Contaminated sample gas analyzer and gas cell therefor

• US 4,370,553 A
• Filed: 07/02/1980
• Issued: 01/25/1983
• Est. Priority Date: 07/02/1980
• Status: Expired due to Term

• Current Assignee: JJH Incorporated
• Original Assignee: Sensors, Inc.
• Inventors: Waycaster, Roy A., Bidle, Jerry D., Baker, William T.
• Primary Examiner(s): Smith, Alfred E.
• Assistant Examiner(s): Fields, Carolyn E.
• Application Number:
  US06/165,250
• Time in Patent Office: 937 Days
• Field of Search: 356/440, 356/246, 250/343, 250/344, 250/345, 250/252, 128/719
• US Class Current: 250/343
• CPC Class Codes: G01N 21/03 Cuvette constructions
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 2201/1215 for interfering gases

Abstract

A gas analyzer for performing gas analysis on a sample gas containing contaminants which normally interfere with the operation of the analyzer is disclosed comprising a source of radiant energy; means for directing radiant energy through a sample gas; a disposable gas cell; a detector for receiving radiant energy; and a circuit for analyzing the output of the detector and indicating the concentration of predetermined constituents in the sample gas. The gas cell comprises a disposable sample gas cell having a sample enclosure for containing a sample gas volume; sample windows defining a portion of a sample gas optical path extending from the source of radiant energy through the sample gas volume to the detector; an inlet for supplying sample gas to the sample gas volume and an outlet for exhausting sample gas from the sample gas volume. The disposable sample cell is provided with inlet and exhaust manifolds having cross-sectional areas that minimize dead space and insure laminar flow, minimizing stagnant areas. Specifically, the cross-sectional areas of the inlet and outlet manifolds are relatively constant, the cross-sectional area of the outlet being larger than the cross-sectional area of the inlet, and the inlet and outlet manifolds vary in cross-sectional shape from elongate shapes proximate the windows to a shape having roughly equilateral dimensions distal to the windows. The analyzer and the gas cell are provided with a number of inter-related features that make the analyzer self aligning and eliminates the necessity of recalibrating the analyzer each time a sample cell is replaced.

Claims

1. A gas analyzer for performing gas analysis on a sample gas containing contaminants comprising:

a source of radiant energy;

means for directing radiant energy through a sample gas, the radiant energy being directed along a sample gas optical path;

a gas cell comprising a sample gas cell having a sample enclosure for containing a sample gas volume, a sample window means for defining a portion of said sample gas optical path extending through said sample gas volume, an inlet for supplying sample gas to said sample gas volume and an outlet for exhausting sample gas from said sample gas volume, said sample cell being provided with a flow pattern extending transversely with respect to said sample gas optical path, said flow pattern being defined by an inlet manifold interconnecting said inlet and said sample gas volume, said inlet manifold being provided with a roughly constant cross-sectional area, and an outlet manifold extending from said sample gas volume to said outlet, said outlet manifold being provided with a roughly constant cross-sectional area, the cross-sectional area of said outlet manifold being greater than the cross-sectional area of said inlet manifold, the cross-sectional area of said inlet manifold being provided with a shape having roughly equilateral dimensions at said inlet to an elongate shape having a roughly uniform width at said sample volume, and the cross-sectional area of said outlet manifold being provided with an elongate shape having a roughly uniform width at said sample volume to a shape having roughly equilateral dimensions at said outlet, whereby turbulent flow and dead space in said sample gas volume is minimized;

a connector module for defining a channel for slidably receiving said gas cell and to provide for the periodic removal and replacement of said gas cell while maintaining the optical alignment of the gas analyzer;

detector means for receiving radiant energy from said sample gas optical path;

means for securing together in optical alignment said source, said means for directing radiant energy, said connector module and said detector; and

circuit means for analyzing the output of said detector and indicating the concentration of predetermined constituents of the sample gas.

2. The gas analyzer of claim 1 wherein said means for directing radiant energy also directs radiant energy through a reference gas along a reference gas optical path;

said analyzer further includes a reference gas cell comprising a reference cell enclosure for containing a volume of reference gas and a reference window means for defining a portion of said reference gas optical path;

said detector means receives radiant energy from said sample gas optical path and said reference gas optical path; and

said circuit means indicates the concentration of predetermined constituents of the sample gas by measuring the difference in the amount of radiant energy absorbed by said sample gas and said reference gas.

3. The gas analyzer of claim 2 wherein first and second spring biased detents are provided for engaging opposing sides of said sample cell.

4. The gas analyzer of claim 3 wherein said first and second spring biased detents comprise first and second ball bearings spring biased into engagement with said sample cell;

and first and second ball receiving seats disposed on opposing sides of said sample cell for receiving said first and second ball bearings, respectively, and thus properly orienting said sample gas cell in said sample gas optical path.

5. The gas analyzer of claim 2 wherein said gas cell comprises a single unit including said sample gas cell and said reference gas cell.

6. The gas analyzer of claim 2 wherein said sample gas cell and said reference gas cell are formed from the same material.

7. The gas analyzer of claim 2 wherein said source comprises an electrically heated element disposed at approximately the focal point of a concave source mirror, said source mirror comprising said means for directing radiant energy, said source mirror projecting a collimated beam of infrared energy along said sample gas and said reference gas optical paths.

8. The gas analyzer of claim 7 wherein said electrically heated element is disposed in a chamber filled with one of the group of gases consisting of argon and nitrogen.

9. The gas analyzer of claim 7 wherein said electrically heated element is mounted on a plurality of struts.

10. The gas analyzer of claim 9 wherein said detector is mounted on a septum extending roughly parallel to said plurality of struts and between said sample gas and said reference gas optical paths.

11. The gas analyzer of claim 9 wherein said electrically heated element comprises a plurality of electrically heated wire coils centered to the side of said focal point such that as said element is heated it expands through said focal point.

12. The gas analyzer of claim 2 wherein said means for directing radiant energy includes a chopper wheel disposed between said source and said detector in said sample gas and said reference gas optical paths.

13. The gas analyzer of claim 12 wherein said chopper wheel is driven by a synchronous electric motor.

14. The gas analyzer of claim 12 wherein said chopper wheel comprises a reference window, a sample window and a dark window.

15. The gas analyzer of claim 14 wherein said reference window blocks said sample gas optical path and is open in sad reference gas optical path providing for the passage of radiant energy therethrough;

said sample window blocks said reference gas optical path and is open in said sample gas optical path providing for the passage of radiant energy therethrough; and

said dark window blocks both of said reference gas and said sample gas optical paths.

16. The gas analyzer of claim 15 wherein said chopper wheel is provided with sync marks and said circuit means includes means for generating reference gate, sample gate and dark gate signals.

17. The gas analyzer of claim 16 wherein said circuit means further includes a reference sample/hold circuit, a sample sample/hold circuit and a dark sample/hold circuit for receiving the output of said detector and said gate signals;

said reference gate, said sample gate and said dark gate signals activating said reference, said sample and said dark sample/hold circuits, respectively, to detect and store for a predetermined period a detector reference signal, a detector sample signal and a detector dark signal, respectively.

18. The gas analyzer of claim 17 wherein the output of said reference and said dark sample/hold circuits is inputted to a first differential amplifier and the difference signal from said first differential amplifier is inputted to an automatic gain control circuit for maintaining said difference signal constant.

19. The gas analyzer of claim 18 wherein the outputs of said sample sample/hold circuit and said reference sample/hold circuit are inputted to a second differential amplifier where the outputs of said sample and said reference sample/hold circuits are subtracted from one another.

20. The gas analyzer of claim 19 wherein the output of said second differential amplifier is connected to means for indicating the concentration of a predetermined constituant gas contained in said sample gas.

21. The gas analyzer of claim 20 wherein said sample gas is breath gas expired from a patient and said predetermined constituent gas is carbon dioxide.

22. The gas analyzer of claim 1 wherein said sample gas cell comprises first and second substantially identical halves injection molded from a polymeric material and secured together.

23. The gas analyzer of claim 22 wherein each of said first and second halves includes half of said sample volume;

sample window means comprising a transparent window bounding a portion of said sample volume;

half of an inlet manifold; and

half of an exhaust manifold.

24. The gas analyzer of claim 23 wherein a plurality of locator pins are disposed between said first and second halves, said locator pins extending into both of said first and second halves for accurately aligning the same during assembly.

25. The gas analyzer of claim 1 wherein the cross-sectional shape of said inlet manifold varies from a square at said inlet to an elongate rectangle at said sample volume, said rectangle being bounded by said window means.

26. The gas analyzer of claim 25 wherein said inlet manifold extends along a curve effecting approximately a 90°

change in the direction of flow of the sample gas.

27. The gas analyzer of claim 1 wherein said cross-sectional shape of said exhaust manifold varies gradually from an elongate rectangle having a uniform width at the exit of said sample volume to a square at the outlet of said sample cell.

28. The gas analyzer of claim 27 wherein said inlet manifold extends along a curve effecting a first approximately 90°

change in the direction of flow of the sample gas flowing into said sample volume; and

said exhaust manifold extends along a curve effecting a second approximately 90°

change in the direction of flow of the sample gas, such that said outlet and inlet are roughly parallel and sample gas flows in opposing directions in said inlet and outlet.

29. The gas analyzer of claim 1 wherein said source comprises a source of infrared energy and said detector means comprises an infrared sensitive lead selenide detector.

30. The gas analyzer of claim 1 wherein said gas cell is provided with a labyrinth seal surrounding the periphery of said gas cell for defining a mounting guide for said cell and reducing light leakage about the periphery of said cell.

31. The gas analyzer of claim 1 wherein the portion of said sample gas optical path extending through said sample gas volume is on the order of 1.0 mm.

32. The gas analyzer of claim 1 further including a negative cell disposed in said sample gas optical path ahead of said detector.

33. The gas analyzer of claim 32 wherein said negative cell comprises a plenum filled with a predetermined interfering gas found in the sample gas.

34. The gas analyzer of claim 33 wherein said analyzer is particularly adapted for measuring respired levels of carbon dioxide in breathing gases and said negative cell is filled with nitrous oxide.