Preparation of pure magnesian values

• US 4,370,307 A
• Filed: 10/09/1980
• Issued: 01/25/1983
• Est. Priority Date: 02/29/1980
• Status: Expired due to Term

• Current Assignee: Martin Marietta Magnesia Specialties, LLC
• Original Assignee: Martin Marietta Corporation
• Inventors: Judd, George G.
• Primary Examiner(s): Straub, Gary P.
• Application Number:
  US06/192,301
• Time in Patent Office: 838 Days
• Field of Search: 423/430, 423/432, 423/169, 423/165
• US Class Current: 423/432
• CPC Class Codes: C01F 5/02 Magnesia
• CPC Class Codes: C01F 5/24 Magnesium carbonates
• CPC Class Codes: C01P 2006/80 Compositional purity

Abstract

A method for recovering a magnesium carbonate of high purity from an aqueous magnesium hydroxide slurry is disclosed. The slurry contains at least 1 percent of magnesium hydroxide and consists of water, magnesium hydroxide and impurities normally associated with magnesium hydroxide slurries. The method involves carbonating the slurry with sufficient carbon dioxide to dissolve a substantial proportion of the magnesium hydroxide therein as magnesium bicarbonate, continuing carbonation until a solution saturated with magnesium bicarbonate is formed, a portion of the magnesium bicarbonate is converted to a crystalline magnesium carbonate and substantially all dissolved calcium is precipitated, so that the slurry contains dissolved magnesium bicarbonate, a crystalline magnesium carbonate precipitate and a calcium carbonate precipitate. Solids are then separated from the magnesium bicarbonate solution, the solution is decarbonated, for example by heat or vacuum, and hydrous magnesium carbonate is separated from the aqueous phase.

Claims

1. A method for recovering a magnesium carbonate of high purity containing, on an oxide basis, at least 99 percent of magnesium carbonate and not more than 1 percent of calcium carbonate, from an aqueous magnesium hydroxide slurry consisting of water, commercially produced magnesium hydroxide and impurities normally associated with said magnesium hydroxide, and containing an amount of magnesium hydroxide, at least 1 percent, sufficient to form a solution saturated with magnesium bicarbonate and containing a crystalline magnesium carbonate precipitate, said method involving the steps of carbonating the slurry with sufficient carbon dioxide to dissolve a substantial proportion of the magnesium hydroxide therein as magnesium bicarbonate, continuing carbonation under conditions of temperature, time and pressure such that a solution saturated with magnesium bicarbonate and containing an appreciable amount of a crystalline magnesium carbonate precipitate is formed and substantially all calcium present is precipitated so that the slurry contains dissolved magnesium bicarbonate, the crystalline magnesium carbonate precipitate and a calcium carbonate precipitate, separating crystalline magnesium carbonate and other solids from the slurry to recover a solution saturated or essentially saturated with magnesium bicarbonate, decarbonating the magnesium bicarbonate solution to precipitate hydrous magnesium carbonate therein, and separating hydrous magnesium carbonate from the aqueous phase.

2. A method as claimed in claim 1 wherein the magnesium hydroxide slurry which is carbonated is a portion of a process stream of magnesium hydroxide and wherein the precipitate separated after carbonation is returned to the main magnesium hydroxide process stream.

3. A method as claimed in claim 1 wherein the magnesium bicarbonate solution is decarbonated by heat.

4. A method as claimed in claim 1 wherein the magnesium bicarbonate solution is decarbonated by vacuum.

5. A method as claimed in claim 1 wherein the magnesium bicarbonate solution is decarbonated by a combination of heat and vacuum.