Apparatus for chemical conversion of materials

• US 4,363,671 A
• Filed: 05/18/1981
• Issued: 12/14/1982
• Est. Priority Date: 03/18/1980
• Status: Expired due to Fees

• Current Assignee: New York University
• Original Assignee: New York University
• Inventors: Stanton, Robert, Rugg, Barry A.
• Primary Examiner(s): Marcus, Michael S.
• Application Number:
  US06/264,244
• Time in Patent Office: 575 Days
• Field of Search: 127/1, 127/28, 127/37, 422/137, 366/83, 366/85, 366/88, 366/90, 162/56, 162/236, 425/204, 425/208
• US Class Current: 127/1
• CPC Class Codes: B01J 3/042 in the form of a tube
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32

Abstract

A process and apparatus for the acid hydrolysis of waste cellulose to glucose of the type wherein waste cellulose is continuously fed into an inlet port of a twin screw extruder, water is continuously fed into reaction zone in the extruder downstream of the inlet port, the cellulose is continuously reacted with water in the presence of an acid catalyst at elevated temperature and pressure in the reaction zone while continuously conveying same to an outlet port of the extruder and the reacted cellulose is discharged from the extruder the elevated temperature and pressure in the reaction zone is maintained, has the elevated pressure is maintained by forming a dynamic seal zone at the upstream end of the reaction zone by providing an unthreaded and radially recessed discontinuity in the screws.

Claims

1. In an apparatus for the dilute sulfuric acid hydrolysis of waste cellulose and being of the type comprising:

extruding means including a housing having inlet ports receptive of cellulose to be converted, dilute sulfuric acid and steam or superheated water, an outlet port and a reaction zone therebetween;

twin screws mounted in the housing for continuously, conveying the cellulose through the reaction zone and to the outlet port;

means defining supply sources of waste cellulose, dilute sulfuric acid and steam or superheated water, said supply means being connected to the respective inlet port;

means for continuously feeding the cellulose to the waste cellulose inlet port;

means for continuously injecting dilute sulfuric acid into the reaction zone;

means for effecting an elevated temperature and pressure with the reaction zone during discharge comprising means for continuously injecting steam or superheated hot water at elevated pressure into the reaction zone and means for maintaining the elevated temperature and pressure including means forming a dynamic seal of the cellulose at the upstream end of the reaction zone and valve means downstream of the outlet port, the improvement wherein the means forming the dynamic seal comprises means forming a radially recessed and unthreaded discontinuity in the twin screws.

2. The apparatus according to claim 1, wherein the means forming the discontinuity comprises said radially recessed unthreaded screw element along each screw and a right hand pitch thread upstream thereof and downstream thereof in the reaction zone.

3. The apparatus according to claim 1 or claim 2, wherein the valve means comprises a valve for continuously discharging the reacted material downstream of the outlet port in response to a selected pressure in the reaction zone.

4. The apparatus according to claim 3, wherein the valve comprises means forming a valve aperture, a spherical valve body seatable in the valve aperture and means for biasing the valve body into the valve aperture against the pressure in the reaction zone.

5. The apparatus according to claim 4, wherein the biasing means comprises a spring and means for adjustably selecting the spring force on the valve body.

6. The apparatus according to claim 1, further comprising means for pretreating the cellulose material before being received by the feeding means including means for irradiating the cellulose material.

7. In an apparatus for the dilute sulfuric acid hydrolysis of waste cellulose and being of the type comprising:

extruding means including a housing having an inlet port receptive of cellulose to be converted, an outlet port and a reaction zone therebetween;

twin screws mounted in the housing for continuously conveying the cellulose through the reaction zone and to the outlet port;

means for continuously feeding the cellulose to the inlet port;

means for continuously injecting dilute sulfuric acid into the reaction zone;

means for effecting an elevated temperature and pressure within the reaction zone during discharge comprising means for continuously injecting steam or superheated hot water at elevated pressure into the reaction zone; and

means for maintaining the elevated temperature and pressure within the reaction zone including means forming a dynamic seal of the cellulose at the upstream end of the reaction zone and valve means downstream of the outlet port, the improvement wherein the means forming the dynamic seal comprises means forming a radially recessed and unthreaded discontinuity in the twin screws, the radially recessed unthreaded screw element along each screw being flanked by two like sections of threaded pitch opposite that of the remaining screw.

8. The apparatus according to claim 7, wherein the means for continuously feeding the cellulose waste material comprises means for continuously feeding dry cellulose material into the inlet port.