Chiral smectic C or H liquid crystal electro-optical device

• US 4,367,924 A
• Filed: 01/08/1980
• Issued: 01/11/1983
• Est. Priority Date: 01/08/1980
• Status: Expired due to Term

• Current Assignee: Clark, Noel A., Sven T. Lagerwall
• Original Assignee: Clark, Noel A., Sven T. Lagerwall
• Inventors: Clark, Noel A., Lagerwall, Sven T.
• Primary Examiner(s): Punter, William H.
• Application Number:
  US06/110,451
• Time in Patent Office: 1,099 Days
• Field of Search: 350/350 S, 350/351, 350/334-335, 350/347 E, 350/391, 350/348, 350/347 R, 350/347 V, 350/352
• US Class Current: 349/37
• CPC Class Codes: C09K 19/02 characterised by optical, electrical or physical properties of the components, in general
• CPC Class Codes: C09K 19/0225 Ferroelectric
• CPC Class Codes: G02F 1/141 using ferroelectric liquid crystals
• CPC Class Codes: Y10S 359/90 Methods

Abstract

An electro-optical device including a chiral smectic C or H liquid crystal disposed between flat plates treated to enforce molecular orientation parallel to the plates. The plates are spaced by a distance sufficiently small to ensure unwinding of the helix typical in a bulk of the material to form two stable states of the orientation field. The liquid crystal is switched between two stable states by reversing the polarity of an externally applied electric field to make a bistable light valve or other electro-optical devices.

Claims

1. A liquid crystal electro-optical device comprising:

a quantity of chiral, at least one of smectic C and smectic H, liquid crystal having a plurality of adjacently disposed layers each comprised of a plurality of molecules, each molecule having a long axis;

first and second means, perpendicular to and contiguous with said layers, for aligning the long axes of said molecules adjacent to said first and second means parallel to said first and second means, said molecules of said layers in a bulk of said liquid crystal forming helixes having axes perpendicular to said layers, the distance between said first and second means being less than the distance at which said helixes form in the absence of an electric field, said first and second means causing said long axes to assume one of a first and second stable orientation;

means for applying an electric field to at least a portion of said layers, said electric field being parallel to said layers and perpendicular to said first and second means, and for reversing the direction of said electric field, the strength of said electric field being sufficient to shift the long axis of molecules in said portion of said layers from said first orientation to said second orientation upon application of said electric field in a direction reversed from the direction of said electric field previously applied; and

means for processing light passing through said liquid crytstal so that light passing through portions of said liquid crystal having said first orientation can be distinguished from light passing through portions of said liquid crystal having said second orientation.

3. A device as in claim 1 or 2 wherein said liquid crystal is any one of the group consisting of decycloxytbenzylidene p'"'"'-amino 2 methyl butyl cinnamate and hexyloxy-benzylidene p-amino 2 chloropropyl cinnamate.

4. A device as in claim 3 wherein said first and second means comprises plates having at least one of a glass and a tin oxide surface contiguous with said liquid crystal.

5. A device as in claim 1 or 2 wherein said applying means comprises first and second electrodes disposed adjacent to said first and second means, respectively, and means for applying a voltage across said first and second electrodes.

6. A device as in claim 1 or 2 wherein:

said liquid crystal has at least a first optical axis in a first direction during said first orientation and in a second direction during said second orientation; and

said first and second means, said applying means and said processing means comprise first and second plates having surface means contiguous with said liquid crystal for aligning said long axis of molecules adjacent to said surface means parallel to said surface means, said first plate including means for polarizing light in said first direction and said second plate including means for polarizing light in a direction perpendicular to said first direction, first and second electrodes disposed adjacent to said first and second plates, respectively, and means for applying a voltage across said first and second electrodes.

7. A device as in claim 1 or 2 wherein said helixes have a pitch and the distance between said first and second means is no more than five times said pitch.

10. A device as in claim 1, 2, 8 or 9 wherein said orientation remains after said electric field is removed.

11. A device as in claim 1, 2, 8 or 9 wherein said liquid crystal has at least a first optical axis in a first direction in said first orientation and in a second direction in said second orientation;

and

said means for processing includes first means for polarizing light in said first direction and second means for polarizing light perpendicular to said first direction, said first and second polarizing means being disposed on opposite sides of said liquid crystal.

16. A device as in claim 1, 2, 8 or 9 wherein said aligning means includes first ridges extending parallel to said first orientation and second ridges extending parallel to said second orientation.

22. A device as in claim 1 or 2 wherein:

said liquid crystal has at least a first optical axis in a first direction during said first orientation and in a second direction during said second orientation; and

said first and second means, said applying means and said processing means comprise first and second plates having surface means contiguous with said liquid crystal for aligning said long axis of molecules adjacent to said surface means parallel to said surface means, said first plate including means for polarizing light in a third direction and said second plate including means for polarizing light in a fourth direction, said third and fourth directions causing said polarizing means to induce birefringence colors in transmitted light upon change in said optic axis reorientation, first and second electrodes disposed adjacent to said first and second plates, respectively, and means for applying a voltage across said first and second electrodes.

23. A device as in claim 1, 2, 8 or 9 wherein said liquid crystal has at least a first optical axis in a first direction in said first orientation and in a second direction in said second orientation;

and

said means for processing includes first means for polarizing light in a third direction and second means for polarizing light in a fourth direction, said third and fourth directions causing said polarizing means to induce birefringence colors in transmitted light upon change in said optic axis reorientation, said first and second polarizing means being disposed on opposite sides of said liquid crystal.

2. A liquid crystal electro-optical device comprising:

a quantity of chiral, at least one of smectic C and smectic H, liquid crystal, said liquid crystal having a plurality of adjacently disposed layers each comprised of a plurality of molecules, each molecule having a long axis;

first and second means, perpendicular to and contiguous with said layers, for aligning said long axis of molecules adjacent to said first and second means parallel to said first and second means, said molecules of said layers in a bulk of said liquid crystal forming helixes having axes perpendicular to said layers, the distance between said first and second means being less than the distance at which said helixes form in the absence of an electric field, said first and second means causing said long axes to assume one of a first and second stable orientation;

means for selectively applying an electric field to any of a plurality of portions of said layers, said electric field being parallel to said layers and perpendicular to said first and second means, and for reversing the direction of said electric field, the strength of said electric field being sufficient to shift molecules in said any of a plurality of portions from said first orientation to said second orientation upon application of said electric field in a direction reversed from the direction of said electric field previously applied; and

means for processing light passing through said liquid crystal so that light passing through portions of said liquid crystal having said first orientation can be distinguished from light passing through portions of said liquid crystal having said second orientation.

12. A device as in claim 2 wherein said applying means comprises:

a plurality of first electrodes extending in a direction, a plurality of second electrodes extending perpendicular to said direction, said first electrodes being disposed on a side of said liquid crystal opposite said second electrodes;

and means for selectively applying a voltage across any of said first electrodes and any of said second electrodes to selectively apply said field to any of a plurality of portions of said liquid crystal.

8. A liquid crystal electro-optical device comprising:

a quantity of chiral, at least one of smectic C and smectic H, liquid crystal having a plurality of adjacently disposed layers, each comprised of a plurality of molecules, each molecule having a long axis;

first and second plates perpendicular to said layers, said first and second plates including means, contiguous with said liquid crystal for aligning the long axis of said molecules adjacent to said aligning means parallel to said plates, said molecules of said layers in a bulk of said liquid crystal forming helixes having axes perpendicular to said layers, the distance between said first plate and said second plate being less than the distance at which said helixes form in the absence of an electric field;

a first electrode disposed on one side of said liquid crystal parallel to said first and second plates;

a second electrode disposed on the other side of said liquid crystal parallel to said first and second plates and opposite said first electrode;

means for applying a voltage across said first and second electrodes for creating an electric field parallel to said layers and perpendicular to said plates, and for reversing the polarity of said voltage, said voltage being such that the strength of said electric field is sufficient to shift the long axis of molecules in a portion of said layers between said electrodes from a first orientation to a second orientation upon application of said electric field in a direction reversed from the direction of said electric field previously applied; and

means for processing light passing through said liquid crystal so that light passing through portions of said liquid crystal having said first orientation can be distinguished from light passing through portions of said liquid crystal having said second orientation.

13. A device as in claim 8 or 9 wherein said helixes have a pitch and the distance between said first and second plates is no more than five times said pitch.

14. A device as in claim 8 or 9 wherein said liquid crystal is any one of the group consisting of decycloxybenzylidene p'"'"'-amino 2 methyl butyl cinnamate and hexyloxybenzylidene p'"'"'-amino 2 chloropropyl cinnamate.

15. A device as in claim 14 wherein said first and second means comprises plates having at least one of a glass surface and a tin oxide surface contiguous with said liquid crystal.

9. A liquid crystal electro-optical device comprising:

a quantity of chiral, at least one of smectic C and smectic H, liquid crystal having a plurality of adjacently disposed layers, each comprised of a plurality of molecules, each molecule having a long axis;

first and second plates perpendicular to said layers, said first and second plates including means, contiguous with said liquid crystal, for aligning the long axis of said molecules adjacent to said aligning means parallel to said plates, said molecules of said layers in a bulk of said liquid crystal forming helixes having axes perpendicular to said layers, the distance between said first plate and said second plate being less than the distance at which said helixes form in the absence of an electric field;

a plurality of first electrodes disposed on one side of said liquid crystal parallel to said first and second plates;

a plurality of second electrodes disposed on the other side of said liquid crystal parallel to said first and second plates and transverse to said first electrodes;

means for selectively applying a voltage across any of said first electrodes and any of said second electrodes for creating an electric field in any of a plurality of portions of said liquid crystal parallel to said layers and perpendicular to said plates, and for reversing the polarity of said voltage, said voltage being such that the strength of said electric field is sufficient to shift the long axis of molecules in said any of a plurality of portions from a first orientation to a second orientation upon application of said electric field in a direction reversed from the direction of said electric field previously applied; and

means for processing light passing through said liquid crystal so that light passing through portions of said liquid crystal having said first orientation can be distinguished from light passing through portions of said liquid crystal having said second orientation.

17. A process of making an electro-optical device including a chiral, at least one of smectic C and smectic H, liquid crystal, molecules in a bulk of said liquid crystal forming helixes, first and second means for containing said liquid crystal, means for applying an electric field to at least a portion of said liquid crystal and means for processing light passing through said liquid crystal, said method comprising:

aligning the molecules of said liquid crystal adjacent to said first and second means parallel to said first and second means, but free to move between at least two particular orientations; and

suppressing the formation of said helixes.

18. A process of making an electro-optical device including a chiral, at least one of smectic C or smectic H, liquid crystal, molecules in a bulk of said liquid crystal forming helixes, first and second means for containing said liquid crystal, means for applying an electric field to at least a portion of said liquid crystal and means for processing light passing through said liquid crystal, said method comprising:

disposing said first means a distance from said second means less than the distance at which said helixes form;

first cooling said liquid crystal from at least one of an isotropic and nematic phases;

aligning the molecules of said liquid crystal adjacent to said first and second means parallel to said first and second means, but free to move between at least two particular orientations; and

orienting said liquid crystal during said first cooling step to form at least one of smectic C and smectic H phases in flat layers perpendicular to said first and second means.

20. A process as in claim 19 or 18 wherein said first cooling step is from a nematic phase and said orienting step comprises the step of applying a field parallel to said first and second means.

21. A process as in claim 19 or 18 wherein said orienting step comprises the step of gently moving said first means parallel to and with respect to said second means.

19. A process of making an electro-optical device including a chiral, at least one of smectic C or smectic H, liquid crystal, molecules in a bulk of said liquid crystal forming helixes, first and second means for containing said liquid crystal, means for applying an electric field to at least a portion of said liquid crystal and means for processing light passing through said liquid crystal, said method comprising:

disposing said first means a distance from said second means less than the distance at which said helixes form;

first cooling said liquid crystal from at least one of an isotropic and nematic phases to a smectic A phase;

aligning the molecules of said liquid crystal adjacent to said first and second means parallel to said first and second means, but free to move between at least two particular orientations;

orienting said liquid crystal during said first cooling step to form said smectic A liquid crystal in flat layers perpendicular to said first and second means; and

second cooling of said liquid crystal from said smectic A phase to said at least one of smectic C and smectic H phases.

24. A process as in claim 19 wherein:

said first cooling step is from a nematic phase; and

said orienting step comprises the step of gently moving said first means parallel to and with respect to said second means while applying a magnetic field parallel to said first and second means.