Method of recovering lead and lead compounds from discarded lead storage batteries

• US 4,384,683 A
• Filed: 03/11/1981
• Issued: 05/24/1983
• Est. Priority Date: 06/18/1980
• Status: Expired due to Fees

• Current Assignee: Salzgitter Maschinenbau GmbH
• Original Assignee: Hazemag Dr E Andreas GmbH & Company
• Inventors: Konig, Rolf, Huwald, Eberhard
• Primary Examiner(s): Rosenbaum, Mark
• Application Number:
  US06/242,476
• Time in Patent Office: 804 Days
• Field of Search: 241/14, 241/16, 241/18, 241/20, 241/21, 241/23, 241/24, 241/27, 241/29, 241/76, 241/77, 241/78, 241/79.1, 241/19
• US Class Current: 241/19
• CPC Class Codes: B03B 2009/066 the refuse being batteries
• CPC Class Codes: C01G 21/00 Compounds of lead
• CPC Class Codes: C22B 13/00 Obtaining lead
• CPC Class Codes: C22B 7/005 Separation by a physical processing technique only, e.g. by mechanical breaking
• CPC Class Codes: H01M 10/54 Reclaiming serviceable parts of waste accumulators
• CPC Class Codes: Y02P 10/20 Recycling
• CPC Class Codes: Y02W 30/52 Mechanical processing of waste for the recovery of materials, e.g. crushing, shredding, separation or disassembly
• CPC Class Codes: Y02W 30/84 Recycling of batteries or fuel cells

Abstract

Scrapped storage batteries are first preliminarily crushed to discharge acid from individual cells, thereupon rinsed by alkaline water, crushed in a hammermill and simulataneously dried by a stream of hot air; noncrushed lead pieces are discharged separately from the hammermill and the remaining crushed material is discharged in dry condition from the mill and classified into two fractions, namely a coarse lead fraction and a second fraction consisting of fine particles of lead compounds mixed with coarser pieces of plastic material.

Claims

1. A method of recovering lead and lead compounds from scrapped storage batteries, comprising the steps of preliminarily crushing the batteries to discharge acid therefrom;

rinsing the crushed pieces by a minimum amount of a liquid preferably alkaline water;

further crushing the coarsely crushed pieces while simultaneously drying the same at a relatively low temperature at which only a negligible amount of the residual acid is vaporized; and

thereafter classifying the crushed dry material into the coarse lead fraction, a fraction of fine lead compounds and remaining materials of low specific weight, mostly plastics.

2. A method as defined in claim 1, wherein said crushing and drying step is carried out in a two-rotor hammermill, the rotors of which are driven at a relatively low speed in the range of about 40 meters per second on their circumference, said hammermill having a top inlet and a bottom outlet, grates provided between said rotors and said outlet and having a slot at the end of the grate furthest away from the said inlet through which non-crushed-parts of the battery are discharged.

3. A method as defined in claim 2, wherein said step of crushing and drying includes the exposure of material in said hammermill to a stream of drying gases having temperature between 300°

and 350°

C.

4. A method as defined in claim 3, further including the step of discharging said stream of drying gases together with entrained finely pulverized particles of lead compounds into a separator and thereupon admixing the separated fine lead-compound particles to crushed and dry particles discharged from said outlet of the hammermill.

5. A method as defined in claim 4, wherein said classifying step includes the separation of crushed and dry material into two fractions, one fraction including coarse lead parts and the second fraction including a mixture of fine lead compounds and of plastic pieces.

6. A method as defined in claim 5, wherein said two fractions are separated in an air sifter.

7. A method as defined in claim 5, wherein said second fraction is fed on a screen for separating finely divided particles of lead compounds from coarser particles of plastics.

8. A method as defined in claim 7, wherein said plastic particles are washed in a washing device for removing adhering dust of lead compounds.

9. A method as defined in claim 8, wherein sludges contained in the used washing water are recovered and the water is neutralized and purified.

10. A method as defined in claim 4, wherein used drying gases upon their discharge from the separator are purified in a washing device.