Solid non-azide nitrogen gas generant compositions

• US 4,369,079 A
• Filed: 12/31/1980
• Issued: 01/18/1983
• Est. Priority Date: 12/31/1980
• Status: Expired due to Term

• Current Assignee: Autoliv ASP Incorporated (Autoliv Incorporated)
• Original Assignee: Thiokol Corporation (Howmet Aerospace, Inc.)
• Inventors: Shaw, Graham C.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US06/221,942
• Time in Patent Office: 748 Days
• Field of Search: 149/2, 149/45, 149/61, 264/3 C, 280/728
• US Class Current: 149/2
• CPC Class Codes: C01B 21/02 Preparation of nitrogen by decomposition of ammonia C01B3/047
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

A solid non-azide, non-toxic, substantially moisture-free nitrogen gas generating composition intended for use in the deployment of inflatable safety crash bags for driver and passenger protection in vehicles consists essentially of a metal salt of a non-hydrogen containing tetrazole compound selected from the group consisting of alkali metal salts and alkaline earth metal salts and an oxidizer containing nitrogen and a member selected from the group consisting of an alkali metal and an alkaline earth metal, the tetrazole being an azobitetrazole, and examples of the oxidizer being sodium nitrate, sodium nitrite and potassium nitrate.

Claims

1. A solid pellet for generating non-toxic, substantially moisture-free nitrogen gas consisting essentially of a metal salt of a non-hydrogen containing tetrazole compound selected from the group consisting of alkali metal salts, alkaline earth metal salts and admixtures thereof and an oxidizer containing nitrogen and a member selected from the group consisting of alkali metal nitrates, alkali metal nitrites, and admixtures thereof.

2. The pellet of claim 1 wherein said tetrazole is azobitetrazole.

3. The pellet of claim 1 wherein said oxidizer is an alkali metal nitrate.

4. The pellet of claim 3 wherein said oxidizer is an alkali nitrite.

5. The pellet of claim 3 wherein said oxidizer is sodium nitrate.

6. The pellet of claim 4 wherein said oxidizer is sodium nitrate.

7. The pellet of claim 3 wherein said oxidizer is potassium nitrate.

8. The pellet of claim 1 wherein said tetrazole compound is present in an amount from about 35 to about 60 weight percent and said oxidizer is present in an amount from 40 to about 65 weight percent.

9. In a method for inflating air bag comprising igniting a pellet of pyrotechnic material to generate a gas, filtering and cooling the generated gas, and using the filtered and cooled gas to inflate the air bag, the improvement comprising, the step of using a solid pellet for generating non-toxic, substantially moisture-free, nitrogen gas consisting essentially of a metal salt of a non-hydrogen containing tetrazole compound selected from the group consisting of alkali metal salts, alkaline earth metal salts and admixtures thereof and an oxidizer containing nitrogen and a member selected from the group consisting of alkali metal nitrates, alkali metal nitrites, and admixtures thereof.

10. A method for the generation of a substantially moisture-free, non-toxic nitrogen gas which comprises:

a. compounding a gas generant composition consisting essentially of a non-hydrogen containing metal salt of a tetrazole compound selected from the group consisting of alkali metal salts, alkaline earth metal salts and admixtures thereof and an oxidizer containing nitrogen and a member selected from the group consisting of alkali metal nitrates, alkali metal nitrites, and admixtures thereof;

b. pelletizing said composition;

c. igniting said pelletized composition to produce a substantially moisture-free, non-toxic nitrogen gas.

11. The method of claim 10 whereby said non-toxic nitrogen gas contains carbon monoxide in non-toxic amounts.

12. The method of claim 10 whereby said non-toxic nitrogen gas contains carbon monoxide in amounts less than about 1000 ppm.

13. The method of claim 10 whereby said tetrazole compound is present in an amount from about 35 to about 60 weight percent and said oxidizer is present in an amount from about 40 to 65 weight percent.