Method for treating polypropylene ether and poly-1,2-butylene ether polyols

• US 4,355,188 A
• Filed: 09/25/1981
• Issued: 10/19/1982
• Est. Priority Date: 10/16/1980
• Status: Expired due to Fees

• Current Assignee: The General Tire & Rubber Company
• Original Assignee: The General Tire & Rubber Company
• Inventors: Bingham, Robert E., Herold, Robert J.
• Primary Examiner(s): MARS, HOWARD
• Application Number:
  US06/305,432
• Time in Patent Office: 389 Days
• Field of Search: 568/608, 568/609, 568/620, 568/621, 568/623-625, 536/120
• US Class Current: 568/620
• CPC Class Codes: C08G 18/48 Polyethers
• CPC Class Codes: C08G 18/4841 containing oxyethylene end groups
• CPC Class Codes: C08G 18/4866 having a low unsaturation value
• CPC Class Codes: C08G 2110/0008 flexible
• CPC Class Codes: C08G 2110/0025 rigid
• CPC Class Codes: C08G 65/2663 Metal cyanide catalysts, i.e. DMC's
• CPC Class Codes: C08G 65/30 Post-polymerisation treatment, e.g. recovery, purification, drying

Abstract

Polyetherpolyols containing residues of catalysts of the double metal cyanide complex class are treated with a strong base and ion exchanged or neutralized and filtered to provide a stable polyol with reduced tendency to form allophanates with diisocyanates. Further, the addition of ethylene oxide to the polyol while in contact with the strong base serves to end cap the polyol to provide it with primary hydroxyl groups.

Claims

1. The method which comprises treating a polyol selected from the group consisting of polypropylene ether polyol and poly-1,2-butylene ether polyol and mixture of the same, said polyol containing catalyst residues of the double metal cyanide complex class, with a treating agent selected from the group consisting of sodium metal, potassium metal, sodium hydroxide and potassium hydroxide in an amount and at a temperature and for a time sufficient to convert said catalyst residues to ionic species, adding ethylene oxide to said polyol while said polyol is in admixture with said treating agent present in an amount at least sufficient to convert at least some of, preferably all of, the secondary hydroxyl groups of said polyol to primary hydroxyl groups and then removing said ionic species and said treating agent from said polyol, said polyol having been made by polymerizing propylene oxide or 1,2-butylene oxide or mixture of the same with a copolymerizable initiator or telogen consisting essentially of a polyol having from 2 to 8 hydroxyl groups, 2 to 21 carbon atoms and consisting of carbon hydrogen and oxygen using a polymerization catalyst of the double metal cyanide complex class.

2. The method according to claim 1 wherein the removal of said ionic species and said treating agent is accomplished by treatment of said polyol containing said ionic species and treating agent with a mineral acid to precipitate said species and said treating agent and then filtering said polyol to remove the precipitate formed.

3. The method according to claim 1 wherein the removal of said ionic species and said treating agent is accomplished by passing said polyol containing said ionic species and said treating agent through a cationic ion exchanger.

4. The method according to claim 3 where said polyol is polypropylene ether polyol, said residue is from a zinc hexacyanocobaltate complex catalyst and said treating agent comprises sodium metal dispersion in mineral oil.

5. The method according to claim 3 where said polyol after being passed through said cationic ion exchanger is additionally passed through an anionic ion exchanger.