 Crystallisation

Abstract

A product comprising a mixture of α- and β- forms of glucose as microcrystals, at least 70% of the glucose being in the form of the β-isomer, dissolves readily in water to give approximately 60% solids solutions at ambient temperature. It is obtained by a process comprising the steps of

(1) evaporating water from syrup at a pressure of less than 400 mm Hg to provide an at least 60% supersaturated solution of greater than 95% solids at a temperature of from 95° to 140° C.;

(2) subjecting the supersaturated solution substantially instantaneously to a shear force to cause immediate nucleation of the syrup without cooling; and

(3) immediately forming the nucleated but substantially uncrystallized syrup into a quiescent layer and allowing the layer to crystallize substantially isothermally to produce solid crystalline glucose.

Claims

1. A process for the production of crystalline glucose from a glucose syrup, comprising the steps of

(1) evaporating water from the glucose syrup at a pressure of less than 400 mm Hg to provide an at least 60% supersaturated solution of greater than 95% solids at a temperature of from 95°

to 140°

C.;

(2) subjecting the supersaturated solution to a shear force for less than 0.5 second to cause immediate nucleation of the syrup without cooling; and

(3) immediately forming the nucleated but substantially uncrystallised syrup into a quiescent layer and allowing the layer to crystallise substantially isothermally to produce solid crystalline glucose.

2. A process according to claim 1, wherein the glucose solution is at least 70% supersaturated.

3. A process according to claim 2, wherein the glucose syrup is of 98-100 DE and is evaporated at a temperature of from 110°

to 130°

C.

4. A process according to claim 3, wherein the temperature is 115°

to 125°

C.

5. A process according to claim 2, wherein the glucose syrup is prepared by hydrolysis of starch to a DE of 93-98 and is evaporated at a temperature of from 105°

to 125°

C.

6. A process according to claim 5, wherein the temperature is 10°

to 120°

C.

7. A process according to claim 1 wherein the glucose syrup is evaporated at 100 to 150 mm Hg.

8. A process according to claim 7 wherein the evaporation gives a solution of 98 to 99% solids.

9. A process according to claim 1 wherein the process is operated so as to attain "steady state" conditions, whereby the temperature of the syrup leaving the evaporator and the temperature of the syrup in the shearing equipment remain constant and are substantially the same.

10. A product produced by the process of claim 1 comprising microcrystals of a mixture of α

- and β

-forms of glucose, at least 70% of the glucose being in the form of the β

-isomer, wherein the microcrystals each have a maximum dimension of less than 50 microns.

11. A product according to claim 10, wherein the microcrystals form part of an agglomerate or other composite structure.

12. A product according to claim 10 in which the maximum dimension is less than 10 microns.

13. A product according to claim 10 wherein at least 85% of the glucose is the β

-isomer of D-glucose.