Printed circuits

• US 4,368,281 A
• Filed: 09/15/1980
• Issued: 01/11/1983
• Est. Priority Date: 09/15/1980
• Status: Expired due to Term

• Current Assignee: AMP Incorporated (Johnson Controls International plc)
• Original Assignee: AMP Incorporated (Johnson Controls International plc)
• Inventors: Shaak, Ray N., Crumley, J. A., Whitaker, Dewey R., Brummett, Charles R.
• Primary Examiner(s): Briggs, Sr., Wilbert J.
• Assistant Examiner(s): Lilling, Herbert J.
• Application Number:
  US06/187,102
• Time in Patent Office: 848 Days
• Field of Search: 260/33.8 R, 427/98, 524/462, 524/465, 524/469, 524/473, 524/413, 524/431, 524/175, 524/176, 523/458, 523/459, 523/462, 106/20
• US Class Current: 523/458
• CPC Class Codes: C09D 11/102 containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
• CPC Class Codes: H05K 1/095 for polymer thick films, i.e. having a permanent organic polymeric binder

Abstract

Ink compositions especially suitable for printing electronic circuit patterns on a substrate such as a flexible polyester substrate; methods for developing electrolessly and electrolytically the circuit configurations as articles of manufacture; flexographic printing with the ink composition has been disclosed as the preferred method.

Claims

1. An ink for printing of electronic circuits on a substrate comprising:

a substrate compatible polymer base resin adhesive of a polyester, a polyimide, polyimide-amide, poly-parabanic acid, polycarbonate, polysulfones, polyamine, cellulose triacetate, polyepoxides, or polyurethane, a filler from 0 to about 16%, by weight, based on total solids content of the ink, and from about 5 to about 16%, by weight, based on total solids content of ink, a coordination complex of a metal of a formula LmZXn, wherein L is a ligand or unsaturated organic group, Z is palladium, platinum, nickel or copper metal base of the complex, X is halide, alkyl group, or bidentate ligand and m and n are integers wherein m is from 1 to 4 and n is from 0 to 3, a halogenated alkyl compound of 2 to 4 carbon atoms as a solvent for said ink, said ink having a viscosity of 80 to 2000 cps.

2. An ink for printing of electronic circuits on a substrate comprising:

a polyester base resin adhesive, a filler from 0 to about 15%, by weight, based on total solids content of ink, and from about 5 to about 15%, by weight, based on total solids content of ink, of a coordination complex of palladium of a formula LmZXn wherein L is a ligand or unsaturated organic group, Z is palladium, platinum, nickel or copper metal base of the complex, X is a halide, alkyl group, or bidentate ligand and m and n are integers wherein m is from 1 to 4 and n is from 0 to 3, a halogenated alkyl compound, such as of 2 to 4 carbon compounds, as a solvent for the said ink, said ink having a viscosity of 80 to 2000 cps.

3. The ink as defined in claim 2, wherein the substrate polymer is a polyester base.

4. The ink as defined in claim 2, wherein the polymer base resin adhesive contains a crosslinking agent therefor.

5. The ink as defined in claim 4, wherein the crosslinking agent is an isocyanate crosslinking agent.

6. The ink as defined in claim 2, wherein the coordination complex of palladium is bisbenzonitrile palladium dichloride.

7. The ink as defined in claim 2, wherein the ink contains a pigment as a filler and wherein the pigment is titanium dioxide.

8. The ink as defined in claim 2, wherein the filler is ferric oxide.

9. The ink as defined in claim 2, wherein the solvent is 1,1,2-trichloroethane.

10. The ink as defined in claim 2, wherein the same contains from 0 to 2% by weight of an organo functional titanate coupling agent as an additive for said filler.

11. The ink composition as defined in claim 2, wherein the same comprises:

total solids from 12 to 55% by weight, resin solids from 5 to 20% by weight, crosslinking agent from 0 to 4% by weight, pigment from 0 to 16% by weight, coordination complex from 5 to 15% by weight, and solvent or solvent mixtures from 88 to 45% by weight.

12. The ink as defined in claim 11, wherein the same has a total solids content from 15 to 20% by weight.