Production of hydrogels

• US 4,367,323 A
• Filed: 12/02/1981
• Issued: 01/04/1983
• Est. Priority Date: 12/03/1980
• Status: Expired due to Term

• Current Assignee: Sumitomo Chemical Company Limited
• Original Assignee: Sumitomo Chemical Company Limited
• Inventors: Kitamura, Shuji, Niwano, Masahiro, Fujita, Fumio, Tatsukami, Yoshiharu, Oota, Masaru, Ogura, Masato, Oonishi, Toshihiro, Tamura, Toshifumi
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): Lipman, Bernard
• Application Number:
  US06/326,651
• Time in Patent Office: 398 Days
• Field of Search: 526/201, 524/460
• US Class Current: 526/201
• CPC Class Codes: A61L 15/60 Liquid-swellable gel-forming materials, e.g. super-absorbents
• CPC Class Codes: C08F 20/06 Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
• CPC Class Codes: C09K 17/22 Polyacrylates; Polymethacrylates

Abstract

The invention is to provide the methods for producing highly water-absorbable and water-retainable hydrogels having a large particle diameter together with a sufficient gel strength. The method is characterized by use of a specific dispersing agent in the water-in-oil type inverse phase suspension polymerization of an α,β-unsaturated carboxylic acid and/or its alkali metal salt. Due to the high water-absorbability and water-retainability, along with the superior gel strength and the stable gel structure, the hydrogels of the invention enlarge the conventional range of usages.

Claims

1. A method for producing hydrogels which comprises that, in producing the hydrogel by water-in-oil type inverse phase suspension polymerization of an α

,β

-unsaturated carboxylic acid monomer and/or its alkali metal salt in the presence or absence of a cross-linking agent, a carboxyl-containing polymer having affinity to the organic solvent is used as the dispersing agent.

2. The method for producing hydrogels according to claim 1, wherein the carboxyl-containing polymer is selected from the group consisting of methacrylic acid-methyl acrylate-2-ethylhexyl acrylate copolymer;

reaction product from maleic anhydride-modified liquid polybutadiene and 2-hydroxyethyl methacrylate;

graft polymer of ethylene-propylene-monomeric diene copolymer grafted with an α

,β

-unsaturated carboxylic acid and an alkyl or hydroxyalkyl α

,β

-unsaturated carboxylate; and

polybutadiene-butyl methacrylate-methacrylic acid graft copolymer.

3. The method for producing hydrogels according to claim 1, wherein the α

,β

-unsaturated carboxylic acid is any of acrylic acid and methacrylic acid.

4. The method for producing hydrogels according to claim 1, wherein the organic solvent is any of hexane, heptane, cyclohexane, benzene, xylene and toluene.