Extended area diffractive subtractive color filters

• US 4,372,649 A
• Filed: 05/22/1978
• Issued: 02/08/1983
• Est. Priority Date: 05/22/1978
• Status: Expired due to Term

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Kellie, Truman F.
• Primary Examiner(s): Lee, John D.
• Application Number:
  US05/908,242
• Time in Patent Office: 1,723 Days
• Field of Search: 350/162 R, 350/162 SF, 350/311, 350/316, 350/320, 156/643, 156/659, 96/27 H, 96/36, 96/38.3, 430/1, 430/2, 430/311, 430/320, 430/321, 430/322, 430/323, 430/324, 430/325, 430/326, 430/328, 430/329
• US Class Current: 359/359
• CPC Class Codes: G02B 5/1857 using exposure or etching means, e.g. holography, photolithography, exposure to electron or ion beams
• CPC Class Codes: G02B 5/203 having holographic or diffractive elements diffraction gratings per se G02B5/18; holographic elements per se G02B5/32; generating the spectrum using diffraction elements G01J3/18

Abstract

Large area, diffractive subtractive color filters are provided from a density image of a standing wave interference fringe field pattern in a high speed, high resolution silver halide photographic plate. The high speed enables conventional coherent sources to be spread out to provide a low but constant intensity over extended areas, while still enabling the production of the density image at exposure times sufficiently short to preclude vibrational degradation in resolution. The plates are then developed, overcoated with a photoresist and back-exposed, after which the photoresist is developed to provide a subtractive filter having an extended area surface relief pattern which includes a width controlled periodic diffraction grating.

Claims

1. A method for forming a subtractive color filter suitable for selective attenuation of predetermined wavelengths comprising

(a) directing a pair of mutually coherent beams of radiation having a substantially constant intensity over a given area onto a surface of a photographic medium to form a latent image of a standing wave interference fringe field pattern in which the peak image intensity is substantially constant across an area greater than a square of 50 cm²,

(b) processing said medium to form a permanent image of said field pattern as regions of uniformly varying optical density,

(c) applying a transparent barrier layer to the exposed surface of said medium,

(d) applying a positive photoresist material onto the exposed surface of the barrier layer to form thereon a photoresist layer having a substantially uniform thickness in the range of 0.50-2.00 μ

m±

0.05 μ

m,

(e) directing radiation through the processed medium to form in the photoresist layer a latent image of the optical density image in said medium, under controlled time and exposure conditions such that the total exposure in the photoresist layer results in an aspect ratio in exposed regions in the photoresist layer corresponding to adjacent regions of said optical density image ranging between 0.25 and 0.75,

(f) processing said photoresist layer to remove substantially all of the exposed portions corresponding to the transmissive portions of said optical density image, forming therein a surface relief pattern, having a succession of peaks and valleys, the distance therebetween being substantially equal to the thickness of the layer, and

(g) replicating said pattern into the surface of a polymeric web to form on a surface thereof an optically detectable, width controlled periodic surface relief pattern corresponding to said interference fringe field pattern and extending uniformly and free of discontinuities over a square area greater than 50 cm².

2. A method according to claim 1, comprising applying onto said exposed surface of the barrier layer a positive photoresist material having a peak sensitivity to UV radiation, and directing UV radiation through the processed medium to form said latent image in said photoresist layer.

3. A method according to claim 1, comprising directing said pair of mutually coherent beams onto a high speed silver halide photographic medium having a sensitivity at least sufficient to provide an optical density image having after development an optical density of 1.0 when exposed to radiation having an energy density of not greater than 10,000 ergs/cm².

4. A method according to claim 1, comprising applying as said barrier layer a solution of polyvinyl cinnamic acid and solvent and evaporating the solvent to form a layer thereof.

5. A method according to claim 1, comprising applying said photoresist material by spin-casting onto said exposed surface of the barrier layer a solution of a positive photoresist material and a surfactant, wherein the spin rate and relative compositions are controlled to provide the desired thickness of the resultant photoresist layer.

6. A method according to claim 1, comprising directing said pair of beams onto said photographic medium surface at predetermined angles to form a said standing wave interference fringe field pattern having a predetermined periodicity and directing the radiation through the processed medium and onto the photoresist layer under controlled conditions to provide an aspect ratio in the range between 0.25 and 0.75.

7. A method according to claim 6, comprising forming a set of three subtractive color filters for magenta, cyan and yellow by repeating the steps a-g three times, each time using a separate photographic medium and photoresist material, and controlling the exposure conditions to provide said set of filters having periods, optical peak amplitudes and aspect ratios appropriate for cyan, magenta and yellow filters respectively.

8. A set of subtractive color filters according to the method of claim 7.

9. A subtractive color filter according to the method of claim 1.