Liquid detergent of controlled viscosity

• US 4,368,147 A
• Filed: 06/02/1981
• Issued: 01/11/1983
• Est. Priority Date: 10/03/1974
• Status: Expired due to Fees

• Current Assignee: Colgate-Palmolive Company
• Original Assignee: Colgate-Palmolive Company
• Inventors: Chirash, William, Inamorato, Jack T.
• Primary Examiner(s): Willis, Jr., P. E.
• Application Number:
  US06/269,917
• Time in Patent Office: 588 Days
• Field of Search: 252/174.21, 252/550, 252/545, 252/551, 252/555, 252/559, 252/108, 252/DIG. 1, 252/DIG. 14, 252/548
• US Class Current: 510/340
• CPC Class Codes: C11D 1/72 Ethers of polyoxyalkylene glycols
• CPC Class Codes: C11D 17/003 Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
• CPC Class Codes: C11D 3/2006 Monohydric alcohols
• CPC Class Codes: C11D 3/2079 Monocarboxylic acids-salts thereof

Abstract

A liquid detergent having a viscosity in the range of 40 to 120 centipoises at 24° C. and which is fluid at 7° C. which consists essentially of, by weight, from 10% to 60% of a water soluble C₂ -C₃ alkoxylated C₁₀ -C₁₈ alkanol nonionic detergent; 4% to 12% of a C₂ -C₃ alkanol, the proportion of alcohol being such that the physical properties of the liquid detergent would be unsatisfactory in the absence of a viscosity control and gel prevention agent 1% to 6% of sodium or potassium formate as a viscosity control and gel prevention agent and 22 to 84.5% of water.

Claims

1. A liquid detergent having a viscosity in the range of 40 to 120 centipoises at 24°

C. and which is fluid at 7°

C. which consists essentially of, by weight, from 10% to 60% of a water-soluble C₂ -C₃ alkoxylated C₁₀ -C₁₈ alkanol nonionic detergent;

4% to to 12% of a C₂ -C₃ alkanol, the proportion of alcohol being such that the physical properties of the liquid detergent would be unsatisfactory in the absence of a viscosity control and gel prevention agent;

1% to 6% of sodium or potassium formate as a viscosity control and gel prevention agent and 22 to 84.5% of water.

2. A liquid detergent according to claim 1 in which the nonionic detergent is a polyethoxylated alkanol which is present in an amount of 20% to 40% by weight, said lower alkanol is selected from the group consisting of ethanol, isopropanol and mixtures thereof, and which contains, in addition, 4 to 12% by weight of a water-soluble synthetic organic anionic detergent salt having carboxylate, sulfate or sulfonate group in its molecular structure and selected from the group consisting of sodium, potassium, ammonium and triethanolamine salts, and 29 to 69.5% by weight of water.

3. A liquid detergent according to claim 2 wherein the nonionic detergent is a polyethoxylated C₁₀ -C₁₈ alkanol having from 3 to 12 ethylene oxide groups per mol and the anionic detergent is selected from the group consisting of water-soluble salts of polyethoxy C₁₀ -C₁₈ alkanol ether sulfates having from 2 to 8 ethylene oxide groups per mol and C₁₀ -C₁₅ alkyl benzene sulfonates.

4. A liquid detergent according to claim 3 wherein said alkanol is ethanol which is present in an amount of 4% to 8% by weight and said viscosity control agent is sodium formate.

5. A liquid detergent according to claim 3 wherein the nonionic detergent is a polyethoxylated C₁₁ -C₁₅ alkanol having from 5 to 9 ethoxy groups per mol and the anionic detergent is a sodium salt.

6. A liquid detergent according to claim 4 wherein said nonionic detergent is present in an amount of 30% to 40% by weight and said anionic detergent is a sodium polyethoxy linear C₁₂ -C₁₅ alkanol sulfate having from 2 to 5 ethylene oxide groups per mol which is present in an amount of 4% to 12% by weight.

7. A liquid detergent according to claim 4 wherein said nonionic detergent is present in an amount of 30% to 40% by weight and said anionic detergent is a sodium C₁₀ -C₁₄ alkylbenzene sulfonate which is present in an amount of 4% to 12% by weight.

8. A method of washing laundry which consists essentially of washing laundry in water containing 0.05% to 0.03% by weight of the liquid detergent of claim 1, said water being at a temperature of 10°

C. to 80°

C.

9. A method of controlling the viscosity of a liquid detergent consisting essentially of, by weight, 10% to 60% of a water-soluble C₂ -C₃ alkoxylated C₁₀ -C₁₈ alkanol nonionic detergent, 4% to 12% of C₂ -C₃ alkanol, the proportion of said alcohol being insufficient to obtain the desired viscosity range and to maintain fluidity at 7°

C., and water which comprises incorporating from 1% to 6% by weight of a water-soluble sodium or potassium formate in said liquid detergent, the mixture of said alcohol and said formate being effective to provide a composition which is fluid at 7°

C. and which has a reduced viscosity as compared with the same composition not containing the formate salt.