Tin-phosphorus oxyfluoride glass containing aromatic organic compound

• US 4,379,070 A
• Filed: 04/26/1982
• Issued: 04/05/1983
• Est. Priority Date: 04/26/1982
• Status: Expired due to Term

• Current Assignee: Corning Glass Works Inc. (Corning Incorporated)
• Original Assignee: Corning Glass Works (Corning Incorporated)
• Inventors: Tick, Paul A.
• Primary Examiner(s): McCarthy, Helen M.
• Application Number:
  US06/371,791
• Time in Patent Office: 344 Days
• Field of Search: 252/301.16, 252/301.18, 252/301.33, 252/301.4 P, 501/44, 501/13, 501/32, 350/354, 350/357, 430/945
• US Class Current: 252/301.16
• CPC Class Codes: C03C 3/247 containing fluorine and phosphorus
• CPC Class Codes: C03C 4/04 for photosensitive glass
• CPC Class Codes: C03C 4/12 for luminescent glass; for fluorescent glass
• CPC Class Codes: C09K 11/06 containing organic luminescent materials
• CPC Class Codes: G02F 1/1516 comprising organic material
• CPC Class Codes: H01S 3/168 using an organic dye dispersed in a solid matrix
• CPC Class Codes: Y10S 430/146 Laser beam

Abstract

A tin-phosphorous oxyfluoride glass in the Sn--P--O--F composition field is used as a supporting matrix for light-responsive polycyclic aromatic hydrocarbons, such as triplet state or lasing dyes. Dye compatibility with the glass is good, as evidenced by the fact that glasses containing the dyes exhibit luminescence characteristic of the dissolved dye in a rigid solvent.

Claims

1. A tin-phosphorous oxyfluoride glass article containing at least one dissolved polycyclic aromatic hydrocarbon which exhibits a response to light or an electric field, the compound being present in a concentration ranging up to about 1% by weight of the glass.

2. A glass article in accordance with claim 1 having a composition which comprises, exclusive of the polycyclic aromatic hydrocarbon compound, about 20-85% Sn, 2-20% P, 3-20% O, 10-36% F, and at least 75% total of Sn+P+O+F.

3. A glass article in accordance with claim 2 wherein the polycyclic aromatic hydrocarbon compound contains 14-42 carbon atoms, has boiling and decomposition temperatures above 250°

C., and exhibits a photophysical response to light.

4. A glass article in accordance with claim 3 which includes at least one triplet-state dye compound and which exhibits phosphorescence or fluorescence upon exposure to ultraviolet light.

5. A glass article in accordance with claim 3 which includes at least one triplet-state dye compound exhibiting triplet-state absorption of visible light.

6. A glass article in accordance with claim 3 which includes at least one laser dye.

7. A glass article in accordance with claim 2 which includes at least one electrochromic dye.

8. A glass article in accordance with claim 7 wherein the dye is a viologen dye.