Laminated board

• US 4,361,616 A
• Filed: 02/26/1980
• Issued: 11/30/1982
• Est. Priority Date: 03/01/1979
• Status: Expired due to Term

• Current Assignee: Dsm Nv
• Original Assignee: Stamicarbon B.V. (MAIRE)
• Inventors: Bomers, Joseph J. P.
• Primary Examiner(s): HERBERT JR, THOMAS
• Application Number:
  US06/124,903
• Time in Patent Office: 1,008 Days
• Field of Search: 428/212, 428/241, 428/312, 428/315, 428/313, 428/425.5, 428/454, 428/446, 428/310, 428/325, 428/703, 428/327, 428/404, 428/332, 428/215, 428/220, 428/304.4 , 428/312.2, 428/312.4, 428/315.7, 428/316.6, 428/317.9
• US Class Current: 428/215
• CPC Class Codes: B32B 13/04 comprising such water setting substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to a glass layer B32B17/06
• CPC Class Codes: B32B 13/12 of synthetic resin
• CPC Class Codes: B32B 2262/101 Glass fibres
• CPC Class Codes: B32B 2305/08 Reinforcements
• CPC Class Codes: B32B 2307/102 Insulating
• CPC Class Codes: B32B 2307/304 Insulating
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: C04B 16/04 Macromolecular compounds C04B16/02 takes precedence
• CPC Class Codes: C04B 20/0048 Fibrous materials
• CPC Class Codes: C04B 24/26 obtained by reactions only involving carbon-to-carbon unsaturated bonds C04B24/243 takes precedence
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 40/02 Selection of the hardening environment
• CPC Class Codes: E04C 2/288 composed of insulating material and concrete, stone or stone-like material
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified
• CPC Class Codes: Y10T 428/249953 Composite having voids in a component [e.g., porous, cellular, etc.]
• CPC Class Codes: Y10T 428/249967 Inorganic matrix in void-containing component
• CPC Class Codes: Y10T 428/249968 Of hydraulic-setting material
• CPC Class Codes: Y10T 428/249979 Specified thickness of void-containing component [absolute or relative] or numerical cell dimension
• CPC Class Codes: Y10T 428/249981 Plural void-containing components
• CPC Class Codes: Y10T 428/249986 Void-containing component contains also a solid fiber or solid particle
• CPC Class Codes: Y10T 428/252 : Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
• CPC Class Codes: Y10T 428/254 : Polymeric or resinous material
• CPC Class Codes: Y10T 428/26 : Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/2993 : Silicic or refractory material containing [e.g., tungsten oxide, glass, cement, etc.]
• CPC Class Codes: Y10T 428/31598 : Next to silicon-containing [silicone, cement, etc.] layer

Abstract

Laminated board structures having excellent mechanical properties made up of a layer of thermal and/or acoustic insulating material strongly bonded to a layer of fibre-reinforced water hardened cement with an aqueous dispersion containing an addition polymer preferably containing acid groups and having an average particle size between 0.05 micron and 5 microns. Improved mortar composition used in the laminate structure.

Claims

1. An insulating board laminate panel structure having a combination of a fiber reinforced water-hardened cement mortar layer securely bonded to an insulating foam material so that high bond strength between said insulating board and said cement mortar layer is achieved and said resulting laminate panel has higher buckling strength, load bearing and impact resistance, wherein said panel structure is composed of:

(A) said insulating board foam material having a density of less than about 0.5 grams/cc; and

(B) said water-hardened cement mortar layer adjacent said insulating board material has a composition consisting essentially of;

(i) cement mortar having a weight ratio of water to said cement mortar between 0.2 to 0.5, and further having up to 40 percent by volume of reinforcing fibers; and

(ii) a dispersion of an addition-polymerized resin of vinyl monomers having an average particle size of between 0.05 to 1.5 microns, said resin being present in a resin to said cement weight ratio of between 0.02 to 0.4 and containing between 2.5% to 30.0% by weight of monomers having an acid group.

2. Laminate panel structure according to claim 1, wherein said acid group is selected from the group consisting of phosphoric acid groups, sulfonic acid groups and carboxyl groups.

3. Laminate panel structure according to claim 1, wherein said cement includes up to 0.1 percent by volume of a thixotropy imparting substance.

4. Laminate panel structure according to claim 1 wherein said laminate structure hardens at a temperature between 35°

C. and 100°

C.

5. Laminate panel structure according to claim 1, wherein said cement layer completely envelopes said insulating material.

6. Laminate panel structure according to claim 1 or 5, wherein said cement layer is from 1 mm to 50 mm thick and said insulating material is from 10 mm to 500 mm thick.

7. Laminated structure according to claim 1, wherein said reinforcing fibers are polymer fibers.

8. Laminated panel structure according to claim 7, wherein said polymer fibers in said cement are in the form of continuous networks.

9. Laminate panel structure according to claim 1, wherein said acid group is a monounsaturated acid selected from the group consisting of acrylic acid, methacrylic acid, fumaric acid, itaconic acid, crotonic acid or semiesters of malic acid, fumaric acid or itaconic acid.

10. Laminate panel structure according to claim 9, wherein said mono-unsaturated acids are monomers having at least one carboxyl group wherein said monomers are polymerized into said resin.

11. Laminate panel structure according to claim 9 or 10, wherein said particle size is between 0.1 micron and 0.75 microns.

12. Laminate panel structure according to claim 1, wherein said fibers are mineral fibers.

13. Laminate panel structure according to claim 12, wherein said mineral fibers are present in amounts between 1% and 20%.

14. Laminate panel structure according to claim 12 or 13, wherein said mineral fibers are glass fibers.