Electric furnace construction

• US 4,366,571 A
• Filed: 03/16/1981
• Issued: 12/28/1982
• Est. Priority Date: 03/16/1981
• Status: Expired due to Term

• Current Assignee: Corning Glass Works (Corning Incorporated)
• Original Assignee: Corning Glass Works (Corning Incorporated)
• Inventors: Palmquist, Ronald W.
• Primary Examiner(s): Envall, Jr., Roy N.
• Application Number:
  US06/243,811
• Time in Patent Office: 652 Days
• Field of Search: 13/6, 373/27, 373/30, 373/137, 373/41
• US Class Current: 373/30
• CPC Class Codes: C03B 5/0275 Shaft furnaces C03B5/0277 takes precedence
• CPC Class Codes: C03B 5/425 Preventing corrosion or erosion C03B5/44 takes precedence

Abstract

A method and apparatus for melting thermoplastic material is disclosed utilizing, in a preferred embodiment, a vessel having a bottom wall and upstanding sidewalls. A protective liner for the vessel is provided, being formed of corrosion resistant material. The furnace may include both through-the-batch and floor electrodes, and also hot spot fining to a conductive outlet channel.

A method is set forth for operating the furnace described herein utilizing symmetrical, below the batch heat dissipation for accelerated melting. In order to protect the liner, which in some instances may be fabricated from an oxidizable refractory metal, start-up burners are operated under a reduced oxygen supply.

Claims

1. A furnace for melting thermoplastic material comprising:

a vessel having a bottom wall and a first upstanding peripheral sidewall, liner means concentrically disposed within said vessel having an upstanding sidewall, spaced apart from said first sidewall and extending continuously from a lower portion to near an upper portion of said first sidewall for containing convection flow of said thermoplastic material therewithin and for protecting said vessel from excessive corrosion by the molten thermoplastic material, and peripherally located means partly associated with at least one of said vessel and said liner means for providing a relatively cool peripheral zone wherein the temperature of the thermoplastic material within said zone is sufficiently low so that movement thereof is minimized and corrosion of the vessel is thereby inhibited.

4. The furnace of claim 1 or 3 wherein the means for providing the relatively cool peripheral zone includes at least one peripheral portion of said vessel which is radially offset with respect to an upper or lower portion of said liner means.

5. The furnace of claim 1 or 3 wherein said means for providing the relatively cool peripheral zone includes a laterally outwardly stepped upper peripheral sidewall of said vessel for spacing the upper portion of said vessel further away from a relatively hot central portion of the furnace than remaining portions of said vessel.

6. The furnace of claim 5 wherein said means for providing the relatively cool peripheral zone includes a portion of said liner means sidewall located adjacent to at least a portion of said stepped zone peripheral sidewall but spaced apart a greater distance therefrom than from the remainder of said first sidewall.

7. The furnace of claim 5 wherein said portion of said liner means sidewall has a lateral flange extending therefrom, and said flange extending laterally over at least a radial portion of the stepped sidewall.

8. The furnace of claim 1 or 3 wherein said means for providing a relatively cool zone includes means partially associated with said vessel and said liner means including a slotted wall portion of said vessel adapted to receive therein a free peripheral portion of said liner means forming an interface therebetween, said slotted wall portion being partially shielded from heat whereby the viscosity of material adjacent thereto is relatively high in comparison to the remainder of the furnace such that seepage around said interface is inhibited.

9. The furnace of claim 1 or 3 wherein said means for providing the relatively cool zone includes a fluid conducting means adjacent to a peripheral portion of the liner means for cooling thermoplastic material in the vicinity thereof.

10. The furnace of claim 9 including fluid conducting means comprising a cooling pipe positioned circumferentially with respect to said liner means.

11. The furnace of claim 1 or 2 further including:

an upstanding conductive outlet channel located through an opening in a lower portion of said vessel, said channel having an inlet opening at a free upstanding end thereof positioned at a selected level above the bottom wall within the furnace, and said inlet being positioned to receive melted thermoplastic material from said level and convey said material to an outlet end remotely located from the inlet of said channel.

12. The furnace of claim 11 further including:

an electrically energizable electrode located in spaced relation with said outlet channel, and means for firing said electrode electrically with respect to the outlet channel so that electrical energy flows through the molten thermoplastic material between said electrode and said outlet channel.

13. The furnace according to claim 12 wherein said electrode is located above the outlet channel for firing thereto.

14. The furnace of claim 12 wherein said firing means includes means for providing a relatively high concentration of energy in the vicinity of said inlet opening of said channel.

15. The furnace of claim 1 or 2 further including a plurality of sets of electrodes disposed through at least one of an upper open end of said furnace and openings in the bottom wall thereof, and means for energizing said electrodes to fire electrical energy therebetween through the thermoplastic material.

16. The furnace of claim 15 wherein said furnace has a diameter less than about 6 feet and said electrodes are immersed in the thermoplastic material and have distal ends located in an area relatively close to the center of the furnace so as to lie in a central area of the furnace extending radially about one half the distance from the center of the furnace to said liner means.

17. The furnace of claim 15 including at least one of a first set of electrodes extending through an upper open end of the furnace and through a batch blanket on said thermoplastic material, and a second set of electrodes extending through openings in the bottom of the furnace and the electrodes of each respective set adapted to fire to electrodes therein and to those of the other set.

18. The furnace of claim 15 including at least one of a first and second set of electrodes extending through an upper open end of the furnace and through a batch blanket on said thermoplastic material, each respective set adapted to fire to electrodes therein and to those of the other set.

19. The furnace of claim 15 wherein each of said first and second sets of electrodes includes at least three electrodes firing in a double delta circuitry arrangement.

20. The furnace of claim 15 wherein the first and second sets of electrodes are electrically symmetrical.

21. The furnace of claim 15 wherein said first and second sets of electrodes are circumferentially staggered relative to each other.

22. The furnace of claim 15 wherein the electrodes are spaced away from the upstanding sidewall of said liner means.

23. The furnace of claim 15 further including support means for each of said sets of electrodes for movably carrying and positioning said electrodes at selected orientations, each electrode in a set being removably mounted to said support means at a proximal end thereof and having a distal end adapted to be submerged into the bath of thermoplastic material for inducing electrical currents in said material near an upper level thereof.

24. The furnace of claim 23 wherein the thermoplastic material to be melted therewithin includes a volume of electrically conductive molten material, a batch blanket floating therein, and a fusion zone therebetween;

and the electrodes are positioned with their distal ends located through the batch and fusion zone into the molten material relatively close to the fusion zone for inducing electrical heating currents in the molten material close to the batch blanket.

25. The furnace of claim 15 wherein each of said plurality of sets of electrodes are circumferentially and radially located symmetrically thereabout and symmetrically energized so that the liner operates at an essentially neutral potential relative to said electrodes.

26. The furnace of claim 15 wherein said electrodes are electrically energizable in at least one of cross and peripheral firing modes.

27. The furnace of claim 21 wherein the plurality of sets of electrodes are circumferentially located about the furnace at approximately 30°

intervals to provide symmetry for said electrode locations.

28. The furnace of claim 27 wherein said plurality of sets of electrodes include a first group of sets of electrodes located at approximately 60°

intervals about the furnace and a second group of sets located approximately midpoint therebetween.

29. The furnace of claim 28 wherein the first and second groups of sets of electrodes are symmetrically energized in at least one of cross fired and peripheral firing modes.

30. The furnace of claim 15 wherein the plurality of sets of electrodes include at least two electrodes per set located on radial lines projecting from the center of the furnace.

31. The furnace of claim 15 wherein the electrodes passing through the bottom wall are aligned obliquely relative to a vertical central axis of the furnace with tip ends converging inwardly of the furnace towards said axis.

32. The furnace of claim 15 wherein said electrodes disposed through the open upper end are moveably mounted having distal ends being selectively located in at least one of a vertical, radial and axially oblique location therewithin relative to a central axis of the furnace.

33. The furnace of claim 1 or 2 wherein said liner means includes a bottom wall portion joining with a lower portion of said upstanding peripheral wall portion.

34. The furnace of claim 33 further including an electrical connector coupled to said liner means for electrically energizing same.

35. The furnace of claim 1 wherein said spaced apart upstanding sidewall forms a relatively narrow space between said liner means and said vessel compared to space centrally of said liner means for containing and trapping material therebetween and providing limited space so as to inhibit motion of the material therewithin.

36. The furnace of claim 1 or 2 wherein said liner means is comosed of an oxidizable conductive material selected from refractory metals consisting of molybdenum, tungsten, tantalum, columbium, and alloys thereof.

37. The furnace of claim 1 wherein said liner means is submerged within the molten thermoplastic material within the furnace and some of the thermoplastic material is trapped in the space between said liner means and said vessel for inhibiting oxidation of said liner means.

38. The furnace of claim 1 wherein the level of said thermoplastic material within said vessel is maintained at least at the level closely adjacent the upper extent of said liner means.

39. The furnace of claim 1 or 2 wherein said liner means is composed of materials selected from the group consisting essentially of oxidizable metals, noble metals, steel and alloys thereof.

40. The furnace of claim 1 or 2 wherein the space between said vessel and said liner means is filled at least partially with at least one of a relatively high viscosity glass, granular refractory, sand and ramming mix in which it is relatively difficult to induce convection currents and which is non-corrosive at selected relatively high temperatures.

46. The furnace of claim 1 or 2 wherein said furnace comprises an outer support structure and an internal at least partially refractory inner structure including said vessel into which said linear means is located, and said liner means blocking inspiration of contaminants from said refractory into the thermoplastic material centrally of said liner means.

47. The furnace of claim 46 wherein said support structure includes an outer shell of upstanding walls and a bottom, and the means for electrically separating the former from the latter.

48. The furnace of claim 47 wherein the means for electrically separating the upstanding walls from the bottom includes an insulating shim peripherally located about the bottom and receiving therein a lower margin of the upstanding walls.

49. The furnace of claim 47 wherein said bottom includes at least two plates electrically isolated from each other.

50. The furnace of claim 47 further including:

an electrical connector coupled to said upstanding walls and a ground potential monitoring means coupled across said connector for detecting any current flow therein.

51. The furnace of claim 46 wherein said internal structure includes at least one layer of at least one of refractory block, granular refractory, sand, ramming mix and glass.

52. The furnace of claim 46 wherein said internal structure comprises a plurality of layers beginning from said liner means outwardly including, a layer of high viscosity glass, a layer of refractory block, a layer of ramming mix, a layer of insulation means adjacent the outer support structure.

53. The furnace of claim 52 wherein the layer of insulation means comprises at least one of a layer of rigid insulation, and a layer of compressible insulation adjacent the upstanding wall adapted to accommodate relative movement of the various recited layers during thermal cycling of the furnace.

54. The furnace of claim 1 or 2 including means for introducing an inert purge gas into said furnace both centrally and externally of said liner means for saturating the space within the furnace with such gas.

55. The furnace of claim 1 or 2 wherein said liner means comprises upstanding sidewalls and a bottom wall, and said vessel includes means for spacing said bottom wall of the liner means therefrom.

56. The furnace of claim 54 wherein said means for spacing the liner bottom wall from said vessel includes a plurality of shims located within the space therebetween.

57. The furnace of claim 56 wherein said shims are formed of at least one of the materials of said liner means and said vessel, and the bottom wall of said vessel has counter bores therein for receiving said shims.

58. The furnace of claim 57 wherein the sidewalls of said liner means include an inwardly extending flange member for supporting a peripheral edge of the liner bottom spaced above the vessel bottom.

59. The furnace of claim 1 or 2 further including heater means located within the space between said liner means and said vessel.

60. The furnace of claim 1 or 3 wherein the peripherally located means includes:

active cooling means located proximately to the peripheral zone for cooling the thermoplastic material in the vicinity thereof including a conduit for carrying cooling fluid about said peripheral zone.

2. A furnace for melting thermoplastic material having an open upper portion for receiving batch material to be melted therein comprising:

a refractory vessel having a sidewall and bottom wall;

an oxidizable liner means positioned within the refractory vessel in close proximity with at least the sidewall of the vessel but spaced apart therefrom so as to form a relatively narrow annular space between the liner means and the sidewall;

an upper edge of the liner means being adapted to be located below the fusion line formed by said batch material to be melted and the molten thermoplastic material therebelow to protect the same from oxidation and;

the molten thermoplastic material being free to form convection currents within the liner means and at the same time being inhibited from forming convection currents within the narrow annular space whereby the liner means protects the vessel from corrosion and the molten thermoplastic material covering the linear means protects the same from oxidation.

41. The furnace of claim 2 wherein a trap in the form of a concentric space is formed between said liner means and said vessel near an upper extent thereof for receiving thereabout thermoplastic material.

42. The furnace of claim 41 wherein said trap receives therein material for filling a space between said liner means and said vessel.

43. The furnace of claim 2 wherein a slot formed in a bottom wall of the furnace receives therein a lower margin of said liner means to form an effective seal against flow of material between interior and exterior portions of said liner means.

44. The furnace of claim 43 wherein said slot and lower margin of said liner means are spaced from relatively higher temperatures interior of said furnace and are thereby maintained at a relatively cool temperature.

45. The furnace of claim 44 wherein the vessel is susceptible to corrosion producing products thereof, and the slot receives therein a mixture of said products and thermoplastic material, said mixture tending to be highly viscous and devitrified within and adjacent the slot for forming the seal.

3. The furnace of claim 102 further including peripherally located means partially associated with at least one of the vessel and the liner means for providing a relatively cool zone wherein the temperature of the thermoplastic material is sufficiently low so that circulation thereof between the liner means and the annular space is minimized.

61. In a furnace having a relatively hot central region therein for continuously melting thermoplastic material, a vessel susceptible to corrosion by the molten thermoplastic material, a liner located within the vessel and closely conforming to but spaced apart from the interior thereof and being of a material strongly resistant to corrosion by the thermoplastic material, said liner being at least partially immersed within the thermoplastic material and being effective to protect the vessel from corrosion, passive cooling means at least at an upper extent of said vessel and said liner for shielding a portion of the molten material from heat energy of the hot central region and for rendering molten thermoplastic material within such shielded portion relatively highly viscous in comparison to the remainder of the thermoplastic material within the vessel thereby reducing convection, seepage and cross contamination of the materials on opposite sides of said liner.

62. The furnace of claim 61 wherein the thermoplastic material to be continuously melted is a glass, a portion of which is located within the vessel as an electrically conductive molten layer having a glass forming batch blanket thereover and a fusion zone between the glass and blanket which includes a mixture of molten glass and batch, and said liner and vessel each include upstanding inclined sidewalls converging from a larger upper open inlet end to a smaller lower outlet end.

63. In a furnace for melting thermoplastic material having a zone of relatively intense heat in a central portion thereof comprising:

a vessel having a bottom wall and a first upstanding peripheral sidewall, a liner concentrically disposed within said vessel having an upstanding sidewall spaced apart from said first sidewall and extending from a lower portion to near an upper portion of said first sidewall for containing said thermoplastic material therewithin and for protecting the vessel from excessive corrosion by the molten thermoplastic material, an upstanding electrically conductive outlet channel located through an opening in the bottom wall of the vessel, the channel having an inlet opening at a free upstanding end thereof positioned at a selected level above the bottom wall within the furnace, said inlet being positioned to receive melted thermoplastic material from said level and to convey said material to an outlet end remotely located from the inlet of said channel, and an electrically energizable electrode means mounted for positionment in spaced relation with the outlet channel, means for firing the electrode electrically with respect to the outlet channel so that relatively concentrated electrical energy flows through the molten thermoplastic material between the electrode and outlet channel.

64. The furnace of claim 63 wherein said electrode means is direct current electrically biased relative to the outlet channel so as to become a sacrificial electrode.

65. The furnace of claim 63 wherein said electrode means includes a distal end positioned opposite the inlet end of the outlet channel, the former being disk like and the latter being an outwardly flanged annular portion of said outlet channel.

66. In a furnace for melting thermoplastic material, a method of protecting a refractory vessel portion of said furnace from corrosion caused by moving convection currents of the hot molten thermoplastic material contained within the vessel by providing an oxidizable liner for the interior of the vessel, and at the same time protecting the liner from oxidation from ambient oxygen comprising the steps of:

locating the liner within the vessel in close proximity with the same for providing a relatively narrow space between the liner and vessel;

confining some of the thermoplastic material within the vessel between the liner and the vessel, the confines of the narrow space inhibiting motion of the thermoplastic material, whereby corrosion of the vessel is reduced; and

totally immersing the liner beneath the thermoplastic material for shielding the same from the ambient oxygen and thereby protecting the liner from oxidation while the liner protects the vessel.

67. The method of claim 66 further including the step of providing a relatively cool zone near at least one of a lower and upper extremity of said liner for preventing cross contamination of the thermoplastic material in the space with the thermoplastic material within the liner.

68. The method of claim 66 further including the step of disposing a thermoplastic material relatively inert with respect to the liner between the liner and said vessel.

69. The method of claim 66 further including the step of insulating a major portion of the furnace vessel for reducing heat loss therefrom.

70. The method of claim 66 further including the step of providing at least one layer of refractory material in contact with an outer surface of the vessel for limiting seepage of thermoplastic material beyond said layer.

71. The method of claim 70 including the step of sintering said one layer by heat generated with the furnace.

72. The method of claim 66 further including the step of inhibiting flow of materials including contaminants between inside and outside portions of the liner.

73. The method of claim 72 wherein the step of inhibiting the flow of material includes the step of cooling the material in selected cool zone areas of the furnace to thereby increase its resistance to flow at the relatively cool zone thereof.

74. The method of claim 66 wherein the step of providing the relatively cool zone includes the step of imposing a zone of electrically produced intense heating in an upper portion of the vessel and spaced from said liner.

75. The method of claim 66 further including the step of providing at least one zone of electrically produced heating through at least one of an open upper end of the vessel and a sealable through opening in a lower portion of the vessel.

76. The method of claim 75 further including the step of orienting the position of the electrically produced heating in selected symmetrically spaced locations within the vessel.

77. The method of claim 66 including the step of electrically energizing the liner with at least one of cathodic direct current bias and an alternating current neutral.

78. The method of claim 66 including the step of forming the liner from materials selected from the group consisting of ferrous, refractory and noble metals and alloys thereof.

79. The method of claim 66 including the step of maintaining the liner submerged in thermoplastic material when the temperature of the material exceeds an oxidation temperature of the liner.

80. The method of claim 66 including the step of locating an outlet of the vessel in a position above a lowermost portion thereof for trapping thermoplastic material below the outlet within the vessel.

81. The method of claim 80 further including the steps of electrically energizing the outlet, and producing relatively high electrical heat in the vicinity thereof.

82. The method of claim 81 further including the step of direct current biasing the outlet to an electrical polarity sufficient to prevent electrolytic corrosion thereof.

83. The method of claim 81 including the step of providing a sacrificial electrically energizable heating means, and direct current biasing said heating means relative to the outlet and sacrificing said heating means by electrolytic corrosion in preference to the outlet.

84. The method of claim 66 including the step of inducing electrical current within the thermoplastic material and segmenting the vessel into electrically isolated portions for inhibiting flow of electrical current therebetween.

85. The method of claim 84 further including the step of monitoring current flow in at least one of said isolated portions.

86. The method of claim 84 further including the steps of grounding at least one of said isolated portions, monitoring current flow therein, and severing said ground in the event the current flow therein exceeds a selected level.

87. The method of claim 66 further including the steps of:

depositing a batch blanket of fusible thermoplastic material overlying the molten thermoplastic material, and dissipating electric power in a molten layer of the thermoplastic material immediately underneath the batch blanket, and concentrating electrical heating energy in said layer.

88. The method of claim 87 further including the step of placing sources of electrical heating energy close to each other for providing electrical currents in the material in a symmetrical pattern.

89. The method of claim 87 further including the step of providing a zone of relatively high temperature in the molten layer immediately below the batch blanket and producing convective rolls within the molten material in the layer.

90. The method of claim 89 further including the step of containing the convective rolls near the layer by concentrating the dissipation heat energy therein.

91. The method of claim 89 further including the step of optimizing the size of convective rolls by symmetrical dissipation of the heat energy in said layer.

92. The method of claim 89 further including the step of providing relatively small driving force for said convective rolls by relatively uniform dissipation of heat energy into said layer.

93. An operating glass-melting furnace of the type in which batch materials introduced through an opening in the upper end are melted by means of current-carrying electrodes extending into the interior of said furnace and the resulting molten glass is discharged through an opening formed in the lower end thereof, characterized in that said furnace includes a refractory bottom wall, refractory sidewalls, and a metallic liner spaced interiorly of said refractory sidewalls whereby to form an annular channel at least between said sidewalls and said metallic liner, and said metallic liner is completely immersed in and surrounded by molten glass.

94. A furnace for melting thermoplastic material comprising;

a refractory vessel having sidewall portions,

a discharge opening formed in a lower portion of said vessel,

a metallic liner positioned within said refractory vessel in close proximity with said sidewall portions but spaced apart therefrom so as to form a relatively narrow annular space between said liner and said sidewall portions,

said refractory vessel having an open upper portion for receiving batch material to be melted, and

electrode means for melting batch material delivered to said furnace;

the upper edge of said liner being below the fusion line formed by said batch material to be melted and the molten material therebelow.

95. A furnace as defined in claim 94 wherein said sidewall portions are radially outwardly offset adjacent an upper portion of said liner and said flange portion of said liner contacts said offset sidewall portion to form a trap area between said offset sidewall portion and the upper portion of said liner.

96. A furnace as defined in claim 94 wherein said narrow annular space between an external surface of said liner and adjacent surfaces of said sidewall portions is in communication with the interior of said liner.