Process for making fermentable sugars and high-protein products

• US 4,361,651 A
• Filed: 07/18/1980
• Issued: 11/30/1982
• Est. Priority Date: 07/18/1980
• Status: Expired due to Term

• Current Assignee: Carroll R. Keim
• Original Assignee: Carroll R. Keim
• Inventors: Keim, Carroll R.
• Primary Examiner(s): Jones, Raymond N.
• Assistant Examiner(s): Tarcza, John E.
• Application Number:
  US06/170,033
• Time in Patent Office: 865 Days
• Field of Search: 435/161, 435/162, 435/163, 435/164, 435/165, 435/93, 435/813, 435/96, 435/97
• US Class Current: 435/161
• CPC Class Codes: C12P 7/06 Ethanol, i.e. non-beverage
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

Disclosed is a dry or wet milling process for making fermentable sugars and high-protein products from starch bearing material, characterized by saccharification of the starch followed by recovery of fiber and other non-protein materials and of destarched protein as separate products, leaving a sugar solution that is essentially free of insoluble materials. The sugars are fermented to ethanol and carbon dioxide by the action of added yeast. After fermentation, the yeast is recovered for use in fermenting additional quantities of sugars supplied either for batch or continuous processing. The alcohol is then removed leaving a dilute solution of unfermentable soluble materials, and this liquid, in whole or in part, is recycled to preceding steps in the process.

Claims

1. A process for obtaining from carbohydrate-bearing grain high yields of soluble carbohydrates, a protein fraction essentially free of carbohydrates, and ethanol which comprises, in combination, the steps of:

(a) steeping said grain in water for a period of time sufficient only to toughen the hull and germ thereof to facilitate subsequent separation and to form a steepwater;

(b) separating said steepwater from said grain and concentrating said steepwater to produce feedstuff.

(c) degerminating said grain and recovering germ containing oil and minimum amounts of starch and protein leaving a magma containing 75 to 80% by weight of water including minerals, proteins and carbohydrates and insolubles including starch, protein, fiber and fatty materials;

(d) forming a slurry of said magma resulting from step (c) with water;

(e) saccharifying the carbohydrates from said carbohydrate material to produce a sugar solution containing sugars, other water-soluble compounds and suspended coarse and fine insoluble materials;

(f) removing the coarse insolubles from said sugar solution;

(g) removing, washing and drying the fine insolubles comprising principally protein from said sugar solution;

(h) cooling and adding yeast to said sugar solution and fermenting same to produce ethanol;

(i) recovering at least a portion of said yeast from said fermented material in (h) and recycling same for further fermentation;

(j) distilling ethanol from the fermented material;

(k) recycling water remaining after distillation to said solution and to wash said protein.

2. The process of claim 1 in which the magma remaining after steeping and degerminating is dewatered to reduce the amount of solubles which move forward in the process and the water expelled is recycled to wash said germ and to steep said grain.

3. The process of claim 1, wherein coarse insoluble materials are washed to remove the carbohydrates therefrom, leaving a sugar solution in which finely divided particles of protein and other finely divided particles are suspended.

4. According to claim 3 wherein the fine insolubles are recovered from the sugar solution by filtration or centrifugation.

5. The process of claim 4, wherein after said sugar solution is freed of insoluble protein by filtration and/or centrifugation or other suitable means, said protein is separated from sugar solution, dewatered (and dried) from about 88% moisture to about 60% moisture and the extracted water is recycled to said sugar solution.

6. The process of claim 1, wherein said material is selected from the group of grain sorghum, wheat, barley, corn, rice, soybean, alfalfa, tapioca, potato, yams, and banana.

7. The process of claim 1, wherein said sugar solution is converted to n-butanol, acetone, glycerol, lactic acid, butylene glycol, citric acid, gluconic acid or itaconic acid.

8. A process according to claim 1, in which the carbohydrate material is dry milled, the dry milled material is slurred with water, the carbohydrates are converted to a solution containing sugars, other water soluble compounds and suspended insoluble materials removing therefrom a mash of coarse insolubles consisting mainly of cellulosic material;

removing fine insolubles consisting mostly of protein and fatty materials from said mash;

separating and recovering said protein;

adding yeast to the remaining material to ferment same;

centrifugally recovering said yeast;

recycling said yeast for futther fermentation;

distilling alcohol from said material.

9. The process of claim 1, wherein carbon dioxide produced during fermentation is recovered.

10. The process of claim 1, wherein said slurry is (1) separated from steepwater;

(2) said steepwater is concentrated to yield material suitable as feedstuff;

(3) said slurry is degermed;

(4) said germ is recovered while (5) the remaining underflow containing fibers, starch, protein, soluble and insoluble materials is dewatered from about 80 to 50% water;

(6) said underflow then being cooked;

(7) cooled to saccharification temperature;

(8) its pH adjusted to 4.0 to 4.5 and (9) from 1 to 1.5 liters of amylase per ton of dry starch is added.

11. The process of claim 10, wherein said fibers are removed dewatered, pre-dried to a moisture content of 20 to 40%, mixed with said concentrated steepwater and the resulting mixture is dried to form feedstuff.

12. The process of claim 1, wherein said sugar solution is concentrated to form syrup, cast as solid sugar or crystallized as dextrose.

13. The process of claim 1, wherein said grain is corn and said steeping lasts ten to thirty hours.