V-Shaped sandwich-type cell with reticulate electodes

• US 4,377,455 A
• Filed: 07/22/1981
• Issued: 03/22/1983
• Est. Priority Date: 07/22/1981
• Status: Expired due to Fees

• Current Assignee: OLIN Corporation
• Original Assignee: OLIN Corporation
• Inventors: Kadija, Igor V., Woodard, Kenneth E. Jr.
• Primary Examiner(s): Andrews, R. L.
• Application Number:
  US06/285,724
• Time in Patent Office: 608 Days
• Field of Search: 204/265, 204/266, 204/98, 204/128, 204/258, 204/283-284
• US Class Current: 205/348
• CPC Class Codes: C25B 11/03 perforated or foraminous
• CPC Class Codes: C25B 9/19 with diaphragms

Abstract

An electrolytic cell for the electrolysis of aqueous solutions to produce gaseous products is comprised of a housing, a separator traversing said housing to form an anode compartment and a cathode compartment, an anode in the anode compartment, a cathode in the cathode compartment, means for introducing an electrolyte into and removing said electrolyte from said anode compartment, an outlet for gaseous products in the anode compartment, means for introducing a liquid into and removing a liquid from the cathode compartment, and an outlet for gaseous products in the cathode compartment. The electrolytic cell has at least one of the anode and the cathode comprising a porous electrode having a porosity in the range of from about 30 to about 98 percent, the porous electrode having a first portion in direct contact with the separator and a second portion spaced apart from the separator, the second portion being closer to said outlets for gaseous products than said first portion.

The electrolytic cell operates at reduced cell voltages with improved release of gas bubbles formed during electrolysis and improved liquid circulation through the porous electrode.

Claims

1. An electrolytic cell for the electrolysis of aqueous solutions to produce gaseous products which comprises a housing, a separator traversing said housing to form an anode compartment and a cathode compartment, an anode in said anode compartment adjacent to said separator, a cathode in said cathode compartment adjacent to said separator, means for introducing an electrolyte into and removing said electrolyte from said anode compartment, an outlet for gaseous products in said anode compartment, means for introducing a liquid into and removing a liquid from said cathode compartment, an outlet for gaseous products in said cathode compartment, means for supplying electrical current to said anode and said cathode, at least one of said anode and said cathode comprising a porous electrode having a porosity in the range of from about 30 to about 98 percent, said porous electrode having a first portion in direct contact with said separator and a second portion spaced apart by an angle of inclination from said separator, said second portion being closer to said outlets for gaseous products than said first portion.

2. The electrolytic cell of claim 1 in which said separator is selected from the group consisting of hydraulically permeable diaphragms and hydraulically impermeable ion exchange members.

3. The electrolytic cell of claim 2 in which compression means are employed to maintain said first portion in contact with said separator.

4. The electrolytic cell of claim 3 in which said first portion is from about 5 to about 50 percent of the length of said porous electrode.

5. The electrolytic cell of claim 4 in which said separator is a hydraulically impermeable cation exchange membrane.

6. The electrolytic cell of claim 5 in which said porous electrode has a porosity of from about 70 to about 98 percent.

7. The electrolytic cell of claim 6 in which said porous electrode is a reticulate electrode.

8. The electrolytic cell of claim 7 in which said reticulate electrode is a cathode.

9. The electrolytic cell of claim 7 in which said reticulate electrode is an anode.

10. The electrolytic cell of claim 1 in which said anode and said cathode are porous electrodes.

11. The electrolytic cell of claim 2 in which said separator is positioned vertically within said housing.

12. The electrolytic cell of claim 11 in which the angle of inclination between the separator and the second portion of said porous electrode is from about 2 to about 8 degrees.

13. The electrolytic cell of claim 12 having a plurality of porous electrodes.

14. The electrolytic cell of claim 13 in which said porous electrodes are reticulate electrodes.

15. A process for the electrolysis of an aqueous alkali metal chloride solution employing the electrolytic cell of claim 1, said process comprising applying electrolysis current between anode and cathode to produce chlorine and alkali metal hydroxide.

16. An electrolytic cell for the electrolysis of aqueous solutions to produce gaseous products which comprises a housing, a separator positioned vertically in said housing to form an anode compartment and a cathode compartment, an anode in said anode compartment adjacent to said separator, a cathode in said cathode compartment adjacent to said separator, means for introducing an electrolyte into and removing said electrolyte from said anode compartment, an outlet for gaseous products in said anode compartment, means for introducing a liquid into and removing a liquid from said cathode compartment, an outlet for gaseous products in said cathode compartment, means for supplying electrical current to said anode and said cathode, at least one of said anode and said cathode comprising a porous electrode having a porosity in the range of from about 30 to about 98 percent, said porous electrode having a first lower portion in direct contact with said separator and a second upper portion spaced apart from said separator to provide a fluid release zone between said separator and said second portion.