Method of making humidity sensors

• US 4,343,688 A
• Filed: 11/17/1980
• Issued: 08/10/1982
• Est. Priority Date: 11/22/1979
• Status: Expired due to Term

• Current Assignee: US Philips Corporation (Koninklijke Philips N.V.)
• Original Assignee: US Philips Corporation (Koninklijke Philips N.V.)
• Inventors: Harwood, Mervyn G.
• Primary Examiner(s): Kaplan, G. L.
• Application Number:
  US06/207,485
• Time in Patent Office: 631 Days
• Field of Search: 204/195 W, 204/1 W, 427/125, 338/35, 367/191, 73/52, 73/49.3, 73/73, 73/336, 310/313 R, 310/313 B, 310/313 C
• US Class Current: 204/430
• CPC Class Codes: G01N 27/121 for determining moisture content, e.g. humidity, of the fluid moisture content of the tested material G01N27/048
• CPC Class Codes: H01C 1/142 the terminals or tapping points being coated on the resistive element
• CPC Class Codes: H01C 17/288 by thin film techniques

Abstract

A method of making a humidity sensor which comprises an alumina substrate bearing a pair of noble metal electrodes. The electrodes are electrically connected to each other by an electrically conductive moisture-sensitive layer present on the substrate. In order to be able to monitor the moisture content of a gaseous atmosphere inside the housing of a sealed electronic device, for example an integrated circuit or an acoustic surface wave device, it is necessary to use a small sensor which can be used in a static atmosphere. According to the method, an electrode system may be formed by sputtering gold onto an alumina substrate. The substrate bearing the electrode system is then baked in air at a temperature in the range of from 100° to 750° C. for from 30 hours to 1/2 hour, and then a coating comprising orthophosphoric acid or phosphorus pentoxide is applied over that area of the substrate which is to bear the moisture-sensitive layer. The assembly is heated at from 50° to 500° C. for from 30 hours to 1/2 hour so as to form the electrically conductive, moisture-sensitive layer by a reaction between the alumina and the orthophosphoric acid or the phosphorus pentoxide.

Claims

1. A method of making a humidity sensor comprising the steps of:

providing an alumina substrate;

providing a pair of noble metal electrodes on the substrate; and

forming an electrically conductive, moisture-sensitive layer on the substrate between and electrically contacting the electrodes;

characterized in that the moisture-sensitive layer is formed by;

heating the alumina substrate to a temperature in the range of 100°

to 750°

C. for from 30 hours to 1/2 hour in order to activate the alumina;

coating at least a portion of the substrate between the electrodes with orthophosphoric acid or phosphorus pentoxide, said coating contacting the electrodes; and

heating the coated substrate to a temperature in the range of 50°

to 500°

C. for from 30 hours to 1/2 hour so as to form the electrically conductive, moisture-sensitive layer by a reaction between the alumina and the orthophosphoric acid or phosphorus pentoxide.

2. A method as claimed in claim 1, characterized in that the first heating step is performed in air, and it also removed any residual organic matter from the surface of the substrate.

3. A method of claimed in claim 2, characterized in that the coating step is performed with a 1/2 normal to 27 normal solution of orthophosphoric acid.

4. A humidity sensor made by the method of claim 1, 2, or 3.