Metallurgical extractant system

• US 4,382,872 A
• Filed: 09/08/1980
• Issued: 05/10/1983
• Est. Priority Date: 07/25/1979
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Grinstead, Robert R.
• Primary Examiner(s): Jiles, Henry R.
• Assistant Examiner(s): Whittenbaugh, Robert C.
• Application Number:
  US06/184,828
• Time in Patent Office: 974 Days
• Field of Search: 252/182, 252/189, 75/101 R, 23/230 R, 423/139, 260/429 J
• US Class Current: 252/189
• CPC Class Codes: C01G 3/003 Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
• CPC Class Codes: C01G 51/003 Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
• CPC Class Codes: C01G 53/003 Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
• CPC Class Codes: C22B 3/402 of acyclic or carbocyclic compounds of different types
• CPC Class Codes: Y02P 10/20 Recycling

Abstract

An extractant system comprising (a) a high molecular weight alkylaromatic sulfonic acid and (b) a chelating amine having a pKa of from about 3 to about 9 in a solvent which is essentially immiscible with water, said system being useful for the selective extraction of desired metals, e.g., cobalt, nickel or copper ions from aqueous acidic ore leach liquors.

Claims

1. An extractant system useful for the selective extraction of cobalt, copper or nickel metal values present in an aqueous acidic ore leach liquor containing more than one metal value, said extractant system comprising:

(a) an alkylaromatic sulfonic acid having a molecular weight of at least about 400,

(b) a chelating amine having a pKa in the range from about 3 to about 9 selected from the group consisting of picolylamines, oxazoles, benzoxazoles, pyridyl imidazoles and picolinic acid amides and esters, and

a water-immiscible diluent for (a) and (b).

2. The system of claim 1 wherein component (b) has a pKa of from about 3.0 to about 5.0 and the aqueous acidic ore leach liquor comprises either (i) at least two metal values selected from the group consisting of cobalt, copper and nickel or (ii) a first metal value selected from the group consisting of cobalt, copper and nickel and a second metal value selected from the group consisting of aluminum, calcium, iron, magnesium and manganese.

3. The system of claim 1 wherein component (b) is a picolylamine;

a pyridyl imidazole or a picolinic acid amide or ester.

4. The system of claim 1 wherein component (a) is a branched polyalkyl substituted naphthalene sulfonic acid.

5. The system of claim 4 wherein component (b) is a picolylamine.

6. The system of claim 4 wherein component (a) is a branched polyalkyl substituted naphthalene sulfonic acid.

7. The system of claim 6 wherein (a) is dinonylnaphthalene sulfonic acid and (b) is N-(p-dodecylbenzyl)-bis-picolylamine.

8. The system of claim 1 or 5 wherein components (a) and (b) are present in a mole ratio of from about 2:

1 to about 1;

5 and the total concentration of components (a) plus (b) in component (c) is in the range of from about 0.1 to about 1.2 molar.

9. The system of claim 8 wherein components (a) and (b) are present in a mole ratio of from about 1:

1 to about 1;

3.