Apparatus for chemical conversion of materials and particularly the conversion of cellulose waste to glucose

• US 4,368,079 A
• Filed: 05/18/1981
• Issued: 01/11/1983
• Est. Priority Date: 03/18/1980
• Status: Expired due to Fees

• Current Assignee: New York University
• Original Assignee: New York University
• Inventors: Brenner, Walter, Rugg, Barry A.
• Primary Examiner(s): Marcus, Michael S.
• Application Number:
  US06/264,245
• Time in Patent Office: 603 Days
• Field of Search: 127/1, 127/28, 127/37, 422/137, 366/83, 366/85, 366/88, 366/90, 162/56, 162/236, 425/204, 425/208
• US Class Current: 127/1
• CPC Class Codes: B01J 3/042 in the form of a tube
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32

Abstract

A process and apparatus for the conversion of waste cellulose to glucose wherein an aqueous slurry of waste cellulose is acid hydrolyzed includes continuously feeding an aqueous slurry of waste cellulose into an inlet port with a twin screw extruder, continuously reacting the cellulose with water in the presence of an acid catalyst at elevated temperature and pressure in a reaction zone disposed in the extruder between the inlet port and an outlet port while continuously conveying same to the outlet port and at least quasi-continuously discharging the reacted cellulose from the extruder while maintaining the elevated temperature and pressure in the reaction zone by forming a dynamic seal zone at the upstream end of the reaction zone and valving the discharge downstream of the outlet port.

Claims

1. An apparatus for the conversion of waste cellulose to glucose by dilute acid hydrolysation, comprising:

extruding means including a housing having an inlet port receptive of cellulose to be converted, an outlet port, a reaction zone therebetween and twin corotational screws for continuously conveying the cellulose through the reaction zone and to the outlet port;

means for continuously injecting dilute sulfuric acid into the reaction zone;

means for producing an elevated temperature and pressure within the reaction zone including means for continuously injecting steam or superheated water at elevated pressure into the reaction zone;

means for continuously feeding the cellulose to the inlet port;

means for at least quasi-continuously discharging the reacted cellulose from the extruding means while maintaining the elevated temperature and pressure within the reaction zone including means for forming a dynamic seal at the upstream end of the reaction zone;

valve means disposed downstream of the outlet port for controlling the discharge; and

means for cyclically activating said valve means.

2. The apparatus according to claim 1, wherein the hydrolyzing means further comprises means for pretreating the aqueous slurry before being received by the feeding means including means for irradiating the aqueous slurry.

3. The apparatus according to claim 1, wherein the means forming the dynamic seal comprises a portion of the screws having a left hand pitch thread and a right hand pitch thread upstream thereof and downstream thereof in the reaction zone.

4. The apparatus according to claim 1 or claim 3, wherein the valve means comprises a hydraulically activated ball valve.

5. The apparatus according to claim 4, wherein the means for continuously feeding comprises means for continuously removing excess liquid upstream of the reaction zone.

6. The apparatus according to claim 5, wherein the means for continuously feeding comprises means for cram feeding the aqueous slurry into the inlet port.