Process for reducing the hydrogen sulfide content in geothermal steam

• US 4,374,106 A
• Filed: 04/30/1982
• Issued: 02/15/1983
• Est. Priority Date: 08/20/1981
• Status: Expired due to Fees

• Current Assignee: Occidental Research Corporation (Occidental Petroleum Corporation)
• Original Assignee: Occidental Research Corporation (Occidental Petroleum Corporation)
• Inventors: Tipton, Ann B., Crosby, Alan C.
• Primary Examiner(s): Thomas, Earl C.
• Application Number:
  US06/373,317
• Time in Patent Office: 291 Days
• Field of Search: 423/230, 423/231, 423/224, 423/DIG. 19, 60/641.2
• US Class Current: 423/231
• CPC Class Codes: B01D 53/00 Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols, recovery of volatile solvents by condensation B01D5/00; sublimation B01D7/00; cold traps, cold baffles B01D8/00; working-up undefined gaseous mixtures obtained by cracking hydrocarbon oils C10G70/00; cleaning coal gas C10K; working-up of natural gas, or synthetic natural gas, C10L3/10; separation of difficult-to-condense gases or air by liquefaction F25J; for investigating materials G01N30/00
• CPC Class Codes: Y10S 423/19 Geothermal steam purification

Abstract

A process for removing hydrogen sulfide from geothermal steam utilizes iron oxide supported by a carrier resistant to deterioration by the geothermal steam. The process includes the addition of an oxygen-containing gas to the geothermal steam before contacting the steam with the iron oxide at a temperature of at least about 300° F. The amount of oxygen added to the geothermal steam is sufficient to make the molar ratio of oxygen-to-hydrogen sulfide in the steam to be at least about 10.

Claims

1. A process for removing hydrogen sulfide from geothermal steam comprising the steps of:

introducing an oxygen-containing gas into steam produced by a geothermal source, said steam comprising water vapor and hydrogen sulfide and having a temperature of at least about 300°

F.;

said oxygen-containing gas being introduced into said steam in an amount to provide a molar ratio of oxygen-to-hydrogen sulfide in the steam and oxygen-containing gas to be at least about 10; and

,

contacting the steam and oxygen containing gas in a contacting stage with iron oxide supported by a carrier resistant to deterioration by said steam under conditions sufficient to remove hydrogen sulfide from said steam and oxygen containing gas.

2. The process of claim 1, wherein the steam pressure in the contacting stage is at least about 50 psi.

3. The process of claim 1, wherein the steam pressure in the contacting stage is at least about 100 psi.

4. The process of claim 1, 2 or 3, wherein the steam-resistant carrier comprises pumice.

5. The process of claim 1, 2 or 3, wherein the iron oxide comprises iron oxyhydroxide.

6. The process of claim 1, 2 or 3, wherein the iron oxide comprises iron oxyhydroxide and ferric oxide.

7. The process of claim 1, 2 or 3, wherein the oxygen-containing gas comprises air.

8. A process for reducing the hydrogen sulfide content of geothermal steam comprising the steps of:

introducing an oxygen-containing gas into steam produced by a geothermal source, said steam comprising water vapor and hydrogen sulfide and having a temperature of at least about 300°

F.,

said oxygen-containing gas being introduced into said steam in an amount to cause a molar ratio of oxygen-to-hydrogen sulfide in the steam and oxygen-containing gas to be at least about 10;

contacting the steam and oxygen containing gas in a contacting stage with iron oxide supported on a carrier resistant to deterioration by said steam under conditions sufficient to reduce the hydrogen sulfide content of said steam and oxygen-containing gas; and

,

withdrawing steam from the contacting stage, having a lower hydrogen sulfide content than the steam and oxygen-containing gas contacted with said iron oxide in the contacting stage.

9. The process of claim 8, wherein the steam pressure in the contacting stage is at least about 50 psi.

10. The process of claim 8, wherein the steam pressure in the contacting stage is at least 100 psi.

11. The process of claim 9 or 10, wherein the steam-resistant carrier comprises pumice.

12. The process of claim 9 or 10, wherein the steam-resistant carrier comprises alumina.

13. The process of claim 9 or 10, wherein the iron oxide comprises iron oxyhydroxide.

14. The process of claim 9 or 10, wherein the iron oxide comprises iron oxyhydroxide and ferric oxide.

15. The process of claim 9 or 10, wherein the oxygen-containing gas comprises air.

16. A process for reducing the hydrogen sulfide content of geothermal steam comprising the steps of:

introducing air into steam produced by a geothermal source, said steam comprising water vapor and hydrogen sulfide and having a temperature of at least about 300°

F. and a pressure of at least about 100 psi, said air being introduced into said steam in an amount to provide a molar ratio of oxygen to hydrogen sulfide in the steam and air to be at least about 10;

contacting the steam and air in a contacting stage with iron oxyhydroxide at conditions sufficient to reduce the hydrogen sulfide content of said steam and air, said iron oxyhydroxide being supported on pumice; and

,

withdrawing steam and air, from the contacting stage, having a lower hydrogen sulfide content than the steam and air contacted with said iron oxyhydroxide in the contacting stage.

17. A process for reducing the hydrogen sulfide content of geothermal steam comprising the steps of:

introducing air into steam produced by a geothermal source, said steam comprising water vapor and hydrogen sulfide and having a temperature of at least about 300°

F. and a pressure of at least about 100 psi, said air being introduced into said steam in an amount to provide a molar ratio of oxygen to hydrogen sulfide in the steam and air to be at least about 10;

contacting the steam and air in a contacting stage with iron oxyhydroxide under conditions sufficient to reduce the hydrogen sulfide content of said steam and air, said iron oxide being supported on pumice;

withdrawing steam from the contacting stage, having a lower hydrogen sulfide content than the steam and air contacted with said iron oxyhydroxide in the contacting state; and

,

releasing the withdrawn steam and air into the atmosphere.