Hollow fiber permeator

• US 4,367,139 A
• Filed: 11/16/1978
• Issued: 01/04/1983
• Est. Priority Date: 11/16/1978
• Status: Expired due to Term

• Current Assignee: Permea Incorporated
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Graham, Tommy E.
• Primary Examiner(s): SPEAR JR, FRANK
• Assistant Examiner(s): Cross, E. Rollins
• Application Number:
  US05/961,342
• Time in Patent Office: 1,510 Days
• Field of Search: 210/321 A, 210/321 B, 210/321 R, 210/23, 210/433 M, 210/456, 165/161
• US Class Current: 210/321.9
• CPC Class Codes: B01D 2319/04 Elements in parallel
• CPC Class Codes: B01D 53/22 by diffusion manufacturing semi-permeable membranes B01D67/00; form, structure or properties of semi-permeable membranes B01D69/00; material for semi-permeable membranes B01D71/00
• CPC Class Codes: B01D 63/02 Hollow fibre modules
• CPC Class Codes: B01D 63/024 with a single potted end

Abstract

The performance of axially-fed permeators comprising an essentially fluid impermeable tubular shell containing a plurality of selectively permeable hollow fibers suitable for the selective permeation of at least one fluid in a fluid mixture containing at least one other component, wherein the hollow fibers are positioned in a tubular shell and are assembled in the form of an elongated bundle, is enhanced by providing at least one flow diverter in the bundle. The flow diverter comprises a region of a plurality of hollow fibers embedded in a solid wherein the cross-sectional area of the flow diverter which is transverse to the orientation of the hollow fibers is a minor portion of the transverse cross-section sectional area of the bundle sufficient to divert fluid flow within the bundle. Advantageously, the portion of the plurality of hollow fibers encompassed in the flow diverter is insufficient to significantly adversely affect the total available membrane surface area for the selective permeation. In one embodiment, the bundle of hollow fibers substantially completely fills the cross-section of the tubular shell, and the at least one region extends around the transverse cross-section of the bundle encompassing hollow fibers at the periphery of the bundle. Desirably this surrounding flow diverter does not significantly increase the packing factor of the hollow fibers in the zone of the bundle surrounded by the flow diverter, and the flow diverter is adapted to be in an essentially fluid tight relationship with the shell.

Claims

1. A permeator for separating by the selective permeation of at least one fluid from a fluid mixture containing at least one other component comprising an elongated, essentially fluid impermeable tubular shell having at least one end adapted to receive a tube sheet;

a plurality of selectively permeable hollow fibers, said hollow fibers having an exterior surface and a bore and said hollow fibers being generally parallely positioned within the shell in the form of an elongated bundle wherein the bundle substantially completely fills the cross-section of the tubular shell;

at least one tube sheet, said tube sheet being in fluid tight relationship with said shell wherein at least one end of each of said hollow fibers is embedded in a fluid tight relationship in said at least one tube sheet and wherein said bores of said hollow fibers communicate through said tube sheet;

at least one fluid ingress port communicating through said shell and at least one longitudinally distant fluid egress port communicating through said shell, said ingress and egress ports being in communication with the exterior surface of the hollow fibers and adapted to provide axial flow of fluid in said shell; and

at least one fluid flow diverter in said bundle, said fluid flow diverter comprising a region of a plurality of hollow fibers embedded in an essentially fluid tight relationship in a solid wherein the cross-section of said fluid flow diverter which is transverse to the orientation of the hollow fibers is a minor portion of the transverse cross-section of said bundle sufficient to divert and enhance dispersion of fluid flow within the bundle.

2. The permeator of claim 1 in which the packing factor of hollow fibers adjacent to said at least one fluid flow diverter is substantially uniform.

3. The permeator of claim 1 in which the packing factor based on the inside cross-sectional dimensions of the shell and the cross-sectional area of the hollow fibers is at least about 35 percent.

4. The permeator of claim 3 in which the packing factor based on the inside cross-sectional dimensions of the shell and the cross-sectional area of the hollow fibers is about 45 to 60 percent.

5. The permeator of claim 1 in which the effective flow diverter surface area of a fluid flow diverter is less than about 25 percent of the interior cross-sectional area of the shell.

6. The permeator of claim 5 in which the effective flow diverter surface of a fluid flow diverter is about 2 to 25 percent of the interior cross-sectional area of the shell.

7. The permeator of claim 6 in which the thickness of a fluid flow diverter is less than about 5 centimeters.

8. The permeator of claim 6 in which the minor effective diverter dimension of a fluid flow diverter is less than about 20 centimeters.

9. The permeator of claim 6 having at least two fluid flow diverters which are less than 2 meters apart.

10. The permeator of claim 5 in which a fluid flow diverter extends around the periphery of the bundle.

11. The permeator of claim 10 in which said fluid flow diverter which extends around the periphery of the bundle contacts the interior surface of the shell.

12. The permeator of claim 11 in which a fluid flow diverter is within about 25 percent of the length of the bundle to a said at least one fluid ingress port.

13. The permeator of claim 12 in which a fluid flow diverter is within about 50 centimeters to a said at least one fluid ingress port.

14. The permeator of claim 11 in which a fluid flow diverter is within about 25 percent of the length of the bundle to a said at least one fluid egress port.

15. The permeator of claim 14 in which a fluid flow diverter is within about 50 centimeters to a said at least one fluid egress port.

16. The permeator of claim 5 in which a fluid flow diverter is within the bundle.

17. The permeator of claim 16 in which said fluid flow diverter within the bundle is adapted to support at least said hollow fibers embedded in the solid.

18. The permeator of claim 16 in which said fluid flow diverter within the bundle is a rod.

19. The permeator of claim 16 having at least two fluid flow diverters which are off-set.

20. The permeator of claim 1 in which the hollow fibers have an outside diameter of about 50 to 800 microns.

21. The permeator of claim 20 in which the hollow fibers have an outside diameter of about 350 to 800 microns.

22. The permeator of claim 1 in which the diameter of the bundle is about 0.02 to 0.5 meter and the length of the bundle is about 1 to 10 meters.