Process for removing acid gases using a basic salt activated with a non-sterically hindered diamine

• US 4,376,101 A
• Filed: 11/13/1981
• Issued: 03/08/1983
• Est. Priority Date: 11/13/1981
• Status: Expired due to Fees

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Savage, David W., Sartori, Guido, Kim, Chang J., Melchior, Michael T.
• Primary Examiner(s): Thomas, Earl C.
• Application Number:
  US06/321,059
• Time in Patent Office: 480 Days
• Field of Search: 423/223, 423/226, 423/228, 423/229, 423/232, 423/234, 252/189, 252/190, 252/192
• US Class Current: 423/223
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

Acidic gases containing carbon dioxide are removed from a normally gaseous mixture by absorbing CO₂ from the gaseous mixture with an aqueous solution comprising a basic alkali metal salt or hydroxide and an activator or promoter system for the salt or hydroxide which contains (i) at least one non-sterically hindered diamine defined as having both a primary and a tertiary amino moiety wherein the primary amino moiety is attached to a primary carbon atom, and (ii) an amino acid, and desorbing at least partially the absorbed CO₂ from the aqueous solution.

Claims

1. A process for the removal of CO₂ from a gaseous stream containing CO₂ which comprises (1) in an absorption step, absorbing CO₂ from said gaseous stream with an aqueous absorbing solution comprising (a) a basic alkali metal salt or hydroxide selected from the group consisting of alkali metal bicarbonates, carbonates, hydroxides, borates, phosphates and their mixtures, and (b) an activator or promoter system for said basic alkali metal salt or hydroxide comprising (i) at least one non-sterically hindered diamine which is defined as a compound containing both a primary and a tertiary amino moiety wherein the primary amino moiety is attached to a primary carbon atom, and (ii) an amino acid which has the capability to increase the solubility of said diamines in alkaline aqueous conditions at elevated temperatures, and (2) in a desorption and regeneration step desorbing at least a portion of the absorbed CO₂ from said absorbing solution.

2. The process of claim 1 wherein said amino acid has 4 to 8 carbon atoms and is free of any hydroxyl groups and is either a tertiary amino acid wherein the amino moiety is a tertiary amino moiety or a sterically hindered amino acid containing at least one secondary amino moiety attached to either a secondary or tertiary carbon atom or a primary amino moiety attached to a tertiary carbon atom.

3. The process of claim 1 wherein said amino acid is pipecolinic acid or N-secondary butyl glycine.

4. The process of claim 1 wherein said basic alkali metal salt or hydroxide is potassium carbonate.

5. The process of claim 1 wherein the aqueous solution contains 10 to about 40% by weight of said basic alkali metal salt or hydroxide.

6. The process of claim 1 wherein the aqueous solution contains 2 to about 20% by weight of said diamine and 2 to about 20% by weight of said amino acid.

7. The process of claim 1 wherein said diamine is represented by the following general formulae:

space="preserve" listing-type="equation">H.sub.2 N(CH.sub.2).sub.n NRR'"'"' or H.sub.2 N(CH.sub.2).sub.n N(CH.sub.2).sub.m

wherein R and R'"'"' independently represent a C₁ -C₆ alkyl or a C₆ -C₈ cycloalkyl group, n is an integer of at least 2, and m is an integer of at least 4.

8. The process of claim 1 wherein said diamine is N-(3-aminopropyl)-2-pipecoline, N-(2-aminoethyl)-hexamethyleneimine, N-methyl-N-cyclohexyl-1,3-propanediamine, or N-methyl-N-cyclohexyl ethylenediamine.

9. The process of claim 1 wherein the temperature of the absorbing solution during the absorption step is in the range of from about 25°

to about 200°

C., the pressure in the absorber ranges from about 5 to about 2,000 psia, and the partial pressure of the acid components in the feed stream ranges from about 0.1 to about 500 psia.

10. The process of claim 9 wherein the temperature of the absorbing solution during the regeneration step is in the range from about 25°

to about 200°

C. and at pressures ranging from about 16 to 100 psia.

11. The process of claim 1 wherein the absorbing solution additionally includes additives selected from the group consisting of antifoaming agents, antioxidants and corrosion inhibitors.

12. A process for the removal of CO₂ from a gaseous stream containing CO₂ which comprises, in sequential steps, (1) contacting the gaseous stream with an absorbing solution comprising (a) from about 20 to about 30 weight percent of potassium carbonate and (b) an activator or promoter system for the potassium carbonate comprising (i) from about 5 to about 15 weight percent of at least one non-sterically hindered diamine which is defined as a compound containing both a primary and a tertiary amino moiety wherein the primary amino moiety is attached to a primary carbon atom, and (ii) from about 5 to about 10 weight percent of pipecolinic acid or N-secondary butyl glycine, and (c) the balance of said absorbing solution being comprised of water and additives selected from the group consisting of antifoaming agents, antioxidants and corrosion inhibitors, wherein said contacting is conducted at conditions whereby CO₂ is absorbed in said absorbing solution and the temperature of the absorbing solution is in the range from about 35°

to about 150°

C., and the pressure in the absorber is in the range from about 100 to about 1,500 psia; and

(2) regenerating said absorbing solution at conditions whereby CO₂ is desorbed from said absorbing solution, wherein the regeneration takes place at temperatures ranging from about 35°

to about 105°

C. and at pressures ranging from about 5 to about 100 psig.

13. The process of claim 12 wherein the absorbing solution from the regeneration step is recycled for reuse in the contacting step.

14. An aqueous acid gas scrubbing composition comprising:

(a) 10 to about 40% by weight of an alkali metal salt or hydroxide, (b) 2 to about 20% by weight of a non-sterically hindered diamine containing both a primary and a tertiary amino moiety wherein the primary amino moiety is attached to a primary carbon atom, (c) 2 to about 20% by weight of an amino acid which has the capability to increase the solubility of said diamines in alkaline aqueous conditions at elevated temperatures, and (d) the balance, water.

15. An aqueous acid gas scrubbing composition comprising:

(a) 20 to 30% by weight of potassium carbonate, (b) 5 to about 15% by weight of N-(3-aminopropyl)-2-pipecoline, (c) 5 to about 10% by weight of pipecolinic acid, and (d) the balance, water.