Pyrotechnic non-azide gas generants based on a non-hydrogen containing tetrazole compound

• US 4,370,181 A
• Filed: 12/31/1980
• Issued: 01/25/1983
• Est. Priority Date: 12/31/1980
• Status: Expired due to Term

• Current Assignee: Autoliv ASP Incorporated (Autoliv Incorporated)
• Original Assignee: Thiokol Corporation (Howmet Aerospace, Inc.)
• Inventors: Lundstrom, Norman H., Shaw, Graham C.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US06/221,943
• Time in Patent Office: 755 Days
• Field of Search: 149/2, 149/109.2, 149/109.4, 264/3 C, 280/728
• US Class Current: 149/2
• CPC Class Codes: C01B 21/02 Preparation of nitrogen by decomposition of ammonia C01B3/047
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

A solid non-azide composition for generating non-toxic nitrogen gas intended for use in the deployment of inflatable safety crash bags for driver and passenger protection in vehicles consists essentially of a non-hydrogen containing tetrazole compound and a non-oxygen containing oxidizer, examples of the tetrazole being di-alkali metal or mono-alkaline earth metal salts of 5,5'"'"'-bitetrazole, and examples of the oxidizer being sulfur, molybdenum disulfide, chromium trichloride and iron trifluoride.

Claims

1. A solid pellet for generating non-toxic nitrogen gas consisting essentially of a non-hydrogen containing tetrazole compound and a non-oxygen containing oxidizer selected from the group consisting of sulfur, chromium trichloride, molybdenum disulfide, iron trifluoride, and admixture thereof.

2. The pellet of claim 1 wherein said tetrazole comprises a bitetrazole.

3. The pellet of claim 1 wherein said tetrazole comprises metal salt of a tetrazole compound.

4. The pellet of claim 3 wherein said tetrazole compound comprises a bitetrazole.

5. The pellet of claim 3 wherein said metal salt of a tetrazole is selected from the group consisting of alkali metal salts, alkaline earth metal salts, manganese, and admixtures thereof.

6. The pellet of claim 5 wherein said metal salt of a tetrazole is disodium bitetrazole.

7. The pellet of claim 5 wherein said metal salt of a tetrazole is dipotassium bitetrazole.

8. The pellet of claim 5 wherein said metal salt of a tetrazole is calcium bitetrazole.

9. The pellet of claim 1 wherein said oxidizer is sulfur.

10. The pellet of claim 1 wherein said oxidizer is chromium trichloride.

11. The pellet of claim 1 wherein said oxidizer is molybdenum disulfide.

12. The pellet of claim 1 wherein said oxidizer is iron trifluoride.

13. The pellet of claim 1 wherein said tetrazole compound is present in an amount from about 60 to about 90 weight percent and said oxidizer in an amount from about 10 to about 40 weight percent.

14. In a method for inflating an air bag comprising igniting a pellet of pyrotechnic material to generate a gas, filtering and cooling the generated gas, and rising the filtered and cooled gas to inflate the air bag, the improvement comprising the step of using a solid pellet for generating non-toxic nitrogen gas consisting essentially of a non-hydrogen containing tetrazole compound and a non-oxygen containing oxidizer selected from the group consisting of sulfur, chromium trichloride, molybdenum disulfide, iron trifluoride, and admixtures thereof, whereby the air bag when inflated contains a concentration of less than 30 ppm of hydrogen sulfide.

15. A method for the generation of a non-toxic nitrogen gas which comprises:

(a) compounding a gas generant composition consisting essentially of a non-hydrogen containing tetrazole compound and a non-oxygen containing oxidizer selected from the group consisting of sulfur, chromium trichloride, molybdenum disulfide, iron trifluoride, and admixtures thereof;

(b) pelletizing said composition; and

(c) igniting said pelletized composition to produce a non-toxic nitrogen gas.

16. The method of claim 15, whereby said non-toxic nitrogen gas contains less than 30 ppm hydrogen sulfide.

17. The method of claim 15, whereby said non-toxic nitrogen gas contains carbon monoxide and hydrogen cyanide in non-toxic amounts.

18. The method of claim 15, whereby said tetrazole compound is present in an amount from about 60 to about 90 weight percent and said oxidizer in an amount from 10 to 40 weight percent.