Electrically conducting fiber and method of making same

• US 4,378,226 A
• Filed: 05/04/1981
• Issued: 03/29/1983
• Est. Priority Date: 10/09/1978
• Status: Expired due to Term

• Current Assignee: Nihon Sanmo Dyeing Co., Ltd.
• Original Assignee: Nihon Sanmo Dyeing Co., Ltd.
• Inventors: Gomibuchi, Reizo, Takahashi, Kiyofumi, Tomibe, Shinje
• Primary Examiner(s): CANNON, JAMES
• Application Number:
  US06/260,129
• Time in Patent Office: 694 Days
• Field of Search: 8/115.5, 8/116 R, 8/192, 8/193, 8/127.5, 8/128 R, 8/491, 8/194, 8/120, 8/127.6, 8/495, 8/624, 427/121, 427/343, 428/361, 428/373, 428/374, 428/379, 428/392, 428/393, 428/394, 428/395
• US Class Current: 8/491
• CPC Class Codes: D06M 11/53 with hydrogen sulfide or its salts; with polysulfides
• CPC Class Codes: D06M 2101/28 Acrylonitrile; Methacrylonitrile
• CPC Class Codes: H01B 1/122 Ionic conductors
• CPC Class Codes: Y10T 428/2907 with coating or impregnation
• CPC Class Codes: Y10T 428/2929 Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
• CPC Class Codes: Y10T 428/2931 Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
• CPC Class Codes: Y10T 428/294 including metal or compound thereof [excluding glass, ceramic and asbestos]
• CPC Class Codes: Y10T 428/2964 Artificial fiber or filament
• CPC Class Codes: Y10T 428/2965 Cellulosic
• CPC Class Codes: Y10T 428/2967 Synthetic resin or polymer
• CPC Class Codes: Y10T 428/2969 Polyamide, polyimide or polyester

Abstract

Electrically conducting fibers are prepared by introducing cyanic groups into a synthetic or natural starting fiber and then subjecting the fiber to a heat treatment with a copper compound, a reducing agent capable of reducing bivalent copper ions to monovalent copper ions, and a sulfur-containing compound capable of discharging a sulfur atom or sulfur ion for reaction with monovalent copper ions adsorbed by the fiber so that copper sulfide is impregnated into the fibers. Heat treatment with the sulfur-containing compound can be simultaneous with or separate from heat treatment with the copper compound and reducing agent. The electrically conducting fibers of the present invention have excellent conductivity, improved washability and are not plagued by the problem of static charging associated with the starting synthetic or natural fiber.

Claims

1. An electrically conducting fiber comprising a synthetic or natural starting fiber having cyanic groups introduced therein which is impregnated with copper sulfide.

2. An electrically conducting fiber as claimed in claim 1 wherein said starting synthetic fiber is selected from the group consisting of polyamide fiber, polyester fiber, rayon fiber, and cupro-ammonium fiber and said starting natural fiber is selected from the group consisting of wool, cotton, and silk.

3. An electrically conducting fiber as claimed in claim 1 wherein the starting fiber is a synthetic fiber.

4. An electrically conducting fiber as claimed in claim 1 wherein said starting fiber is an animal fiber or a vegetable fiber.

5. An electrically conducting fiber as claimed in claim 2 wherein said cyanic groups are introduced into said starting fiber by reaction with dicyandiamide, graft polymerization of acrylonitrile onto the starting fiber, cyanoethylization, mixed spinning, graft polymerized material spinning, or blocked polymerized material spinning.

6. An electrically conducting fiber as claimed in claim 1 or 2 wherein the weight percentage of copper sulfide is about 1% to about 30% based upon the weight of the starting fiber.

7. An electrically conducting fiber as claimed in claim 6 wherein said copper sulfide is cupric sulfide.

8. An electrically conducting fiber as claimed in claim 6 wherein said copper sulfide is cuprous sulfide.

9. An electrically conducting fiber as claimed in claim 6 wherein said copper sulfide is in the form of digenite which is adsorbed within the fiber.

10. An electrically conducting fiber as claimed in claim 6 which is dyed with a cationic dye.

11. A method of making an electrically conducting fiber comprising heat treating at least one synthetic or natural starting fiber having cyanic groups introduced therein with a copper compound, a reducing agent capable of reducing bivalent copper ions to monovalent copper ions, and a sulfur-containing compound to adsorb copper sulfide within said starting fiber containing said cyanic groups.

12. A method as claimed in claim 11 wherein heat treatment with the sulfur-containing compound is separate from and subsequent to heat treatment with the copper compound and the reducing agent.

13. A method as claimed in claim 11 wherein heat treatment with the copper compound, the reducing agent, and the sulfur-containing compound is within the same heat treating bath.

14. A method as claimed in claim 11 wherein said starting synthetic fiber is selected from the group consisting of polyamide fiber, polyester fiber, rayon fiber, and cupro-ammonium fiber and said starting natural fiber is selected from the group consisting of wool, cotton, and silk.

15. A method as claimed in claim 11 wherein the starting fiber is a synthetic fiber.

16. A method as claimed in claim 11 wherein said cyanic groups are introduced into said starting fiber by reaction with dicyandiamide, graft polymerization of acrylonitrile onto the starting fiber, cyanoethylization, mixed spinning, graft polymerized material spinning, or blocked polymerized material spinning.

17. A method as claimed in claim 11 wherein said copper compound is a cupric salt.

18. A method as claimed in claim 11 wherein said reducing agent is selected from the group consisting of metallic copper, hydroxylamine sulfate, ferrous sulfate, ammonium vanadate, furfural, sodium hypophosphate, glucose, and mixtures thereof.

19. A method as claimed in claim 11 wherein said sulfur-containing compound is selected from the group consisting of sodium sulfide, sulfur dioxide, sodium hydrogen sulfite, sodium pyrosulfite, sulfurous acid, dithionous acid, sodium dithionite, sodium thiosulfate, thiourea dioxide, hydrogen sulfide, NaHSO₂.CH₂ O.2H₂ O;

Z_n SO₂.CH₂ O.H₂ O and mixtures thereof.

20. A method as claimed in claim 11 wherein said heat treatment is at a temperature of from about 80°

C. to about 120°

C.

21. A method as claimed in claim 11 wherein said copper sulfide is in the form of digenite.

22. A method as claimed in claim 11 wherein said heat treatment is in an aqueous bath which contains a pH adjusting compound selected from the group consisting of inorganic and organic acids, salts of inorganic and organic acids, and mixtures thereof.

23. A method as claimed in claim 11 wherein the weight percentage of copper sulfide in the electrically conducting fiber is about 1% to 30% based upon the weight of the starting fiber.