Intumescent compositions obtained by reacting polyisocyanates with phosphorus-containing products, polyesters and cyanuric acid and/or cyanuric acid derivatives

• US 4,367,295 A
• Filed: 06/23/1981
• Issued: 01/04/1983
• Est. Priority Date: 11/05/1980
• Status: Expired due to Fees

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: von Bonin, Wulf
• Primary Examiner(s): Welsh, Maurice J.
• Application Number:
  US06/276,562
• Time in Patent Office: 560 Days
• Field of Search: 521/165, 528/71, 528/72
• US Class Current: 521/165
• CPC Class Codes: C08G 18/3838 containing cyano groups
• CPC Class Codes: C08G 18/3851 containing three nitrogen atoms in the ring
• CPC Class Codes: C08G 18/3889 having nitrogen in addition to phosphorus
• CPC Class Codes: C08G 18/509 having nitrogen in addition to phosphorus
• CPC Class Codes: C09D 5/185 Intumescent paints
• CPC Class Codes: C09K 21/12 containing phosphorus
• CPC Class Codes: C09K 21/14 Macromolecular materials

Abstract

The present invention relates to intumescent compositions, which may be foamed, and which are obtained by reacting:

(1) polyisocyanates with

(2) phosphorus-containing condensation products having at least one hydroxyl group obtainable by condensing (i) primary or secondary aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic monoamines and/or polyamines, which mono- or polyamines may contain OH-groups; (ii) carbonyl compounds; and, (iii) dialkyl phosphites, and

(3) polyesters containing hydroxyl groups and having OH-numbers of from 140 to 300, obtained by reacting polycarboxylic acids containing from 2 to 10 carbon atoms with at least 2 polyols selected from two different groups of the following three:

(a) hydroxyl compounds containing more than three OH groups and having molecular weights of up to 200,

(b) hydroxyl compounds containing three OH groups and having molecular weights of up to 150,

(c) hydroxyl compounds containing two OH-groups and having molecular weights of up to 80, with the proviso that at least one polyol is selected from group (a), and

(4) cyanuric acid and/or cyanuric acid derivatives and

(5) optionally water and/or other organic compounds containing isocyanate-reactive hydrogen atoms.

Claims

1. Intumescent compositions, which may be foamed, and which are obtained by reacting:

(1) polyisocyanates with

(2) phosphorus-containing condensation products having at least one hydroxy group obtainable by condensing (i) primary or secondary aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic monoamines and/or polyamines, which mono- or polyamines may contain OH-groups;

(ii) carbonyl compounds; and

, (iii) dialkyl phosphites, and

(3) polyesters containing hydroxyl groups and having OH-numbers of from 140 to 300, obtained by reacting polycarboxylic acids containing from 2 to 10 carbon atoms with at least 2 polyols selected from two different groups of the following three;

(a) hydroxyl compounds containing more than three OH groups and having molecular weights of up to 200,

(b) hydroxyl compounds containing three OH groups and having molecular weights of up to 150,

(c) hydroxyl compounds containing two OH-groups and having molecular weights of up to 80, with the proviso that at least one polyol is selected from group (a), and

(4) cyanuric acid and/or cyanuric acid derivatives and

(5) optionally water and/or other organic compounds containing isocyanate-reactive hydrogen atoms.

2. The composition of claim 1 wherein, following condensation, said component (2) is alkoxylated.

3. The compositions of claim 1 obtained by reacting from 10 to 35 parts, by weight, of a polyisocyanate with 100 parts, by weight, of a mixture comprising from 5 to 50%, by weight, of phosphorus-containing condensation products, from 30 to 70%, by weight of polyesters, from 7 to 40%, by weight of cyanuric acid and/or derivatives, from 0 to 10%, by weight, of water, and from 0 to 25%, by weight, of other organic compounds containing isocyanate-reactive hydrogen atoms.

4. The composition as of claim 1, characterized in that said polyisocyanate is of the type obtained by phosgenating aniline/formaldehyde condensates.

5. The composition of claim 1, characterized in that the phosphorus compound corresponds to the following formula:

space="preserve" listing-type="equation">(RO).sub.2 PO--CH.sub.2 --N--(CHX--CHX--OH).sub.2,

wherein

R represents C₁ -C₈ alkyl or C₁ -C₈ hydroxyalkyl; and

X represents H or methyl.

6. The composition of claim 1, characterized in that a highly branched polyester of adipic acid, pentaerythritol, glycerol and ethylene glycol is used as the polyesters.

7. The composition of claim 1, characterized in that melamine is used as the cyanuric acid derivative.