Hydrogen sensor

• US 4,373,375 A
• Filed: 12/19/1980
• Issued: 02/15/1983
• Est. Priority Date: 12/19/1980
• Status: Expired due to Fees

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Terhune, James H., Sturtz, John P., Neissel, John P.
• Primary Examiner(s): Gill, James J.
• Application Number:
  US06/218,495
• Time in Patent Office: 788 Days
• Field of Search: 73/23, 73/19, 250/384, 422/83, 422/90, 422/98
• US Class Current: 73/19.01
• CPC Class Codes: G01N 27/66 and measuring current or voltage

Abstract

A hydrogen sensing device for determining the concentration of hydrogen in a fluid atmosphere consists of a sealed chamber formed with a window which selectively allows diffusion of hydrogen into the chamber. Alpha particles from a source contained in the chamber ionize the hydrogen and a pair of polarized electrodes collect the resulting electrons to provide a current which is a function of the hydrogen concentration in the chamber. A second window permeable to helium allows escape of the helium from the chamber that is formed by the combination of electrons with alpha particles therein.

Claims

1. A hydrogen sensor comprising:

a sealed and evacuated chamber;

a first window in said chamber formed of a material selectively permeable to hydrogen to admit hydrogen from an adjacent atmosphere into said chamber;

a source of alpha particles in said chamber for ionizing the hydrogen therein;

a second window in said chamber formed of a material selectively permeable to helium, said second window providing an outlet from said chamber for helium formed by combination of alpha particles and electrons in said chamber; and

a pair of spaced electrodes in said chamber connected to a source of voltage for collecting electrons in said chamber, the resulting electron current being indicative of the concentration of hydrogen in said chamber.

2. The sensor of claim 1 wherein said first window is formed of a palladium-silver alloy.

3. The sensor of claim 1 wherein the outer surface of said first window is covered with a coating of a material selected from the group nickel, stainless steel, alumina, silica, gold, rhodium and rhenium for protection of the surface of said first window but sufficiently thin to permit diffusion of hydrogen through said first window.

4. The sensor of claim 1 wherein said alpha emitter is selected from the group Am-241, Ac-227, Pu-238, Np-237, U-234 and Th-230.

5. The sensor of claim 1 wherein said alpha emitter is formed of Am-241.

6. The combination of claim 1 including means for maintaining said sensor within a predetermined temperature range.

7. The combination of claim 6 wherein said temperature range is from 200 to 700 degrees C.

8. The sensor of claim 1 wherein all the components of said sensor are formed of inorganic materials whereby said sensor is adapted for use in high temperature environments.

9. The combination of claim 1 further including a container surrounding said sensor and forming an enclosed fluid space adjacent said sensor and means for directing a fluid to be sensed for hydrogen content through said container.

10. The combination of claim 9 including means for heating said fluid space.

11. The combination of claim 10 including means for maintaining said fluid space within a predetermined temperature range.

12. The combination of claim 11 wherein said temperature range is from 100 to 650 degrees C.

13. The combination of claim 10 including a jacket of heat insulation material around said container.

14. The combination of claim 9 wherein said means for directing a fluid through said container provides a pressure less than atmospheric pressure in said container.

15. The combination of claim 9 wherein said means for directing a fluid through said container provides a substantially constant rate of flow of fluid through said container.

16. The combination of claim 9 wherein said means for directing a fluid through said container provides a periodically varying rate of flow of fluid through said container.

17. The combination of claim 16 wherein said periodically varying rate of flow of fluid through said container comprises alternating periods of no flow and flow at flow rates of from about 500 ccm for between 1 and 8 seconds to about 2000 ccm for between 2 and 8 seconds.

18. The combination of claim 1 further including means for processing said resulting electron current, comprising:

means for applying only the alternating component of said electron current to a bandpass filter, said filter substantially rejecting signals higher and lower in frequency than a desired band of frequencies.

19. The combination of claim 18 further including a signal squaring circuit connected to receive signals from said bandpass filter and an averaging circuit connected between said squaring circuit and an output terminal whereby the signal at said output terminal is proportional to the mean-square of the alternating current component of said electron current.

20. The combination of claim 1 further including an amplifier circuit for receiving and amplifying said resulting electron current, an averaging RC circuit connecting the output of said amplifier circuit and an output terminal whereby the signal at said output terminal is proportional to the direct current component of said electron current averaged over a period determined by the time constant of said RC circuit.

21. A device for sensing the hydrogen concentration in a fluid atmosphere, comprising:

a first tubular member formed of an electrically conductive material which is selectively permeable to hydrogen;

a second tubular member formed of a material which is selectively permeable to helium secured in end-to-end relationship to said first tubular member to form therewith a tubular body;

a cylindrical member formed at least with an electrically conductive surface electrically insulated from and coaxially positioned with respect to said first tubular member to form therewith an annular chamber for receiving hydrogen which diffuses from said atmosphere through said first tubular member;

a coaxial cable sealed in one end of said tubular body, the center conductor of said coaxial cable being electrically connected to said electrically conductive surface of said cylindrical member and the outer conductor of said coaxial cable being electrically connected to said first tubular member;

means for sealing the other end of said body;

a source of alpha particles contained in said chamber for ionizing hydrogen therein, said first tubular member and said conductive surface of said cylindrical member serving as electrodes to collect the resulting electrons; and

gas passage means communicating said chamber with the inside surface of said second tubular member to provide escape of helium from said chamber.

22. The device of claim 21 wherein said first tubular member is formed of a palladium-silver alloy.

23. The device of claim 22 wherein the outer surface of said first tubular member is covered with a coating of material selected from the group nickel, stainless steel, alumina, silica, gold, rhodium and rhenium--for protection of said surface but sufficiently thin to permit diffusion of hydrogen through said first tubular member.

24. The device of claim 21 wherein said source of alpha particles is a material selected from the group AM-241, Ac-227, Pu-238, Np-237, U-234, Th-230.

25. The device of claim 21 wherein said source of alpha particles is formed of Am-241.

26. The device of claim 21, wherein said source of alpha particles is an alpha emitting material coated on the surface of said cylindrical member.

27. The device of claim 21 wherein said means for sealing the other end of said body includes a pump-out tube for evacuating said body.

28. The device of claim 21 wherein all of the components of said device are formed of inorganic materials whereby said device is adapted for use in high temperature environments.