Synthetic liquid fuel and fuel mixtures for oil-burning devices

• US 4,364,743 A
• Filed: 06/17/1980
• Issued: 12/21/1982
• Est. Priority Date: 09/05/1979
• Status: Expired due to Term

• Current Assignee: William E. Erner
• Original Assignee: William E. Erner
• Inventors: Erner, William E.
• Primary Examiner(s): Howard, Jacqueline V.
• Application Number:
  US06/160,434
• Time in Patent Office: 917 Days
• Field of Search: 44/66, 44/57
• US Class Current: 44/388
• CPC Class Codes: C10L 1/02 essentially based on components consisting of carbon, hydrogen, and oxygen only
• CPC Class Codes: C10L 1/026 for compression ignition
• CPC Class Codes: C10L 1/19 Esters ester radical containing compounds; ester ethers; carbonic acid esters C10L1/1802, C10L1/1805, C10L1/1808, C10L1/1811, C10L1/1814, C10L1/1817 take precedence
• CPC Class Codes: C11C 3/003 by esterification of fatty acids with alcohols C11C3/02 takes precedence
• CPC Class Codes: F02B 3/06 with compression ignition compression ignition engines using air or gas for blowing fuel into compressed air in cylinder F02B13/02
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel
• CPC Class Codes: Y02T 50/678 Aviation using fuels of non-fossil origin

Abstract

A synthetic fuel of fatty acid esters provides a novel source of energy when burned alone or in combination with other known fuels such as diesel oil, heating oil, etc., in oil-burning devices.

Claims

1. A combustible energy-producing fuel mixture consisting essentially of

(a) at least one fatty acid ester having the formula ##STR2## wherein R is alkyl having from 1 to 12 carbon atoms;

alkoxyalkyl where the alkoxy portion has from 1-4 carbon atoms and the alkyl portion is ethyl or propyl;

cyclopentyl or cyclohexyl, or hydroxy ethyl or hydroxy propyl;

n=11-22;

a=2n+1, 2n-1, 2n-3, 2n-5 or 2n-7 and x is 0 or 1, and

(b) a middle distillate fuel, wherein the ester and middle distillates have a ratio in the range of from about 10 to 75 to about 90 to 25 percent by weight based on the total weight of the mixture.

2. The fuel mixture of claim 1 wherein the ester has a boiling point of from about 120°

C. at 5 mm to about 340°

C. at 1 mm.

3. The fuel mixture of claim 1 wherein the ester has a molecular weight in the range of from about 214 to about 489.

4. The fuel mixture of claim 1 wherein the ester is at least one member selected from the group consisting of methyl oleate, methyl linoleate, methyl linolenate;

ethyl oleate, ethyl linoleate, ethyl linolenate;

isopropyl oleate, isopropyl linoleate, isopropyl linolenate;

n-butyl oleate, n-butyl linoleate, n-butyl linolenate;

2-ethylhexyl oleate, 2-ethylhexyl linoleate, 2-ethylhexyl linolenate, 2-ethylhexyl palmitate and 2-ethylhexyl stearate.

5. The fuel mixture of claim 1 wherein the middle distillates have a boiling point in the range of from about 140°

C. to about 330°

C.

6. The fuel mixture of claim 1 wherein the middle distillates have a molecular weight in the range of from about 140 to about 300.