Electrochromic display device

• US 4,349,818 A
• Filed: 07/03/1980
• Issued: 09/14/1982
• Est. Priority Date: 07/04/1979
• Status: Expired due to Term

• Current Assignee: Kabushiki Kaisha Daini
• Original Assignee: Kabushiki Kaisha Daini Seikosha
• Inventors: Kaneko, Noboru, Tabata, Junichi
• Primary Examiner(s): Trafton, David L.
• Application Number:
  US06/165,502
• Time in Patent Office: 803 Days
• Field of Search: 340/785, 340/713, 350/357
• US Class Current: 345/105
• CPC Class Codes: G02F 1/163 Operation of electrochromic cells, e.g. electrodeposition cells; Circuit arrangements therefor
• CPC Class Codes: G09G 3/19 using electrochromic devices

Abstract

An electrochromic display device comprises; an electrolyte held between two substrates at least one of which is transparent. A display electrode is formed on a surface of one substrate and has an electrochromic substance film formed thereon, the surface being in contact with the electrolyte. A first counter electrode is formed on a counter surface of the other substrate in opposed spaced-apart relationship with respect to the display electrode, and a second counter electrode is formed on a face of either one of the substrates, the face being in contact with the electrolyte. Circuitry applies a first voltage between the display electrode and the first counter electrode to effect coloration of the display electrode, and applies a second voltage between the first and second counter electrodes to establish an electric field therebetween effective to remove a negative ion region which forms in the vicinity of the first counter electrode during coloration of the display electrode.

Claims

1. An electrochromic display device comprising:

an electrolyte held between two substrates at least one of which is transparent;

a display electrode formed on a surface of one of said substrates and including an electrochromic substance film, said surface being in contact with said electrolyte;

a first counter electrode formed on a counter surface of the other of said substrates, said counter surface being spaced from and facing said display electrode;

a second counter electrode formed on a face of one of said two substrates, said face being in contact with said electrolyte;

means for selectively applying a voltage between said display electrode and said first counter electrode to effect the coloration of said display electrode;

means for selectively intermittently applying a voltage between said first counter electrode and said second counter electrode to effect removal of a minus ion layer which forms in the vicinity near said first counter electrode; and

means for alternately changing the application of the voltage from between said display electrode and said first counter electrode to the application of the voltage between said first counter electrode and said second counter electrode.

2. An electrochromic display device as claimed in claim 1;

wherein said first counter electrode and said second counter electrode are formed on the same surface of the same substrate, the two counter electrodes having a comb-like shape.

3. An electrochromic display device as claimed in claim 1;

wherein said first counter electrode comprises the electrode for effecting the coloration of at least the display electrode; and

further comprising a control circuit and a driving circuit for applying the voltage between said first counter electrode and said second counter electrode in such a way that said first counter electrode is at a negative potential and said second counter electrode is at a positive potential.

4. A method for driving an electrochromic display device comprised of an electrolyte held between two substrates at least one of which is transparent;

a display electrode formed on a surface of one substrate and having an electrochromic substance film, said surface being in contact with said electrolyte;

a first counter electrode formed on a counter surface of the other substrate, said counter surface being spaced from and facing said display electrode;

a second counter electrode formed on a face of one of the two substrates, said face being in contact with said electrolyte; and

means for intermittently applying a voltage between said first counter electrode and said second counter electrode, said method comprising the steps of;

applying a voltage between said display electrode and said first electrode to effect the coloration of said display electrode accompanied by formation of a minus ion layer in the vicinity near the first counter electrode;

electrically floating said display electrode after coloration thereof; and

then applying a voltage between said first counter electrode and said second counter electrode to remove a minus ion layer which forms in the vicinity near said first counter electrode.

5. In an electrochromic display device having an electrolyte contained between two spaced-apart substrates:

a set of display segments disposed on the surface of one substrate and in contact with the electrolyte, each display segment comprised of a display electrode and an electrochromic substance;

a first counter electrode disposed on the surface of the other substrate and in contact with the electrolyte;

a second counter electrode disposed on the surface of one of the two substrates and in contact with the electrolyte;

first voltage applying means for selectively applying a voltage between preselected display electrodes and the first counter electrode to effect coloration of the preselected display electrodes accompanied by formation of a negative ion region in the electrolyte in the vicinity near the first counter electrode; and

second voltage applying means for selectively applying a voltage between the first counter electrode and the second counter electrode to establish an electric field between the first and second counter electrodes effective to remove the negative ion region thereby increasing the coloration response speed of the electrochromic display device.

6. An electrochromic display device according to claim 5;

wherein the second voltage applying means includes means for intermittently applying the voltage between the first counter electrode and the second counter electrode.

7. An electrochromic display device according to claim 5 or claim 6;

including circuit means for rendering the first and second voltage applying means operable to apply voltage is alternate periods.

8. An electrochromic display device according to claim 7;

wherein the first and second counter electrodes are both disposed on the same surface of the same substrate.

9. An electrochromic display device according to claim 8;

wherein the first and second counter electrodes each have a comb-like shape and are disposed in opposing interdigit relationship with respect to each other.

10. An electrochromic display device according to claim 5;

wherein the first and second counter electrodes are both disposed on the same surface of the same substrate.

11. An electrochromic display device according to claim 10;

wherein the first and second counter electrodes each have a comb-like shape and are disposed in opposing interdigit relationship with respect to each other.