Method and apparatus for making battery paste

• US 4,363,742 A
• Filed: 06/17/1980
• Issued: 12/14/1982
• Est. Priority Date: 06/17/1980
• Status: Expired due to Term

• Current Assignee: Beardsley & Piper LLC
• Original Assignee: Pettibone LLC (Heico Holding Incorporated)
• Inventors: Stone, Milton
• Primary Examiner(s): Miles, Tim R.
• Assistant Examiner(s): Konkol, Chris
• Application Number:
  US06/160,221
• Time in Patent Office: 910 Days
• Field of Search: 252/182.1, 422/109, 422/111, 422/114, 422/117, 422/225, 364/500, 364/502, 366/17, 366/40, 366/132, 366/152, 366/151, 137/90, 137/92, 73/54, 23/230 A
• US Class Current: 252/182.1
• CPC Class Codes: H01M 4/04 Processes of manufacture in general
• CPC Class Codes: H01M 4/56 of lead
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Control apparatus and a method for making battery paste by mixing selected quantities of lead oxide, sulfuric acid and water to form a reaction mixture are disclosed. During the reaction portion of the process, the viscosity of the mixture initially descends on a time-viscosity curve, which then changes in slope to reach a point of minimum viscosity. The temperatures of the reaction mixture form a time-temperature curve having a temperature peak therein. The temperature and the viscosity of the reaction mixture are determined respectively by temperature sensing devices and by viscosity sensing devices. In response to the temperature of the reaction mixture rising to a predetermined temperature or above as determined by the temperature sensing devices and to the viscosity thereof being at or above a predetermined value as determined by the viscosity sensing devices, coincidence devices actuate a valve controlled water supply to add a quantity of water to the reaction mixture, until the viscosity thereof is reduced to a value below the predetermined value. The predetermined temperature corresponds approximately to at least one of (a) a temperature at which a predetermined time-viscosity curve reaches a point adjacent to the minimum viscosity, and (b) a temperature at a point on a predetermined time-temperature curve which corresponds to said predetermined time-viscosity curve, a point adjacent to and below its peak. The water content of the reaction mixture is adjusted thereby, as needed, so as to approximate the water content desired in the final product.

Claims

1. In battery paste making equipment for mixing selected quantities of lead oxide, sulfuric acid and water to form a viscous mixture, control apparatus comprising:

temperature sensing means for determining the temperature of the mixture;

viscosity sensing means for determining the viscosity of the mixture;

valve means for admitting water to the mixture;

coincidence means responsive to said temperature sensing means determining the temperature of the mixture to be a minimum temperature or above and to said viscosity sensing means determining the viscosity of the mixture to be at or above a maximum acceptable value of viscosity, for activating said valve means to admit water to the mixture until the viscosity thereof is reduced to a value below the maximum acceptable value, whereupon said viscosity sensing means disables said coincidence means, thereby de-activating said valve means.

2. Battery paste making equipment according to claim 1 further including timing means responsive to said temperature sensing means at a minimum temperature or above, for disabling said coincidence means after a predetermined time interval.

3. Battery paste making equipment according to claim 2 wherein said minimum temperature is a minimum low temperature and said maximum acceptable value is a maximum acceptable first value, further including second coincidence means responsive to said temperature sensing means determining the temperature of the mixture to be a minimum high temperature or above and to said viscosity sensing means determining the viscosity of the mixture to be at or above a maximum acceptable second value of viscosity, for activating said valve means to admit water to the mixture until the viscosity thereof is reduced to a value below the maximum acceptable second value, whereupon said viscosity sensing means disables said second coincidence means, thereby de-activating said valve means.

4. Battery paste making equipment according to claim 3 wherein said timing means includes switch means connected in series with the first-mentioned coincidence means to disable it upon the termination of said predetermined time interval.

5. Battery paste making equipment according to claim 3 further including recycle timing means responsive to the first-mentioned and said second coincidence means for turning on and off repeatedly said valve means so that a series of bursts of water are supplied to the mixture.

6. Battery paste making equipment according to claim 5 wherein said recycle timing means produces a timing signal having an initial delay off cycle followed by a series of pulses separated by dispersion off cycles, said valve means being activated in response to said pulses and being de-activated during the off cycles.

7. Battery paste making equipment according to claim 5 or 6 further including delay means associated with said valve means for enabling said valve means to remain activated for a predetermined time delay interval independently of the viscosity condition of the mixture when said valve means is activated initially.

8. Battery paste making equipment according to claim 7 wherein said delay means includes a pipe connected in fluid communication with the outlet of said valve means for delivering water therefrom to the mixture, said pipe being of a predetermined length to provide said predetermined time delay interval and being inclined downwardly away from said valve means.

9. Battery paste making equipment according to claim 5 further including means for counting the number of bursts of water delivered to the mixture and for de-activating said valve means in response to counting a predetermined number of bursts of water.

10. Battery paste making equipment according to claim 9 further including alarm means responsive to said counting means for generating an attention-attracting signal.

11. Battery paste making equipment according to claim 10 wherein said alarm means includes a horn for generating an audible alarm signal and a lamp for generating a visual alarm signal.

12. Battery paste making equipment according to claim 3 further including automatic switch means for energizing the first-mentioned and said second coincidence means to provide for an automatic mode of operation, and manual switch means connected in parallel with the first-mentioned and said second coincidence means for overriding them to provide for a manual mode of operation.

13. In a method of making battery paste by mixing selected quantities of lead oxide and water to form a mixture the viscosity of which ascends on a time-viscosity curve, and then admixing a selected quantity of sulfuric acid to form a reaction mixture the viscosity of which initially descends on such curve, the curve then changing in slope to reach a point of minimum viscosity, the temperature of said reaction mixture forming a time-temperature curve having a temperature peak therein at a time subsequent to acid addition, the steps which comprise:

sensing the temperature of said reaction mixture,

sensing the viscosity of said reaction mixture, and

adding a quantity of water to the reaction mixture

when the temperature thereof rises to a predetermined temperature or above and the viscosity thereof is at or above a predetermined value, until the viscosity is reduced to a value below the predetermined value,

said predetermined temperature corresponding approximately to at least one of (a) a temperature at which a predetermined time-viscosity curve reaches a point adjacent to said minimum viscosity, and (b) a temperature at a point on a predetermined time-temperature curve which corresponds to said predetermined time-viscosity curve, at a point adjacent to and below its peak, whereby the water content of the reaction mixture is adjusted so as to approximate the water content desired in the final product.

14. The method of making battery paste according to claim 13 further including the steps of adding the water in bursts, counting the number of bursts of water, and terminating said adding a quantity of water if the viscosity has not been reduced to a value below the predetermined value in response to the counting of a predetermined number of bursts of water.

15. The method of making a battery paste according to claim 14 further including the steps of generating an attention-attracting alarm signal in response to the counting of a predetermined number of bursts of water.