Self-lubricating bearing and the like, and method of making same

• US 4,357,249 A
• Filed: 09/11/1980
• Issued: 11/02/1982
• Est. Priority Date: 09/11/1980
• Status: Expired due to Term

• Current Assignee: Mellor H. Clay
• Original Assignee: Arguto, Inc.
• Inventors: Mellor, H. Clay
• Primary Examiner(s): Howard, Jacqueline V.
• Application Number:
  US06/186,312
• Time in Patent Office: 782 Days
• Field of Search: 252/12, 252/12.2, 252/12.4, 252/12.6, 308/240
• US Class Current: 508/101
• CPC Class Codes: C10M 111/00 Lubrication compositions characterised by the base-material being a mixture of two or more compounds covered by more than one of the main groups C10M101/00 - C10M109/00, each of these compounds being essential
• CPC Class Codes: C10M 2201/041 Carbon; Graphite; Carbon black
• CPC Class Codes: C10M 2201/103 Clays; Mica; Zeolites
• CPC Class Codes: C10M 2201/105 Silica
• CPC Class Codes: C10M 2205/022 Ethene
• CPC Class Codes: C10M 2205/024 Propene
• CPC Class Codes: C10M 2205/14 Synthetic waxes, e.g. polythene waxes
• CPC Class Codes: C10M 2205/16 Paraffin waxes; Petrolatum, e.g. slack wax
• CPC Class Codes: C10M 2205/17 Fisher Tropsch reaction products
• CPC Class Codes: C10M 2207/40 Fatty vegetable or animal oils
• CPC Class Codes: C10M 2207/404 obtained from genetically modified species
• CPC Class Codes: C10N 2040/02 Bearings
• CPC Class Codes: F16C 33/201 Composition of the plastic

Abstract

Self-lubricating bearings, such as journal-type bearings are obtained by molding under pressure at elevated temperatures a substantially homogeneous blend of from about 70 to 95% of an ultra high molecular weight ethylene polymer and from about 5 to 30% of a normally solid lubricant which can be a wax, fat or mixtures thereof, or a mixture of either or both of these lubricants with a grease. The bearings exhibit excellent dimensional stability, good wear resistance, and a surface which is not oily to the touch. The bearings are self-lubricating, slowly releasing lubricant at temperatures developed in ordinary use.

Claims

1. A composition particularly suitable for being molded into structural members which are dimensionally stable and have a low coefficient of friction comprising a substantially homogeneous blend of from about 70% to about 95% of a substantially linear ultra high molecular weight ethylene polymer, and from about 5% to about 30% of a normally solid lubricant selected from the group consisting of waxes, fats and mixtures thereof, and mixtures of one or both of said lubricants with a grease, said percentages being by weight based on the total weight of the composition.

2. The composition according to claim 1 in which said ethylene polymer has an average molecular weight of from about 1.5×

10⁶ to about 3.5×

10⁶.

3. The composition according to claim 1 in which said lubricant comprises a paraffin wax.

4. The composition according to claim 1 in which said lubricant comprises stearin.

5. The composition according to claim 1 in which said lubricant comprises a mixture of a wax and a fat.

6. The composition according to claim 5 in which said wax comprises a paraffin wax and said fat comprises stearin.

7. The composition according to claim 1 in which said lubricant comprises a mixture of a wax, a fat and a grease.

8. The composition according to claim 7 in which said lubricant comprises from about 30% to about 60% wax, from about 10 to about 40% fat and from about 10 to about 40% grease, said percentages being by weight based on the total weight of the mixture of said lubricants.

9. The composition according to claim 1 comprising about 80% polymer and 20% normally solid lubricant, said lubricant comprising about 46% paraffin wax, about 27% stearin and about 27% white oil grease.

10. A structural member having dimensional stability and a low coefficient of friction in the form of a tough, rigid, solid body comprising from about 70% to about 95% of an ultra high molecular weight ethylene polymer having dispersed therein from about 5% to about 30% of a normally solid lubricant selected from the group consisting of waxes, fats and mixtures thereof, and mixtures of one or both of said lubricants with a grease, said percentages being by weight based on the total weight of said polymer and lubricant.

11. A structural member according to claim 10 in the form of a journal-type bearing.

12. A structural member according to claim 10 in which said ethylene polymer has a molecular weight of from about 1.5×

10⁶ to about 3.5×

10⁶.

13. A structural member according to claim 10 in which said lubricant comprises a paraffin wax.

14. A structural member according to claim 10 in which said lubricant comprises stearin.

15. A structural member according to claim 10 in which said lubricant comprises a mixture of a wax and a fat.

16. A structural member according to claim 15 in which said wax comprises a paraffin wax and said fat comprises stearin.

17. A structural member according to claim 10 in which said lubricant comprises a mixture of a wax, a fat and a grease.

18. A structural member according to claim 17 in which said lubricant comprises from about 30% to about 60% wax, from about 10% to about 40% fat and from about 10 to about 40% grease, said percentages being by weight based on the total weight of the mixture of said lubricants.

19. A structural member according to claim 18 comprising about 80% polymer and about 20% normally solid lubricant, said lubricant comprising about 46% paraffin wax, about 27% stearin and about 27% white oil grease.

20. A structural member according to claim 19 in the form of journal-type bearing.

21. A method of making a composition particularly suited for being molded into structural members which are dimensionally stable and have a low coefficient of friction comprising the steps of:

(a) heating a normally solid lubricant selected from the group consisting of waxes, fats and mixtures thereof, and mixtures of one or both of said lubricants with a grease, to form a liquid,

(b) heating a finely-divided ultra high molecular weight ethylene polymer to a temperature above the temperature of said liquid lubricant, but below the temperature at which said polymer softens,

(c) mixing said lubricant and polymer together to form a homogeneous blend comprising from about 5% to about 30%, by weight, of said lubricant and from about 70% to about 95%, by weight, of said polymer, and

(d) cooling said homogeneous blend to obtain a homogeneous powder suitable for molding structural members.

22. The method according to claim 21 wherein said lubricant is heated to a temperature of about 160°

F., and said polymer is heated to a temperature in a range of about 170°

F. to about 200°

F. prior to combining said lubricant and said polymer.

23. The method according to claim 21 in which said blend comprises about 20%, by weight of said lubricant, and about 80% of said polymer.

24. The method according to claim 23 wherein said lubricant comprises a mixture of paraffin wax, stearin and a white oil grease, said wax constituting about 46%, by weight, of said lubricant mixture, the remainder of the mixture comprising about equal parts, by weight, of said stearin and white oil grease.

25. The method according to claim 21 including the step of heating said blend to a temperature from about 380°

to about 420°

F., and subjecting the composition to a pressure in a range of about 1000 psi to about 1500 psi for a time sufficient to produce, upon cooling a tough, rigid, dimensionally stable article having a low coefficient of friction and a surface substantially free from an oil-like film.