Method for medium consistency oxygen delignification of pulp

• US 4,363,697 A
• Filed: 12/03/1979
• Issued: 12/14/1982
• Est. Priority Date: 12/03/1979
• Status: Expired due to Term

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc), The Black Clawson Company
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc), The Black Clawson Company
• Inventors: Markham, Larry D., Eklund, Henrik J.
• Primary Examiner(s): Alvo, Steve
• Application Number:
  US06/099,684
• Time in Patent Office: 1,107 Days
• Field of Search: 162/17, 162/19, 162/25, 162/237, 162/57, 162/90, 162/241, 162/243, 8/116 R, 8/111, 422/229
• US Class Current: 162/19
• CPC Class Codes: B01F 27/1143 screw-shaped, e.g. worms
• CPC Class Codes: D21C 9/10 Bleaching ; Apparatus therefor
• CPC Class Codes: D21C 9/1068 with O2 closed, see D21C9/147

Abstract

Medium consistency oxygen delignification of pulp is carried out in a series of tubular reaction zones. Rapid delignification is achieved by agitating the pulp by rotating a timing screw in the first reaction zone at a speed in excess of 10 rpm, modifying the flights on the timing screw to increase the amount of agitation, or a combination of the two. Primary oxygenation is carried out in the first reaction zone while subsequent zones provide the retention time needed for the delignification reaction to go to completion. A thick stock pump is used to introduce the pulp into the first reaction zone.

Claims

1. A process for the continuous oxygen delignification of medium consistency pulp comprising the steps of:

a. introducing pulp at a consistency of from 8 to 20% and alkaline materials into a first reaction zone and maintaining the consistency of the pulp at between 8% to 20% throughout the first and subsequent reaction zones,

b. introducing gaseous oxygen into said first reaction zone to delignify said pulp and maintaining the oxygen partial pressure in the first and subsequent reaction zones from about 30 to 200 psig,

c. agitating the mixture of the pulp gaseous, oxygen, and alkaline materials with a screw conveyor extending along the length of said first zone operated at from 10 to 200 rpm, and

d. passing said mixture into one or more subsequent substantially horizontal reaction zones and retaining the pulp in said one or more zones for a time sufficient for further delignification to occur while agitating said pulp with a screw operating at from 0.5 to 5 rpm.

2. The process of claim 1 in which said screws extend the entire length of the reaction zones and have modified flights.

3. The process of claim 1 in which the temperature in said reaction zones is maintained at between about 80°

and 160°

C.

4. The process of claim 3 in which steam is injected into the pulp prior to its introduction into said first reaction zone.

5. The process of claim 1 in which a thick stock pump is used to introduce the pulp into said first reaction zone.

6. The process of claim 1 in which said alkaline materials are selected from the group consisting of sodium hydroxide, sodium carbonate, sodium borate compounds, ammonia, oxidized kraft white liquor, or mixtures thereof.

7. The process of claim 6 in which the charge of alkaline materials present in the first reaction zone is from 1% to 20% by weight, calculated as Na₂ O on an oven dry basis of raw materials.

8. The process of claim 7 in which said alkaline materials are introduced at the top of said first reaction zone at points along the length thereof.

9. The process of claim 1 in which at least a portion of said alkaline materials are added to the pulp prior to its introduction into the first reaction zone.

10. The process of claim 1 in which the consistency of the pulp is from 10 to 15% throughout said first and subsequent reaction zones.

11. The process of claim 1 including the step of,

e. passing said mixture into a nonagitated vertical retention column for completion of delignification.

12. The process of claim 1 in which the diameter of said first reaction zone is less than the respective diameters of subsequent reaction zones.

13. The process of claim 1 in which the total retention time for the total retention time for said pulp in said first and subsequent reaction zones is from about 5 to 120 minutes.