Machine for solid phase polymerization

• US 4,370,302 A
• Filed: 12/30/1980
• Issued: 01/25/1983
• Est. Priority Date: 01/04/1980
• Status: Expired due to Term

• Current Assignee: Teijin Limited
• Original Assignee: Teijin Limited
• Inventors: Suzuoka, Akihiro, Matsumura, Eiji, Sasaki, Katsushi, Okuhira, Toshifumi
• Primary Examiner(s): Marcus, Michael S.
• Application Number:
  US06/221,204
• Time in Patent Office: 756 Days
• Field of Search: 422/131, 422/135, 422/136, 422/137, 422/219, 422/233, 422/225, 366/309, 366/310, 366/312, 366/319, 366/320, 366/139, 198/670, 198/676, 528/309, 528/484
• US Class Current: 422/137
• CPC Class Codes: B01J 19/18 Stationary reactors having moving elements inside B01J19/08, B01J19/26 take precedence
• CPC Class Codes: B01J 2208/00212 Plates; Jackets; Cylinders
• CPC Class Codes: B01J 2208/00371 gaseous
• CPC Class Codes: B01J 2208/0053 Controlling multiple zones along the direction of flow, e.g. pre-heating and after-cooling
• CPC Class Codes: B01J 2208/0061 Controlling the level
• CPC Class Codes: B01J 2219/182 horizontal
• CPC Class Codes: B01J 2219/185 vertical
• CPC Class Codes: B01J 3/006 Processes utilising sub-atmospheric pressure; Apparatus therefor
• CPC Class Codes: B01J 3/02 Feed or outlet devices therefor
• CPC Class Codes: C08G 63/785 characterised by the apparatus used
• CPC Class Codes: C08G 63/80 Solid-state polycondensation

Abstract

A machine for solid phase polymerization comprises: a system for supplying particles of a synthetic polymer; a reaction system for effecting solid phase polymerization of the particles, fed from the supplying system, under a vacuum and heated condition; and a system for discharging the solid phase polymerized particles. The supplying system includes a pre-treatment apparatus comprising: a pre-crystallizer of a vertical agitator type; and a beater of a horizontal type. The reaction system includes a horizontal reaction vessel having a horizontal rotary shaft with a helically formed screw vane. The screw vane has a multiplicity of small through-apertures, and scrapers extend axially extending between adjacent screw vane portions. Intermediate pots having specially designed vacuum breakers are disposed at locations between the reaction system and the supplying system and between the reaction system and the discharging system.

Claims

1. A machine for solid phase polymerization comprising means defining a system for supplying particles of a synthetic polymer, means defining a reaction system for effecting solid phase polymerization under a vacuum and heated conditions to said particles of a synthetic polymer fed from said supplying system, and means defining a system for discharging said particles of a synthetic polymer which have been subjected to said solid phase polymerization in said reaction system so that their degree of polymerization is increased, characterized in that said reaction system comprises a horizontal reaction vessel, a shaft rotatable about a horizontal axis within said reaction vessel, at least one screw vane secured to said rotatable shaft and having a multiplicity of small apertures formed therein, and scrapers axially extending between adjacent screw vane portions, said supplying system comprises a pre-treatment apparatus comprising a precrystallizer wherein particles are precrystallized and a beater for separating stuck particles connected to the exit of said precrystallizer, whereby said particles of a synthetic polymer are precrystallized and beaten by means of said pre-treatment apparatus and then are fed to said reaction system, said machine further comprising intermediate vessels disposed for communication between said reaction system and said discharging system, respectively, and vacuum breakers comprising particle shutters and vacuum valves located downstream of said shutters disposed at the particle supply side and the particle discharge side of said intermediate vessels, respectively.

2. A machine for solid phase polymerization according to claim 1, characterized in that said beater comprises a rotary basket rotatable about a horizontal axis, movable rods horizontally projecting from said rotary basket and disposed along two circles coaxial with each other about said horizontal axis, and a plurality of stationary horizontal rods inserted into a space between said two coaxial circles.

3. A machine for solid phase polymerization according to claim 1, characterized in that said pre-crystallizer comprises a vertical vessel communicating with an external heat source so that hot air is fed into said vertical vessel, a vertical spindle rotatable about a vertical axis within said vertical vessel, and a plurality of agitating bars fixed on said vertical spindle.

4. A machine for solid phase polymerization according to claim 1, characterized in that:

said pre-crystallizer comprises a vertical vessel communicating with an external heat source so that hot air is fed into said vertical vessel, a vertical spindle rotatable about a vertical axis within said vertical vessel, and a plurality of agitating bars fixed on said vertical spindle; and

said beater comprises a rotary basket rotatable about a horizontal axis, movable rods horizontally projecting from said rotary basket and disposed along two circles coaxial with each other about said horizontal axis, and a plurality of stationary horizontal rods inserted into a space between said two coaxial cables.