Amphoteric surfactant gels

• US 4,360,451 A
• Filed: 08/10/1981
• Issued: 11/23/1982
• Est. Priority Date: 08/10/1981
• Status: Expired due to Term

• Current Assignee: BASF Corporation (BASF SE)
• Original Assignee: BASF Wyandotte Corporation
• Inventors: Schmolka, Irving R.
• Primary Examiner(s): Phynes, Lucille M.
• Application Number:
  US06/291,337
• Time in Patent Office: 470 Days
• Field of Search: 252/316, 424/70, 424/78, 525/409
• US Class Current: 516/104
• CPC Class Codes: A61K 31/77 of oxiranes
• CPC Class Codes: A61K 8/042 Gels
• CPC Class Codes: A61K 8/90 Block copolymers A61K8/89 takes precedence
• CPC Class Codes: A61Q 19/10 Washing or bathing preparations
• CPC Class Codes: A61Q 5/02 Preparations for cleaning the hair
• CPC Class Codes: C08G 65/08 Saturated oxiranes
• CPC Class Codes: C08J 2371/02 Polyalkylene oxides
• CPC Class Codes: C08J 3/03 in aqueous media
• CPC Class Codes: C08L 71/02 Polyalkylene oxides
• CPC Class Codes: C09K 23/017 Mixtures of compounds

Abstract

Amphoteric surfactant gels containing a polyoxybutylene-polyoxyethylene block copolymer which maintain their gel characteristics at temperatures below about 20° C.

Claims

1. An amphoteric surfactant gel comprising based on the total of 100 parts by weight (a) from about 5 to about 50 parts by weight of amphoteric surfactant, (b) from about 10 to about 80 parts by weight of water, (c) from about 15 to about 40 parts by weight of a polyoxybutylene-polyoxyethylene block copolymer, said block copolymer being a cogeneric mixture of conjugated polyoxybutylene-polyoxyethylene compounds containing in their structure oxybutylene groups, oxyethylene groups and an organic radical derived from a water-soluble organic compound containing a plurality of reactive hydrogen atoms and 2 to 12 carbon atoms;

the compounds being characterized in that all of the oxybutylene groups are present in polyoxybutylene chains that are attached to the organic radical at the site of a reactive hydrogen atom thereby constituting a polyoxybutylene polymer;

the oxyethylene groups being attached to the polyoxybutylene polymer in polyoxyethylene chains;

the average molecular weight of the polyoxybutylene polymers in the mixture being at least 1200, as determined by hydroxyl number, and the oxyethylene groups present constituting 50 to 80 percent, by weight, of the mixture, with the provisos that

(a) when the hydrophobe molecular weight is about 1200, then the minimum polyoxyethylene content is about 60 percent by weight of the block copolymer and the minimum block copolymer content to form a gel is about 25 percent by weight of the aqueous gel compositions;

(b) when the hydrophobe molecular weight is about 1800, then the minimum polyoxyethylene content is about 55 percent by weight of the block copolymer and the minimum block copolymer content to form a gel is about 20 percent by weight of the aqueous gel composition;

(c) when the hydrophobe molecular weight is about 2400, then the minimum polyoxyethylene content is about 50 percent by weight of the block copolymer and the minimum block copolymer content to form a gel is about 16 percent by weight of the aqueous gel composition;

(d) when the hydrophobe molecular weight is about 3000, then the minimum polyoxyethylene content is about 45 percent by weight of the block copolymer and the minimum block copolymer content to form a gel is about 16 percent by weight of the aqueous gel composition.

2. The amphoteric surfactant gel of claim 1 wherein the block copolymer comprises from about 18 to about 25 parts by weight of the amphoteric surfactant gel.

3. The amphoteric surfactant gel of claim 1 wherein the polyoxybutylene polymer has an average molecular weight of about 1800 and a polyoxyethylene content of about 70 percent by weight of the mixture.

4. The amphoteric surfactant gel of claim 2 wherein the polyoxybutylene polymer has an average molecular weight of about 1800 and a polyoxyethylene content of about 70 percent by weight of the mixture.

5. The amphoteric surfactant gel of claim 1 wherein the amphoteric surfactant comprises from about 20 to about 40 parts by weight of the amphoteric surfactant gel.

6. The amphoteric surfactant gel of claim 1 wherein the water comprises from about 30 to about 60 parts by weight of the amphoteric surfactant gel.