Stable calcium hypochlorite composition and method for manufacture thereof

• US 4,355,014 A
• Filed: 05/23/1980
• Issued: 10/19/1982
• Est. Priority Date: 05/29/1979
• Status: Expired due to Term

• Current Assignee: Toyo Soda Manufacturing Co., Ltd.
• Original Assignee: Toyo Soda Manufacturing Co., Ltd.
• Inventors: Hiraga, Yoichi, Murakami, Tsugio, Igawa, Kazushige
• Primary Examiner(s): Ford, John M.
• Assistant Examiner(s): WHITTENBAUGH, ROBERT
• Application Number:
  US06/152,720
• Time in Patent Office: 879 Days
• Field of Search: 252/187 H, 423/155, 423/265
• US Class Current: 423/265
• CPC Class Codes: A01N 59/00 Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
• CPC Class Codes: C01B 11/064 Hypochlorites of alkaline-earth metals
• CPC Class Codes: C02F 1/76 with halogens or compounds of halogens C02F1/4674 takes precedence
• CPC Class Codes: C11D 3/3951 combined with specific additives

Abstract

A stable calcium hypochlorite composition and a method for the preparation thereof. The composition has a calcium hypochlorite anhydride and/or a calcium hypochlorite dihydrate used as main constituent and comprises at least 60 wt % of calcium hypochlorite; at least 5 wt % of calcium hydroxide; at least 4 wt % of water content; and 5 wt % or less of than that calcium chloride. The composition is stable and decomposes only in a less degree at a high temperature and during storage over a long period.

Claims

1. A stable calcium hypochlorite composition having a calcium hypochlorite anhydride and/or a calcium hypochlorite dihydrate as main constituent thereof, said composition comprising at least 60 wt % of calcium hypochlorite, at least 5 wt % of calcium hydroxide, at least 4 wt % of water content and 5 wt % or less than that of calcium chloride.

2. A stable calcium hypochlorite composition according to claim 1 wherein said calcium hydroxide is virtually free calcium hydroxide.

3. A stable calcium hypochlorite composition according to claim 1 or 2 comprising 6-8 wt % of calcium hydroxide and 7-22 wt % of water content.

4. A method for manufacturing a stable calcium hypochlorite composition wherein calcium hydroxide is added to a raw calcium hypochlorite composition having a calcium hypochlorite anhydride and/or a calcium hypochlorite dihydrate as main constituent thereof to obtain a composition comprising at least 60 wt % of calcium hypochlorite, at least 5 wt % of calcium hydroxide, at least 4 wt % of water content and 5 wt % or less than of calcium chloride.

5. A method for preparing a stable calcium hypochlorite composition according to claim 4 wherein said raw calcium hypochlorite composition includes water content not exceeding 70 parts by weight and calcium chloride not exceeding 8 parts by weight of 100 of calcium hypochlorite.

6. A method for preparing a stable calcium hypochlorite composition according to claim 4 or 5 wherein said calcium hydroxide is at least 2 parts by weight as Ca(OH)₂ to 100 of said raw calcium hypochlorite composition.

7. A method for preparing a stable calcium hypochlorite composition according to claim 4 or 5 wherein said calcium hydroxide is between 5 and 10 parts by weight as Ca(OH)₂ to 100 parts of said raw calcium hypochlorite composition.

8. A method for preparing a stable calcium hypochlorite composition according to claim 4 or 5 wherein said calcium hydroxide to be added is a free calcium hydroxide powder.

9. A method for preparing a stable calcium hypochlorite composition according to claim 8 wherein said calcium hydroxide contains water in quantity not exceeding 10 wt % and calcium carbonate not exceeding 5 wt %, said calcium hydroxide being of particle size capable of passing through a 200 mesh screen.

10. A method for preparing a stable calcium hypochlorite composition according to claim 4 or 5 comprising 6-8 wt % of said calcium hydroxide and 7-22 wt % of water content.

11. A method for preparing a stable calcium hypochlorite composition according to claim 4 or 5 wherein said raw calcium hypochlorite composition contains as main constituent thereof a coarse calcium hypochlorite dihydrate or a dried product obtained therefrom, said coarse calcium hypochlorite dihydrate being obtained by adding as seed crystals, in crystallizing a calcium hypochlorite dihydrate, a prismatic calcium hypochlorite dihydrate having its ases a and b (in the direction of width) and axis c (in the direction of thickness) in the ratio of:

##EQU3## and having the axis c measure at least 5 microns.