Heat transfer printing

• US 4,367,071 A
• Filed: 02/04/1981
• Issued: 01/04/1983
• Est. Priority Date: 11/28/1977
• Status: Expired due to Term

• Current Assignee: Dai Nippon Printing Company Limited
• Original Assignee: Dai Nippon Printing Company Limited
• Inventors: Mizuno, Shogo, Kobayashi, Michiaki, Shimomura, Kyoichi
• Primary Examiner(s): Hess, Bruce H.
• Application Number:
  US06/231,395
• Time in Patent Office: 699 Days
• Field of Search: 8/471, 8/454, 8/467, 8/470, 8/472, 8/550, 8/582, 8/594, 8/611, 8/618, 8/638, 8/644, 8/649, 8/654, 8/657, 8/658, 8/659, 106/22, 106/23, 106/26, 106/31, 106/21, 156/234, 156/240, 156/277, 427/43.1, 427/44, 427/54.1, 427/56, 427/146, 427/148, 427/150, 427/151, 427/256, 427/288, 427/299, 427/301, 427/314, 427/316, 427/317, 427/322, 427/326, 427/372.2 , 427/391, 427/394, 427/430.1, 427/439, 428/200, 428/207, 428/211, 428/219, 428/411, 428/537, 428/913, 428/914, 428/195, 428/332, 428/334-336, 428/339, 428/341, 428/342, 428/484, 428/488, 430/200, 430/201, 430/348, 430/964, 260/37 P
• US Class Current: 503/201
• CPC Class Codes: B41M 5/0356 characterised by the inks used for printing the pattern on the temporary support or additives therefor, e.g. dyes, transferable compounds, binders or transfer promoting additives
• CPC Class Codes: C09D 11/033 characterised by the solvent
• CPC Class Codes: D06P 5/004 using subliming dyes
• CPC Class Codes: Y10S 428/913 Material designed to be responsive to temperature, light, moisture
• CPC Class Codes: Y10S 428/914 Transfer or decalcomania
• CPC Class Codes: Y10T 428/24843 with heat sealable or heat releasable adhesive layer
• CPC Class Codes: Y10T 428/24901 including coloring matter
• CPC Class Codes: Y10T 428/24934 including paper layer
• CPC Class Codes: Y10T 428/273 of coating
• CPC Class Codes: Y10T 428/277 Cellulosic substrate

Abstract

An ink composition for heat transfer printing comprising at least one of carbinol bases of basic dyes or their derivatives, a strong base, a binder and a solvent for dissolving the binder. This ink composition is excellent in storage stability because it contains a carbinol base of a basic dye or its derivative in isolated form as a coloring agent along with a strong base. By using this ink composition, a transfer sheet having high storage stability can be obtained.

Claims

1. A transfer sheet comprising a substrate sheet and a coloring layer provided thereon, the coloring layer containing

from about 1 to about 80 weight percent of a coloring agent comprising at least one of carbinol bases of basic dyes and their derivatives, wherein each of said derivatives is the product of the reaction between a corresponding basic dye and an alcoholate, and said coloring agent is sublimable at a temperature between about 80°

C. and about 250°

C.;

from about 1 to about 80 weight percent of a strong base, wherein the mole ratio of said strong base to said coloring agent is between about 1;

1 to about 40;

1; and

the remainder a binder, wherein all weight percents are based on the total weight of said coloring layer.

2. A transfer sheet as claimed in claim 1 in which the coated weight of the coloring layer on a dry basis is 0.2 to 4 g/m².

3. A transfer sheet as claimed in claim 1 in which the carbinol base derivatives are represented by the formula:

space="preserve" listing-type="equation">Dy--O--R

wherein Dy is a cationic moiety of a basic dye, and R is an alkyl group having 1 to 4 carbon atoms, a benzyl group or a phenyl group.

4. A transfer sheet as claimed in claim 1 in which the strong base is selected from the group consisting of hydroxides and alcoholates of alkali metals and alkaline earth metals.

5. A transfer sheet as claimed in claim 1 in which the strong base is sodium hydroxide or potassium hydroxide.

6. A transfer sheet as claimed in claim 1 in which the binder is selected from ethyl cellulose, ethylhydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl methyl cellulose, polyvinyl alcohol, polyvinyl formal, polyvinyl butyral, polyvinyl acetate, and polyvinyl pyrrolidone.

7. A transfer sheet as claimed in claim 1 in which the coloring layer has been obtained by applying on the substrate sheet an ink composition comprising 0.1 to 10% by weight of said coloring agent, 0.1 to 10% by weight of said strong base in the proportion of 1 to 40 moles per mole of the coloring agent, 5 to 20% by weight of said binder, and the remainder being a solvent containing 80% or more of a monohydric alcohol having a total of 3 to 6 carbon atoms, wherein all weight percents are based on the total weight of said ink composition.

8. A transfer sheet as claimed in claim 1 in which the coloring layer has been obtained by applying on the substrate sheet an ink composition comprising 0.1 to 10% by weight of said coloring agent, 0.1 to 10% by weight of said strong base in the proportion of 1 to 40 moles per mole of the coloring agent, 5 to 20% by weight of said binder, and the remainder being a solvent containing a total of 80% or more of a monohydric alcohol having a total of 3 to 6 carbon atoms and a secondary solvent component selected from the group consisting of butyl acetate, isopropyl acetate, toluene, xylene and methyl isobutyl ketone.

9. A transfer sheet as claimed in claim 8 in which the ratio of the monohydric alcohol to the secondary solvent component used in the ink composition is 2/8 to 4/6 on a weight basis.

10. A transfer sheet as claimed in claim 1 in which the coloring layer further comprises a conventional quantity of a conventional additive selected from the group consisting of plasticizers, stabilizers, waxes, greases, drying agents, hardening agents, emulsifiers, dispersants, fillers, and non-sublimable pigments and dyes.

11. A transfer sheet as claimed in claim 1 in which the coloring layer has thereon an overcoat layer of a thickness of 0.5 to 10 um comprising a film forming resin.

12. A heat transfer printing process which comprises:

superposing a transfer sheet comprising

a substrate sheet and

a coloring layer of a desired pattern

provided on the substrate sheet, the coloring layer containing from about 1 to about 80 weight percent of a coloring agent comprising at least one of carbinol bases of basic dyes and their derivatives, wherein each of said derivatives is the product of the reaction between a corresponding basic dye and an alcoholate, and said coloring agent is sublimable at a temperature between about 80°

C. and about 250°

C.;

from about 1 to about 80 weight percent of a strong base, wherein the mole ratio of said strong base to said coloring agent is between about 1;

1 to about 40;

1; and

the remainder a binder, wherein all weight percents are based on the total weight of said coloring layer,

on a transfer receiving base material consisting of a fiber dyeable with cationic dyes in such a manner that the surface of the transfer sheet provided with the coloring layer contacts the base material to form a superposed structure; and

maintaining the superposed structure under heat, at a temperature sufficient to sublime said coloring agent, and pressure.

13. A heat transfer printing process as claimed in claim 12 in which the heating and pressing treatment is carried out at a temperature of 80°

to 250°

C. and a pressure of 20 g to 20 kg/cm² for 10 to 180 seconds.

14. A heat transfer printing process as claimed in claim 12 or 13, which process further comprises pretreating the transfer receiving base material by immersing the same in an aqueous solution comprising water;

5 to 100 g per liter of water of a color developer having a radical selected from the group consisting of an ammonium group, an amino group and an acid amide group, organic acids, and inorganic acids; and

0.5 to 3 g per liter of water of a homogenizing agent selected from nonionic and anionic surfactants.

15. A heat transfer printing process as claimed in claim 14 in which the aqueous solution has a pH not exceeding 8.

16. A heat transfer printing process as claimed in claim 14 in which the pretreatment is carried out at a temperature of 80°

to 100°

C. for 5 to 60 minutes.